Flow behaviour index measurement

The rheograms shown in Figure 4 can be fitted by a power law relation, and the concentrations at which rheological measurements were taken also were those tested in the flow loop. The physical data including suspension density, power law flow behavior index, and material consistency coefficient are given in Table 1. It is noticeable that the suspension displays a consistent movement away from Newtonian behavior as solid concentration increases the flow behaviour index consistently reduces in Table 1. 

Many factors influence the accuracy of experimental data and each experimental run could be described by a different set of parameters n, K, Ty. Since the flow models strongly depend on input data and their evaluation, a sensitivity analysis was used to find effect of value of flow behaviour index n on accuracy of laminar and turbulent flow models. Dependency of slurry/water pressure gradient ratio i / io on mean slurry velocity V of the measured slurries for both tested turbulent models and yield power-law model is shown in Fig. 4, where also a role of parameter n is illustrated. The value of n given by best fitting of laminar data by Eq. (4) represents quite well laminar region. For turbulent data it is not valid (see dashed line). The best fitting value n for turbulent data varies not only with kind of solid material, but depends also on concentration. 

First, the rate of shear, which is not linear with the shearing stress due to the non-Newtonian behaviour, varies with the different types of polymer. The processability of different polymers with an equal value of the MI may therefore differ widely. An illustration of this behaviour is given in Fig. 15.14. Furthermore the standard temperature (190 °C) was chosen for polyethylenes for other thermoplastics it is often less suitable. Finally, the deformation of the polymer melt under the given stress is also dependent on time, and in the measurements of the melt index no corrections are allowed for entrance and exit abnormalities in the flow behaviour. The corrections would be expected to vary for polymers of different flow characteristics. The length-diameter ratio of the melt indexer is too small to obtain a uniform flow pattern. 

Melt rheometers either impose a fixed flow rate and measure the pressure drop across a die, or, as in the melt flow indexer, impose a fixed pressure and measure the flow rate. Equation (B.5) gives the shear stress, but Eq. (B.IO) requires knowledge of n to calculate the shear strain rate. It is conventional to plot shear stress data against the apparent shear rate y, calculated using n = 1 (assuming Newtonian behaviour). If the data is used subsequently to compute the pressure drop in a cylindrical die, there will be no error. However, if a flow curve determined with a cylindrical die is used to predict... 

In a series of experiments on the flow of flocculated kaolin suspensions in laboratory and industrial scale pipelines(26-27-2Sl, measurements of pressure drop were made as a function of flowrate. Results were obtained using a laboratory capillary-tube viscometer, and pipelines of 42 mm and 205 mm diameter arranged in a recirculating loop. The rheology of all of the suspensions was described by the power-law model with a power law index less than unity, that is they were all shear-thinning. The behaviour in the laminar region can be described by the equation ... 

A fluid which exhibits non-Newtonian behaviour is flowing in a pipe of diameter 70 mm and the pressure drop over a 2 m length of pipe is 4 x 104 N/m2. A pitot lube is used to measure the velocity profile over the cross-section. Confirm that the information given below is consistent with the laminar flow of a power-law fluid. Calculate the power-law index n and consistency coefficient K. 

The melt flow index is a useful indication of the molar mass, since it is a reciprocal measure of the melt viscosity p. p depends very strongly on 77 ( ) (doubling of results in a 10.6 times higher 77 ). This relation is valid for the zero-shear viscosity the melt index is measured at a shear stress where the non-Newtonian behaviour, and thus the width of the molar mass distribution, is already playing a part (see MT 5.3.2). The melt index is a functional measure for the molar mass, because for a producer of end products the processability is often of primary importance. 

It would be desirable to have simple tests capable of characterising the fluidisation behaviour or flowability of particulate materials on the basis of their bulk properties. To this end, Carr19 developed a system to characterise bulk solids with respect to flowability. Table 6 summarises the properties which are determined. In Carr s method a numerical value is assigned to the results of each of these tests, and is summed to produce a relative flowability index for that particular bulk material. Given the extensive use of these empirical techniques in academia and industry, a brief review on the subject is reported here. Nevertheless, it should be emphasised that these techniques allow measurements of the flow-ability or cohesion of materials solely in their stationary or compressed status and at ambient conditions. A direct relationship between these... 

Measurement techniques of the elastic moduli, 388 Mechanical behaviour and failure, 819 Mechanical comfort, 879 Mechanical properties of solid polymers, 383 various materials, 389 Melt/Melting, 167, 700 elasticity, 316 expansion, 97 flow index, 801, 802 flow rate diagram, 801 fracture, 578 number, 579 strength, 799, 812 Merkel number, 59 Mesogenic groups, 34 in the main chain, 177 side-chain, 179 Mesogenic polymers, 172... 

The Influence of some Important Industrial parameters such as the hydrogen/ethylene ratio, the 1-butene content In the polymerization mixture and polymerization temperature on the behaviour of the catalysts, has been evaluated by measuring polymer productivity after 4 hours, polymer melt flow Index (MFI), shear sensitivity (SS), Intrinsic viscosity and molecular weight distribution. 

The Mooney index is usually measured under the conditions, i.e., time and temperature, where the material behaviour is rubbery and not flow. Therefore, what is measured is not a viscosity. Yet, it is erroneously called Mooney viscosity. The deformation and fracture may be observable using coloured markers on the rubber specimen. 

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