N-Hexyl ethyl ether

Place 204 g. (249-5 ml.) (2 gram mols) of dry n-hexyl alcohol in a 350 ml. Claisen flask with fractionating side arm. Introduce 5-75 g. (0-25 gram atoms) of clean sodium in small pieces and warm under reflux (as in Fig. Ill, 58, 1 but with dropping funnel omitted ) until all the sodium has reacted (ca. 2 hours). Introduce 39 g. (20 ml.) (0-25 gram 

9pcI6HEXYL ethyl ETHER Prepare 15 5 g. of molecular sodium (granulated sodium) under xylene (Section II,50,d) Fig. Ill, 68,1. replace the xylene completely by 100 ml. of 

Finally distil from a well-lagged Widmer dask (compare Figs. II, 24, 2-5) over a little sodium. Collect the cycZo-hexyl ethyl ether at 148-150°. The yield is 21 g. If the sodium is appreciably attacked, repeat the distillation from a fresh quantity of sodium. 

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UDMH is known to be miscible with the following wafer, benzene, triethyl benzene, toluene, kerosene, ethyl alcohol, isobutyl alcohol, n-butyl ether, n-amyl ether, n-hexyl ether, diethyl ether, petroleum ether, petroleum naphtha, n-heptane, n-hexane, n-octane, n-decane, n-dodecane, n-hexadecane, cyclohexane, 1,2-dimethyl cyclohexane, phenyl cyclohexane, n-tetradecane, trichloroethylene, dichloroethylene, perchloroethylene, 1,1,1-trichloroethane, triethyl amine, ethylenediamine, diethylene triamine, acetonitrile, aniline, cumene, tetra-hydronaphthalene, tetraethylene pentamine, ethylene glycol and hydrazine (Ref 4)... 

Methyl n-amyl carbinol. 247, 254 Methyl n-amyl ketone, 482 Methylaniline (mono), pure, from commercial methylaniline, 562, 570 P-Methylanthraquinone, 728, 740 Methyl benzoate, 780, 781 p-Methyl benzyl alcohol, 811,812 Methyl benzyl ketone, 727, 735 Methyl y-bromocrotonate, 926, 927 2-Methyl-2-butene, 239 Methyl n-butyl carbinol, 247,255 Methyl n-butyl ether, 314 Methyl n-butyl ketone, 475, 481 4-Methylcarbostyril, 855 p-Methylcinnamic acid, 719 4-Methylcoumarin, 853, 854 Methyl crotonate, 926, 927 Methylethylacetic acid, 354, 358 Methylethylethynyl carbinol, 468 Methyl ethyl ketone, 335, 336 purification of, 172 Methyl n-hexyl ether, 314 Methyl n-hexyl ketone, 335, 336 Methyl n-hexyl ketoxime, 348 Methyl hydrogen adipate, 938 Methyl hydrogen sebacate, 938,939 4-Methyl-7-hydroxycoumarin, 834 Methyl iodide, 287 Methyl isopropyl carbinol, 247,255 Methyl 4-keto-octanoate, 936... 

Ethanol, 2-(ethyl (4-((6-methoxy-3-methyl-2-benzothiazolium) azo) phenyl) amino)-, methyl sulfate. See Basic blue 41 Ethanol, 2-(ethyl phenyl ami no)-. See Phenylethylethanolamine Ethanol, 2-(N-ethyl-m-toluidino)-. See N-Ethyl-N-hydroxyethyl-m-toluidine Ethanol, 2-(hexadecyloxy)-. See Ceteth-1 Ethanol, 2-((2-hexyloxy)ethoxy)-. See Diethylene glycol n-hexyl ether Ethanol, 2-(hexyloxy)-, hydrogen phosphate, compd. with N-ethylethanamine (1 1). See Phosphoric acid, bis (2-hexyloxyethyl) ester, diethylamine salt... 

Hexanehexol. See D-Mannitol 6-Hexanelactam. See Caprolactam Hexane, 1-methoxy-. See Methyl hexyl ether Hexane, 1,1 -oxybis-. See n-Hexyl ether Hexane, 1,1 -oxybis (2-ethyl)-. See Di (2-... 

Plgvire 1. Partition of uranyl nitrate between water and simple ethers, o, diethyl ether. A, ethyl-n-propyl ether. , ethyl-n-butyl ether. V, dl-lsopropyl ether. , dl-n-butyl ether. A, dl-n-hexyl ether. , 2,2 -dlchlorethyl ether. 

I, //-hexane 2. benzene 3, pyridine 4, acetone 5, diethyl ether 6, ethyl acetate 7, nitromethane 8, methyl alcohol 9, n-hexyl alcohol 10. bromine 11. 50% chromic acid 12, Nain liq. NR, 13, stannic chloride 14, sulfur chloride. 

N-Alkylation of 3-aroylindole 97 carried out at 80 °C with alkyl halides from ethyl through -hexyl, gives mixtures of products 98 and 99 in yields of 41-90% (Equation 15) <1998JOC4510>. In addition to the expected N-alkylated indoles 98, a substantial fraction of the product was formed by additional replacement of the methoxy group by an alkoxy group. The reaction is very temperature dependent, since a decrease of only 5 °C completely suppresses the formation of the 0-alkylation products with the ethyl or -propyl halide. However, -hexyl bromide provided a 75% yield of hexyl ether 99 under these conditions. 

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