Equation at the interface

On the other hand, the fluctuations due to reactions are controlled by the rate equation at the interface,... 

To evaluate the equilibrium relations requires the computation of the K values. The pure component vapor pressures may be estimated from the Antoine equation. At the interface temperature the vapor pressures are... 

The kinetic equation at the interface itself remains the same as (21). 

Since the kinetic equation at the interface is identical to the one in the absence of salt, so is the expression for the corresponding time scale. However, in the case of added salt the electrostatic interactions are screened, the surface potential is much smaller than Tje, and, therefore, the kinetic time scale, Tk, is only slightly larger than the non-ionic one [Eq. (10)]. 

Let us ensure that by changing the initial concentration of the BC alloy, one can control the phase composition of the diffusion zone. We proceed from the flux balance equations at the interfaces t) p, p — y, and y — a ... 

Given that in conductive media in the absence of polarization, it is impossible to introduce electrical and magnetic fields at the interface and which are nonnull, it follows that the tensors 4Maxwell equations at the interface are obtained by way of two relations ... 

With the classic variables of time and space, these equations give us the Maxwell equations at the interface ... 

Chapter 4 is given over to heterogeneous media in the presence of an electromagnetic field. In that chapter, the balance equations at the interfaces are established. 

Substituting du to the force balance equation at the interface gives as follows ... 

For a circular capillary, the Young-Laplace equation at the interface can be written as... 

Gas spectra excited by EWs can also be influenced by atoms which are adsorbed on the surface. The adsorbate overlayer determines the boundary conditions for Maxwell s equations at the interface and, therefore, also the EW amplitude in the gas. As a result, the gas optical spectra which depend on the EW intensity, contain indirectly information about the adsorbed layer. In particular, the atoms adsorbed on the surface are polarized by the exciting field,... 

As already mentioned, boundary conditions for the dependent variables of the transport equations at the interfaces between different layers of the same domain are not required. At the gas channel entries, conditions of the first kind have to be prescribed for the gas mixture velocities, pressures, temperatures, and component concentrations. At the interfaces between the gas channels and the plate collectors, boundary conditions of the first kind have to be prescribed for the gas mixture velocity components (no slip condition) and for the temperature if the temperature of the cooling (heating) agent is known, or boundary conditions of the second kind are prescribed if the wall is adiabatic. 

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