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Fieser

Anlhraquinone-2-su phonic acid. The sodium salt, commonly called silver salt , is used for the preparation of alizarin and 2-aminoanthraquinone and to prepare Fieser s solution. Aminoanthraquinone derivatives are the basis of many dyestuffs. [Pg.37]

Fieser s solution An aqueous alkaline solution of sodium anthraquinone -sulphonale (silver salt) reduced with sodium dithionite, Na2S204, and used as a scrubbing solution for partially removing O2 from, e.g., N2. [Pg.174]

Fieser, L.F., Fieser, M., "Advanced Organic Chemistry", (Reinhold, New York, 1961)... [Pg.290]

L.F. Fieser and M. Fieser, "Reagents for Organic Synthesis" (Vol. I, p, 911) John Wiley and Sons, New York, London, Sydney (1967). [Pg.271]

For several standard procedures no references are given. They can be easily located in M. Fieser and... [Pg.5]

L.F. Fieser, Reagents for Organic Synthesis, Vol 1, Wiley, N.Y., 1967 or standard textbooks. [Pg.5]

Tertiary alcohols are usually degraded unselectively by strong oxidants. Anhydrous chromium trioxide leads to oxidative ring opening of tertiary cycloalkanols (L.F. Fieser, 1948). [Pg.136]

The most commonly used protected derivatives of aldehydes and ketones are 1,3-dioxolanes and 1,3-oxathiolanes. They are obtained from the carbonyl compounds and 1,2-ethanediol or 2-mercaptoethanol, respectively, in aprotic solvents and in the presence of catalysts, e.g. BF, (L.F. Fieser, 1954 G.E. Wilson, Jr., 1968), and water scavengers, e.g. orthoesters (P. Doyle. 1965). Acid-catalyzed exchange dioxolanation with dioxolanes of low boiling ketones, e.g. acetone, which are distilled during the reaction, can also be applied (H. J. Dauben, Jr., 1954). Selective monoketalization of diketones is often used with good success (C. Mercier, 1973). Even from diketones with two keto groups of very similar reactivity monoketals may be obtained by repeated acid-catalyzed equilibration (W.S. Johnson, 1962 A.G. Hortmann, 1969). Most aldehydes are easily converted into acetals. The ketalization of ketones is more difficult for sterical reasons and often requires long reaction times at elevated temperatures. a, -Unsaturated ketones react more slowly than saturated ketones. 2-Mercaptoethanol is more reactive than 1,2-ethanediol (J. Romo, 1951 C. Djerassi, 1952 G.E. Wilson, Jr., 1968). [Pg.165]

Fieser, L. F. Fieser, M. 1959, Steroids, p. 507, Reinhold New York Chapman Hall London Fieser, L. F. Fieser, M. 1959, Steroide, Verlag Chemie Weinheim, Ger. [Pg.367]

The task of relating carbohydrate configurations to names requires either a world class memory or an easily recalled mnemonic A mnemonic that serves us well here was pop ularized by the husband-wife team of Lours F Fieser and Mary Fieser of Harvard Uni versity m their 1956 textbook Organic Chemistry As with many mnemonics it s not clear who actually invented it and references to this particular one appeared m the chem ical education literature before publication of the Fiesers text The mnemonic has two features (1) a system for setting down all the stereoisomeric d aldohexoses m a logical order and (2) a way to assign the correct name to each one... [Pg.1032]

Sets of empirical rules, often referred to as Woodward s rules or the Woodward-Fieser rules, enable the absorption maxima of dienes (Table 7.11) and enones and dienones (Table 7.12) to be predicted. To the respective base values (absorption wavelength of parent compound) are added the increments for the structural features or substituent groups present. When necessary, a solvent correction is also applied (Table 7.13). [Pg.707]

The correlations presented here are sometimes referred to as Woodward s rules or the Woodward-Fieser rules. [Pg.710]

L. F. Fieser andM. Fieser, Reagents for Ofganic Synthesis, Vol. 3,John Wiley Sons, Inc., New York, 1972, p. 147. [Pg.510]


See other pages where Fieser is mentioned: [Pg.364]    [Pg.186]    [Pg.186]    [Pg.120]    [Pg.232]    [Pg.147]    [Pg.118]    [Pg.367]    [Pg.363]    [Pg.323]    [Pg.91]    [Pg.361]    [Pg.425]    [Pg.449]    [Pg.432]    [Pg.140]    [Pg.152]    [Pg.157]    [Pg.409]    [Pg.406]    [Pg.186]    [Pg.186]    [Pg.105]    [Pg.235]    [Pg.118]    [Pg.406]    [Pg.412]    [Pg.478]    [Pg.109]    [Pg.56]   
See also in sourсe #XX -- [ Pg.4 ]

See also in sourсe #XX -- [ Pg.122 , Pg.126 , Pg.268 ]




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Fieser Louis

Fieser Mary

Fieser reagent

Fieser reagent oxidant

Fieser rules

Fieser’s Reagents for Organic

Fieser’s Reagents for Organic Synthesis

Fieser’s reagent

Fieser’s solution

Polyenes (Woodward-Fieser rules)

The Woodward-Fieser Rules for Dienes

Woodward-Fieser

Woodward-Fieser rules

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