Engineering thermoplastics polycarbonates

Bottenbruch, L. (ed) Engineering Thermoplastics Polycarbonates, Polyacetals, Polyesters, Cellulose Esters. (1996) Hanser Gardner Publications, Cincinnati,... 

To further investigate the question of polymer structure-permeability relationships, this study reports oxygen permeability measurements on a group of structurally varied bisphenol based polymers. In addition to representing commercially important classes of engineering thermoplastics, polycarbonates, polyarylates and polyetherimides can be easily prepared from a common set of... 

Bottenbruch L, editor. Engineering thermoplastics polycarbonates— polyacetals—polyesters— cellulose esters. NY Hanser 1996. 

Triphenyl phosphate [115-86-6] C gH O P, is a colorless soHd, mp 48—49°C, usually produced in the form of flakes or shipped in heated vessels as a hquid. An early appHcation was as a flame retardant for cellulose acetate safety film. It is also used in cellulose nitrate, various coatings, triacetate film and sheet, and rigid urethane foam. It has been used as a flame-retardant additive for engineering thermoplastics such as polyphenylene oxide—high impact polystyrene and ABS—polycarbonate blends. 

Color/Transparency. Almost all amorphous engineering thermoplastics, except PC and some polyester carbonates, are inherently colored. Even polycarbonates have yellowness indexes (YI) (36) of 0.1 to 5.0. Colorless material is produced from these resins by compounding with complementary blue dyes which reduce transmission. Ha2e in amorphous resins is an indication of particulates. Ha2e reduces optical clarity and transmission. 

Good electrical insulation properties with exceptional tracking resistance for an engineering thermoplastic and, in particular, for an aromatic polymer. In tracking resistance most grades are generally superior to most grades of polycarbonates, modified PPOs, PPS and the polyetherimides. 

Many engineering thermoplastics (e.g., polysulfone, polycarbonate, etc.) have limited utility in applications that require exposure to chemical environments. Environmental stress cracking [13] occurs when a stressed polymer is exposed to solvents. Poly(aryl ether phenylquin-oxalines) [27] and poly(aryl ether benzoxazoles) [60] show poor resistance to environmental stress cracking in the presence of acetone, chloroform, etc. This is expected because these structures are amorphous, and there is no crystallinity or liquid crystalline type structure to give solvent resistance. Thus, these materials may have limited utility in processes or applications that require multiple solvent coatings or exposures, whereas acetylene terminated polyaryl ethers [13] exhibit excellent processability, high adhesive properties, and good resistance to hydraulic fluid. 

This class of polyesters consists of four major commercial polymers and their copolymers, namely PET, PTT, PBT, and PEN (see Table 2.1). They compete for engineering thermoplastics, films, and fibers markets with other semicrystalline polymers, such as aliphatic polyamides, and for some other applications with amorphous engineering plastics such as polycarbonate. The syntheses of PET and PBT, detailed in numerous reviews and books,2-5 are described in Sections 23.2.2 and 2.3.2.1. 

Engineering thermoplastics such as acrylics (PMMA), polyamides and polycarbonates are only used for specific properties. 

Mixed esters, such as isopropylphenyl diphenyl phosphate and tcrt-butylphenyl diphenyl phosphate, are also widely used as both plasticizers/flame retardants for engineering thermoplastics and hydraulic fluids.11 These esters generally show slightly less flame-retardant efficacy, when compared to triaryl counterparts however, they have the added advantage of lower smoke production when burned. Some novel oligomeric phosphate flame retardants (based on tetraphenyl resorcinol diphosphate) are also employed to flame retard polyphenylene oxide blends, thermoplastic polyesters, polyamides, vinyls, and polycarbonates. 

Although polycarbonate is an engineering thermoplastic material which provides high toughness, flexibility and thermal stability, it suffers from certain limitations due to poor chemical resistance and low flow characteristics in injection moulding. These shortcomings can be circumvented by blending PC... 

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