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Ethylene, chlorination reaction, with butadiene

The reaction of olefinic compounds with chlorine whereby addition takes place at the double bond has been known for some time. Ethylene dichloride and propylene dichloride are produced by reaction of ethylene or propylene with chlorine (27). A number of articles (23, 24, 31), which review the methods of production of ethylene dichloride, are available. The manufacture of dichloropropane in Germany by reaction of propylene with chlorine in the presence of light was reported by Sergeys (68). High yields of dichlorobutene may be obtained by the vapor phase chlorination of butadiene (73). [Pg.382]

SULFUROUS OXIDE (7446-09-5) SO, Noncombustible liquefied gas under pressure or liquid. Contact with air forms hydrogen chloride fumes. Violent reaction with water or steam, forming sulfurous acid, a medium-strong acid and corrosion hazard. Reacts violently with acetylene, acrolein, alcohols, aluminum powder alkali metals (i.e., potassium, sodium) amines, ammonia, bromine pentafluoride butadiene caustics, cesium acetylene carbide chlorates, chlorine trifluoride chromium powder copper or copper alloy powders chlorine, diethylzinc, fluorine, ethylene oxide lead dioxide lithium acetylene carbide diamino-, metal powders monolithium acetylide-ammonia nitryl chloride potassium acetylene carbide potassium acetylide, potassium chlorate rubidium carbide silver azide sodium acetylide staimous oxide. Decon oses in... [Pg.981]

Additionally to the procedures described earlier, improvements for thermostabilization is copolymerisation of vinyl chloride with suitable monomers. A great number of monomers were investigated to optimize the properties of resins. But only vinyl acetate, vinylidene chloride, ethylene, propylene, acrylonitrile, acrylic acid esters, and maleic acid esters, respectively, are of interest commercially [305,436,437]. The copolymerization was carried out in emulsion, suspension, and solution in connection with water- or oil-soluble initiators, as mentioned elsewhere. Another possibility for modifying PVC is grafting of VC on suitable polymers [305,438], blends of PVC with butadiene/styrene and butadiene/ methacryl acid esters copolymers [433], and polymer-analogous reactions on the macromolecule [439,440] (e.g., chlorination of PVC). [Pg.201]

See other pages where Ethylene, chlorination reaction, with butadiene is mentioned: [Pg.908]    [Pg.870]    [Pg.908]    [Pg.230]    [Pg.231]    [Pg.232]    [Pg.233]    [Pg.323]    [Pg.748]    [Pg.768]    [Pg.773]    [Pg.782]    [Pg.976]    [Pg.981]    [Pg.981]    [Pg.982]    [Pg.826]    [Pg.862]    [Pg.877]    [Pg.484]    [Pg.880]    [Pg.464]    [Pg.369]    [Pg.866]    [Pg.59]    [Pg.866]    [Pg.77]    [Pg.211]    [Pg.2208]    [Pg.238]    [Pg.1]    [Pg.353]    [Pg.463]    [Pg.120]    [Pg.227]    [Pg.394]    [Pg.87]   
See also in sourсe #XX -- [ Pg.362 , Pg.363 ]



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1,3-Butadiene chlorination

Butadiene reaction with

Butadiene reactions

Butadiene, reaction with ethylene

Chlorinated butadiene

Chlorination reactions

Chlorination reactions with

Chlorine reaction with ethylene

Chlorine reactions

Chlorins reactions

Ethylene chlorination

Ethylene reaction with

Ethylene reactions

Ethylene with butadiene

Ethylene, chlorination with chlorine

Reaction with chlorine

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