Fertilizers borate

Approximately 5% of the U.S. consumption of is in agriculture. Boron is a necessary trace nutrient for plants and is added in small quantities to a number of fertilizers. Borates are also used in crop sprays for fast rehef of boron deficiency. Borates, when apphed at relatively high concentration, act as nonselective herbicides. Small quantities of borates are used in the manufacture of alloys and refractories (qv). Molten borates readily dissolve other metal oxides usage as a flux in metallurgy is an important apphcation. Other important small volume apphcations for borates are in fire retardants for both plastics and ceUulosic materials, in hydrocarbon fuels for fungus control, and in automotive antifreeze for corrosion control (see Corrosion and corrosion inhibitors). Borates are used as neutron absorbers in nuclear reactors. Several borates, which are registered with the Environmental Protection Agency (EPA) can be used for insecticidal purposes, eg, TIM-BOR. 

In rats the oral LDso values for borates are essentially the same as for boric acid they range from 3.16 to 6.08 g/kg." When borax was fed to dogs and rats for 2 years, 3 50 ppm as boron in the diet had no effect. In a three-generation feeding study in rats, 350ppm had no effect on fertility, litter size, weight, or appearance. 

Borax decahydrate occurs in nature as mineral, borax (tincal). It is one of the most common sodium borate ores. The compound has several industrial applications. The refined material is mostly used in household cleaning products. It is used to make pyrex and other horosilicate glasses. Borax is added to fertilizers in small quantities as a source of boron, as a trace nutrient for plants. High purity grade borax is used in cosmetics, toilet products and electrolytic capacitors. It also is used in fire retardants, adhesives and herbicides. 

In addition to borax, which can be applied directly as a fertilizer, special borate products are manufactured for fertilizer use. These include granulated beads for blending with other common fertilizer products and soluble borates for application as liquid foliar sprays. Boron fertilizers are typically applied at a rate equivalent to about one to two pounds elemental boron per acre, depending on the specific crop and soil conditions. As with most fertilizers, excessive application can have adverse results. Borate fertilizers are phyotoxic at high levels and are sometimes used as non-selective herbicides. 

Fertilizers - [AMMONIA] (Vol2) -in bioremediation piOREMEDIATION] (Supplement) -blended [POTASSIUM COMPOUNDS] (Vol 19) -boron in [BORON COMPOUNDS - BORON OXIDES, BORIC ACID AND BORATES] (Vol 4) -cyanamidein [CYANAMIDES] (Vol 7) -lecithin in [LECITHIN] (Vol 15) -molybdenum compounds m [MOLYBDENUM AND COMPOUNDS] (Vol 16) -nitric acid m mfg [NITRIC ACID] (Vol 17) -potassium hydroxide mmfg of [POTASSIUM COMPOUNDS] (Vol 19) -radioactive tracers for [RADIOACTIVE TRACERS] (Vol 20) -role of H2 m production of [HYDROGEN] (Vol 13) -specialty liquid [POTASSIUM COMPOUNDS] (Vol 19) -tanks for [TANKS AND PRESSURE VESSELS] (Vol 23) -use of diatomite m [DIATOMITE] (Vol 8) -use of sulfur for [SULFUR] (Vol 23)... 

CALICHE (Nitrate). The gravel, rock. soil, or alluvium cemented with soluble salts of sodium in the nitrate deposits of the Atacama Desert of northern Chile and Peru. The material contains from 14 to 25% sodium nitrate, 2 to 3% potassium nitrate, and up to I i sodium iodaic. plus some sodium chloride, sulfate, and borate. At one time, this was an important natural fertilizer. 

Diaz-Flores, M., G. Duran-Reyes, and J.J. Hicks. 1994. Arrest of rat embryonic development by the inhibition of gamma-glutamyl transpeptidase. I. Intrauterine administration of L-serine-borate complex. Int J Fertil Menopausal Stud 39 234. 

Both hydrated and anhydrous metal borates have numerous industrial uses. Some of the major uses of hydrated metal borates are the manufacture of glasses, ceramics, and industrial fluids, and as micronutrient fertilizers, fire retardants, and biostats. Anhydrous borates find use as heterogeneous catalysts, scintillation hosts, and in the fabrication of optoelectronic devices. Anhydrous aluminum borates are used as additives in oxide ceramics to promote the formation of desirable phases. Also, aluminum borate whiskers are used as reinforcing additives in composite materials. Specific nses of sodium, calcium, zinc, and barium borates are discussed in sections below. 

The reactions of iridium olefin complexes are not restricted to reactions with phosphines. Amines have also employed in bridge-splitting and substitution reactions with [Ir(COD)Cl]2, especially chelating diamines. The reactions proceed to yield [Ir(COD)N-N]2 compounds. A fertile chemical area involves the irw(pyrazolyl)borate (see Tris(pyrazolyl)borates) family of compounds with the monoethylene and bisethylene complexes serving as reactive entries in this field. ... 

Boron, an element, occurs in many compounds, including borax, borates, boric acid, and carboxyboranes used in glass, ceramics, detergents, bleaches, fire retardants, disinfectants, alloys, specialty metals, preservatives, pesticides, and fertilizers (Mastromatteo and Sullivan 1994). Boron compounds also constitute an important group of dopants in the semiconductor industry. Dopants alter crystalline substrates electrical conductivities in the manufacturing of diodes, transistors, and capacitors (Lewis 1986). 

Borates, molybdates, selenates, and arsenates occur in such trace quantities in soils that they probably exist only as impurities in major soil particles and on particle surfaces rather than as separate minerals. Soils in humid regions sometimes benefit from borate and, less often, molybdate additions. The range between deficient and excess is narrow, so spreading a few kg ha-1 (a few Ibs/acre) uniformly over the soil is difficult unless the borate and molybdate salts are mixed in with other fertilizers or inert materials. 

Boron is an essential trace plant nutrient. Although its exact function has not yet been established, deprivation of boron alfects plant growth and in boron-poor soils, crop yields are diminished. An important application of borax is in borate fertilizers. In contrast, the toxicides of boric acid and borax to animal life are sufficient for them to be used as insecticides,... 

During the 40 years of poly(pyrazolyl)borate chemistry, complexes with group 9 metals have provided a particularly fertile area of research. Over 400 publications describe aspects ranging from the synthesis of homoleptic and heteroleptic coordination compounds to the application of complex organometallic molecules in catalysis, and the development of advanced specialist materials. 

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