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Flammability limits concentration

It is further found that the adiabatic flame temperature is approximately 1300 °C for mixtures involving inert diluents at the lower flammable limit concentration. The accuracy of this approximation is illustrated in Figure 4.19 for propane in air. This approximate relationship allows us to estimate the lower limit under a variety of conditions. Consider the resultant temperature due to combustion of a given mixture. The adiabatic flame temperature (7f ad), given by Equation (2.22) for a mixture of fuel (Xp), oxygen (Xo2) and inert diluent (Xd) originally at 7U, where all of the fuel is consumed, is... [Pg.103]

The flash-point of a liquid mixture can be estimated by determining the temperature at which the equilibrium concentration of the flammable vapors in the air reach a concentration such that ( i/LFLi) = 1.0 where yi is the vapor phase mole percent of component i and LFL( is the lower flammability limit concentration of component... [Pg.104]

Tlie flash point of a flanunable liquid is defined as the temperature at which tlie vapor pressure of the liquid is tlie same as the vapor pressure corresponding to tlie lower flammability limit concentration. Tlie tliree major methods of measuring Uie flash point are... [Pg.206]

Flammability limits. A flammable gas will bum in air only over a limited range of composition. Below a certain concentration of the flammable gas, the lower flammability limit, the mixture is too lean to burn, i.e., lacks fuel. Above a certain concentration, the upper flammability limit, it is too rich to burn, i.e., lacks oxygen. Concentrations between these limits constitute the flammable range. [Pg.256]

The autoignition temperature is the minimum temperature required for self-sustained combustion in the absence of an external ignition source. The value depends on specified test conditions. Tht flammable (explosive) limits specify the range of concentration of the vapor in air (in percent by volume) for which a flame can propagate. Below the lower flammable limit, the gas mixture is too lean to burn above the flammable limit, the mixture is too rich. Additional compounds can be found in National Fire Protection Association, National Fire Protection Handbook, 14th ed., 1991. [Pg.498]

Inert Gas Dilution. Inert gas dilution involves the use of additives that produce large volumes of noncombustible gases when the polymer is decomposed. These gases dilute the oxygen supply to the flame or dilute the fuel concentration below the flammability limit. Metal hydroxides, metal carbonates, and some nitrogen-producing compounds function in this way as flame retardants (see Flame retardants, antimony and other inorganic compounds). [Pg.465]

Air is compressed to modest pressures, typically 100 to 200 kPa ( 15-30 psig) with either a centrifugal or radial compressor, and mixed with superheated vaporized butane. Static mixers are normally employed to ensure good mixing. Butane concentrations are often limited to less than 1.7 mol 1 to stay below the lower flammable limit of butane (144). Operation of the reactor at butane concentrations below the flammable limit does not eliminate the requirement for combustion venting, and consequendy most processes use mpture disks on both the inlet and exit reactor heads. A dow diagram of the Huntsman fixed-bed maleic anhydride process is shown in Figure 1. [Pg.455]

The lower flammable limit (LEL) or lower explosive limit (LEL) is the minimum concentration of vapor in air below which a flame is not propagated when an ignition source is present (61—64). Below this concentration, the mixture is considered too lean to bum. The lower flammable limit and the flash point of a flammable Hquid are closely related by the Hquid s vapor pressure characteristics. [Pg.96]

Flammable Limits Flammable limits, or the flammable range, are the upper and lower concentrations (in volume percent) which can just be ignited by an ignition source. Above the upper limit and below the lower hmit no ignition will occur. Data are normally reported at atmospheric pressure and at a specified temperature. Flammable hm-its may be reported for atmospheres other than air and at pressures other than atmospheric. [Pg.2313]

In assessing the hazard of a UVCE or in investigating a UVCE it is often necessary to (1) estimate the maximum distance to the lower flammable hmit (LFL) and (2) determine the amount of gas in a vapor cloud above the LFL. Figure 26-31 shows the maximum distance to the lower flammable limit, i.e., in the centerline of the cloud, based on the previous method from Bodurtha (1980) for wind speeds of 1 iti/s (2.2 mi/h) and 5 m/s (11 mi/h). Maximum concentrations probably occur near 1 m/s. The volume of fuel from the LFL up to 100 percent may be estimated by... [Pg.2320]

FIG. 26-31 Estimated maximum downwind distance to lower flammable limit L, percent by volume at ground level in centerline of vapor cloud, vs. continuous dense vapor release rate at ground level. E atmospheric stability. Level terrain. Momentary concentrations for L. Moles are gram moles u is wind speed. (From Bodmtha, 1980, p. 105, by permission.)... [Pg.2320]

Class A—immediately dangerous to life and health based on oxygen level less than 19.5 percent and/or airborne presence of toxic or poisonous substances in concentration constituting IDLH conditions flammabihty up to 20 percent of lower flammable limit. [Pg.2338]

Example 2 LNG Dispersion Tests Britter and McQnaid (1988, p. 70) report on the Burro LNG dispersion tests. Compute the distance downwind from the following LNG release to obtain a concentration equal to the lower flammability limit (LFL) of 5 percent vapor concentration by volume. Assume ambient conditions of 298 K and 1 atm. The following data are available ... [Pg.2345]

Install dilution system to keep flammable concentration below lower flammable limit (LEL)... [Pg.49]

Design ventilation system to keep flammable concentration below lower flammable limit Provide on-line flammable gas detection and activation of inerting system Install automatic sprinkler system Install deflagration vents... [Pg.50]

Upper Flammable Limit (UFL) The highest concentration of a vapor or gas (the highest percentage of the substance in air) that will produce a flash of fire when an ignition source (heat, arc, or flame) is present. See also Lower Flammable Limit. At concentrations higher then the UFL, the mixture is too rich to burn. [Pg.166]

Note 1. When loading volatile products such as gasoline, whose vapor concentration can be shown to rapidly exceed the upper flammable limit during tank filling, the velocity-diameter product may be increased to 0.50 mVs- This is consistent with API RP2003 [3]. Similarly, shorter wait periods of 1-2 min can be used. [Pg.130]

UEL, UPPER EXPLOSIVE (oR FLAMMABLE) LIMIT The maximum concentration of gas, vapour, mist or dust in air at a given pressure and temperature in which a flame can be propagated. [Pg.20]

LPG is considered to be non-toxic witli no chronic effects, but the vapour is slightly anaesthetic. In sufficiently high concentrations, resulting in oxygen deficiency, it will result in physical asphyxiation. The gases are colourless and odourless but an odorant or stenching agent (e.g. methyl mercaptan or dimethyl sulphide) is normally added to facilitate detection by smell down to approximately 0.4% by volume in air, i.e. one-fifth of the lower flammable limit. The odorant is not added for specific applications, e.g. cosmetic aerosol propellant. [Pg.288]


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See also in sourсe #XX -- [ Pg.277 , Pg.278 ]

See also in sourсe #XX -- [ Pg.277 , Pg.278 ]




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