Expansion Exposure

A recently introduced polycarbonate-based blend offers a low coefficient of thermal expansion. This new thermoplastic is designed for large sheet applications such as doors or siding. Its high dimensional stability will eliminate warping from exposure to varying temperatures. 

Radiation Effects. Alpha sihcon carbide exhibits a small degree of anisotropy in radiation-induced expansions along the optical axis and perpendicular to it (58). When diodes of sihcon carbide were compared with sihcon diodes in exposure to kradiation with fast neutrons (59), an increase in forward resistance was noted only at a flux about 10 times that at which the increase occurs in a sihcon diode. In general, it appears that sihcon carbide, having the more tightly bound lattice, is less damaged by radiation than sihcon. 

Monolithic refractory coatings have been applied to metallic components in furnaces for fuel ash corrosion control. Results have been less than satisfactory because of the large thermal expansion mismatch between the metal and refractory. Failure usually occurs upon thermal cycling which causes cracking, eventual spalling of the refractory, and direct exposure of the metal to the effects of the fuel ash. 

In cases where vessels are provided with PR valves for protection against overpressure from fire exposure or an operating failure contingency, additional thermal expansion protection is not required. 

Each input source is protected by a PSV set no higher than the maximum allowable working pressure of the vessel, and a PSV is installed on the vessel for fire exposure and thermal expansion. 

Paint failure is related to climatic conditions, and the weather prevailing during application of the paint and during subsequent exposure will determine the life of the paint system. This applies, of course, particularly to outdoor work. In unfavourable weather conditions, cracking and blistering can be promoted as a consequence of the expansion of the products of corrosion, and in the case of iron and steel this can lead to under-rusting. 

The preferred brine circuit is that shown in Figure 12.5, and having the feed and expansion tank out of the circuit, which is otherwise closed. This avoids entrainment of air and too much surface exposure. The same arrangement can be used with the divided storage tank shown in Figure 12.6, except that the tank will be enclosed, with a separate feed and expansion tank. 

Many of the non-aqueous solvents used must be protected from exposure to the air, and titrations with such materials must be conducted in a closed vessel such as a three- or four-necked flask. It must also be noted that organic solvents have much greater coefficients of thermal expansion than has water, and every effort must therefore be made to ensure that all solutions are kept as nearly as possible at constant temperature. 

The next step in the design procedure is to select the materials. The considerations are the physical properties, tensile and compressive strength, impact properties, temperature resistance, differential expansion environmental resistance, stiffness, and the dynamic properties. In this example, the only factor of major concern is the long-term stiffness since this is a statically loaded product with minimum heat and environmental exposure. While some degree of impact strength is desirable to take occasional abuse, it is not really subjected to any significant impacts. 

---