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Experimental measurements using

Ultraviolet photoelectron spectroscopy allows the determination of ionization potentials. For thiazole the first experimental measurement using this technique was preformed by Salmona et al. (189) who later studied various alkyl and functional derivatives in the 2-position (190,191). Substitution of an hydrogen atom by an alkyl group destabilizes the first ionization potential, the perturbation being constant for tso-propyl and heavier substituents. Introduction in the 2-position of an amino group strongly destabilizes the first band and only slightly the second. [Pg.51]

Chapter 10, the last chapter in this volume, presents the principles and applications of statistical thermodynamics. This chapter, which relates the macroscopic thermodynamic variables to molecular properties, serves as a capstone to the discussion of thermodynamics presented in this volume. It is a most satisfying exercise to calculate the thermodynamic properties of relatively simple gaseous systems where the calculation is often more accurate than the experimental measurement. Useful results can also be obtained for simple atomic solids from the Debye theory. While computer calculations are rapidly approaching the level of sophistication necessary to perform computations of... [Pg.686]

These equations contain only one unknown parameter, kiAj. Assume values for it and solve Equations (11.20) and (11.21) simultaneously. Compare the calculated results with the experimental measurements using nonlinear least-squares analysis as in Equation (7.8). This is the preferred, modern approach, but the precomputer literature relied on computationally simpler methods for fitting kiAj. [Pg.398]

Modelling Approach Establish a model and design experiments to determine the model parameters. Compare the model behaviour with the experimental measurements. Use the model for rational design, control and optimisation. [Pg.4]

Also experimentally measured using other conditions. See Elschenbroich et al.5<... [Pg.344]

In the Lagrangian frame, droplet trajectories in the spray may be calculated using Thomas 2-D equations of motion for a sphere 5791 or the simplified forms)154 1561 The gas velocity distribution in the spray can be determined by either numerical modeling or direct experimental measurements. Using the uncoupled solution approach, many CFD software packages or Navier-Stokes solvers can be used to calculate the gas velocity distribution for various process parameters and atomizer geometries/configurations. On the other hand, somesimple expressions for the gas velocity distribution can be derived from... [Pg.369]

In this chapter we describe the elastic scattering of positrons by atoms and molecules over the kinetic energy range from zero to several keV, concentrating mainly on the angle-integrated cross section, crei- However, reference is also made to differential cross sections, dae /dQ, which have recently become amenable to experimental measurement using crossed gas and positron beams. [Pg.94]

The frictional and adhesion forces between the abrasive particles and wafer surfaces were experimentally measured using alumina and silica slurries with and without citric acid. Although citric acid did not affect the zeta potential of the silica particles, it resulted in a more negative zeta potential of the alumina particles due to the adsorption of the negatively charged citrate ions onto the alumina surfaces. The highest particle adhesion force was measured in an alumina slurry without the addition of citric acid. However, the alumina slurry with the addition of citric acid had the lowest particle adhesion force due to the adsorption of citrate ions onto the alumina surfaces. Although citrate ions could easily adsorb onto alumina particles, the silica particles did not appear to benefit in terms of reduced frictional force when in citric acid solutions. [Pg.498]

Solubility is a complex property, and this complexity confounds our ability to develop computational models to predict it. Most computational solubility models are empirical QSPR models, trained on solubility data sets either sourced from the literature and corporate databases or generated specifically for the purposes of modeling. Hence, it is not surprising that the quality of the computational model depends on the quality of the data set of experimental measurements used to train the model. [Pg.56]

Numerical values of Aa i and Aai2 are obtained from integration of the experimental measurements using the definition of the first and second moments. [Pg.292]

Figure 14.6 Electron density in silicon, (a) A contour plot of experimental measurements using the electron scattering (b) theoretical results found using the linear augmented plane wave (tAPW) method and density functionals (c) calculations using generalized-... Figure 14.6 Electron density in silicon, (a) A contour plot of experimental measurements using the electron scattering (b) theoretical results found using the linear augmented plane wave (tAPW) method and density functionals (c) calculations using generalized-...
The average absorption and scattering cross-sections Cabs,x and Csca, i of microorganisms suspensions can be experimentally measured using a spectrometer equipped with an integrating sphere. Pint, the spectral normal-normal T j and normal—hemispherical T f, transmissions of several dilute suspensions with different known concentrations are measured, as illustrated in Fig. 5. Here, the scattering phase function Or (0) previously measured for the same suspension is used to correct for various optical effects. [Pg.128]

PRO has seen significant progress in the past few years, mainly thanks to the development of better and better membranes. However, experimental activity has been so far mostly limited to laboratory-scale testing of commercially available RO and FO membranes [6,7, 13,14] or prototype lab-cast membranes [12,15,16]. In particular, experiments have been reported where commercial FO spiral-wound modules were used the maximum power densities reported as inferred from experimental measurements, using seawater-equivalent as the concentrated stream, are 0.5 W/m in a commercially available spiral-wound module [14] and 3.5 W/m with a prototype, lab-cast TFC membrane [12]. [Pg.277]

Besides the calculation using Eqn (6.25), this collection efficiency can also be experimentally measured using a simple reaction such as [FedllKCNig] + e - [Fe(II)(CN)6] . The detailed calibration of the RRDE collection efficiency will be given in the following section. [Pg.209]

FIGURE 19.7. Interfacial activity in a Type I blend of an A-B diblock copolymer added to a blend of A and B homopolymers [A = SPB(89) and B = SPB(63)]. A/a = 4,230 and A/b = 3,600 for the homopolymers, while A/Ab = 790 and Nsb = 730 for the block copolymer. Symbols show experimental measurements using secondary-ion mass spectrometry (SIMS), and curves show SCFT predictions using x and / values from Tables 19.1 and 19.2. (a) Volume fraction profile in loglinear format of the diblock copolymer for a sample with 0.07 volume% block copolymer with an A/B interface at z = 190 nm. (b) Volume fraction profile in linear-linear format of the diblock copolymer for a sample with 0.07 volume% block copolymer with an A/B interface at z = 190 nm. The cross-hatched area represents the adsorbed amount, F. (c) Adsorption isotherm the dependence of the adsorbed amount, r, on the copolymer volume fraction in the A-rich phase ab/a- (d) The thickness of the adsorbed layer (standard deviation of the volume fraction profile near the peak), a, plotted versus the amount adsorbed, F. [Pg.347]

Figure 8.1 Simple visualization of meanings of accuracy and precision in experimental measurements, using darts thrown at a dartboard as an analogy in which the center of the dartboard represents the true value, (a) Good precision, low accuracy, (b) Poor precision, poor accuracy, (c) Good accuracy and precision, (d) Poor precision, and therefore accuracy is indeterminate (quantitative statistical evaluation is essential). Figure 8.1 Simple visualization of meanings of accuracy and precision in experimental measurements, using darts thrown at a dartboard as an analogy in which the center of the dartboard represents the true value, (a) Good precision, low accuracy, (b) Poor precision, poor accuracy, (c) Good accuracy and precision, (d) Poor precision, and therefore accuracy is indeterminate (quantitative statistical evaluation is essential).
Complete cladding failure leading to agglomeration of fuel pellets in the bottom of the canister 1 referred to as a fuel slump. The assumed volume fraction of fuel pellets In the slumped fuel region was 0.532 based on experimental measurements using standard Westinghouse fuel pellets... [Pg.671]

Experimental Measurements using Friction Force Microscopy... [Pg.286]


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Absorption, experimental system used measurements

Experimental measurement

Experimental use

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