Phosphines reactions, with

The reaction with sodium sulfite or bisulfite (5,11) to yield sodium-P-sulfopropionamide [19298-89-6] (C3H7N04S-Na) is very useful since it can be used as a scavenger for acrylamide monomer. The reaction proceeds very rapidly even at room temperature, and the product has low toxicity. Reactions with phosphines and phosphine oxides have been studied (12), and the products are potentially useful because of thek fire retardant properties. Reactions with sulfide and dithiocarbamates proceed readily but have no appHcations (5). However, the reaction with mercaptide ions has been used for analytical purposes (13)). Water reacts with the amide group (5) to form hydrolysis products, and other hydroxy compounds, such as alcohols and phenols, react readily to form ether compounds. Primary aUphatic alcohols are the most reactive and the reactions are compHcated by partial hydrolysis of the amide groups by any water present. 

Synthesis of azindines Irom epoxides via amino alcohols or azido alcohols and reaction with phosphines or phosphites... 

Formation, reaction with phosphines, phosphites, CO and CH3CN 6.5.3.4 i682sB2FeS... 

The reaction with phosphines, which have a primary amino group as a substituent, proceeds in a similar manner. Interaction with carbon... 

In marked contrast to the results of Gassman and Schrock, major differences were noted by Casey and co-workers in a series of studies utilizing phenylcarbene-substituted W(0) complexes in reactions with olefins. The H NMR spectra of new phenylcarbene tungsten and iron (69) complexes indicate a substantial positive charge residing on the carbene carbon, and as expected, these complexes readily form ylides on reaction with phosphines ... 

A general summary of the chemistry of H4Os4(CO)12 is given in Scheme 10 (159, 166). Substitution reactions with phosphine, phosphites, or pyridine have been observed. An addition reaction occurs with I2 to yield the anionic species [H3Os4(CO)12I] The X-ray structure of this anion has established that the iodide is bridging between two metal centers, to yield an Os4 "butterfly configuration in which one of the metal- metal bonds of the initial Os4 tetrahedron has been broken (Os-Os = 3.817 A) (Fig. 38). Interestingly, if the two Os-1... 

C NMR spectra, 29 188-189 structures, 29 207-208, 218 with copper, 29 202, 204, 206 fluxionality, 29 226 with manganese, 29 210 mass spectra, 29 190 MO calculations, 29 197 with molybdenum, 29 189 with nickel, 29 176, 179 reaction with phosphines, 29 229 structures, 29 210, 215, 221-222 photoelectron spectra, 29 193 with ruthenium structure, 29 218 synthesis, 29 229-230 structures, 29 210, 213-214 with tungsten, 29 189... 

Pentadecacarbonylpentaruthenium carbide oxidative addition reactions, 30 206 reaction with phosphines and diphosphines, 30 191... 

The dinuclear structure (340) is broken up by N donors which give mononuclear octahedral complexes [Ni(RCOS)2B2] (B = py, substituted pyridines, bipy).2478-2480 On the other hand the same dinuclear complexes are transformed into square planar complexes [Nil BJ by the reaction with phosphines.2481... 

---