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Emulsifiable oils

Detergents may be produced by the chemical reaction of fats and fatty acids with polar materials such as sulfuric or phosphoric acid or ethylene oxide. Detergents emulsify oil and grease because of their abiUty to reduce the surface tension and contact angle of water as well as the interfacial tension between water and oil. Recent trends in detergents have been to lower phosphate content to prevent eutrification of lakes when detergents are disposed of in municipal waste. [Pg.135]

Surfactants. Surfactants (qv) perform a variety of functions in a drilling fluid. Depending on the type of fluid, a surfactant may be added to emulsify oil in water (o/w) or water in a nonaqueous Hquid (w/o), to water-wet mud soHds or to maintain the soHds in a nonwater-wet state, to defoam muds, or to act as a foaming agent. [Pg.182]

Phenomena at Liquid Interfaces. The area of contact between two phases is called the interface three phases can have only aline of contact, and only a point of mutual contact is possible between four or more phases. Combinations of phases encountered in surfactant systems are L—G, L—L—G, L—S—G, L—S—S—G, L—L, L—L—L, L—S—S, L—L—S—S—G, L—S, L—L—S, and L—L—S—G, where G = gas, L = liquid, and S = solid. An example of an L—L—S—G system is an aqueous surfactant solution containing an emulsified oil, suspended soHd, and entrained air (see Emulsions Foams). This embodies several conditions common to practical surfactant systems. First, because the surface area of a phase iacreases as particle size decreases, the emulsion, suspension, and entrained gas each have large areas of contact with the surfactant solution. Next, because iaterfaces can only exist between two phases, analysis of phenomena ia the L—L—S—G system breaks down iato a series of analyses, ie, surfactant solution to the emulsion, soHd, and gas. It is also apparent that the surfactant must be stabilizing the system by preventing contact between the emulsified oil and dispersed soHd. FiaaHy, the dispersed phases are ia equiUbrium with each other through their common equiUbrium with the surfactant solution. [Pg.234]

Emulsified oil contains a Hquid film so that it will not separate by gravity without first breaking the emulsion. This is achieved by adding surfactants, emulsion breaking polymers or coagulants. After the emulsion is broken, the conventional technologies described above are appHcable. [Pg.182]

Cleaners. Cleaner formulations can be classified with respect to the abiUty to emulsify oils, keep them in solution or to reject oils, spHt them out of solution. The latter type loosens the oil, and the separated oil does not dissolve but is rejected, and usually floats to the top of the cleaner solution. For the cleaner that rejects oil, the tank needs to be skimmed constantly. This is most easily accompHshed usiag the overflow weir, sump, and recirculating pump arrangement. OH-rejecting cleaners last longer. [Pg.149]

UF is widely used to concentrate oil-in-water emulsions, the by-produc t of many metal-workiug applications, because the membrane retains stable emulsified oil while the water and the veiy low concen-... [Pg.2038]

When the primary target is oil removal, we should distinguish between the forms of oil. There are two forms of oil that we find in wastewater. Free oil is oil that will separate naturally and float to the surface. Emulsified oil is oil that is held in suspension by a chemical substance (Detergents - Surfactants) or electrical energy. When making an evaluation, free oil will normally separate by gravity and float to the surface in approximately 30 minutes. Emulsified oil is held in a molecular... [Pg.318]

A eoaleseer aehieves separation of an oily phase from water on the basis of density differences between the two fluids. These systems obviously work best with non-emulsified oils. Applications historically have been in the oil and gas industry, and hence the most famous oil/water separator is the API separator (API being the abbreviation for the American Petroleum Institute). [Pg.323]

Finally, to evaluate the membranes, analysis such as X-ray diffraction (XRD), SEM, TEM and light scattering were performed at the School of Mineral and Material Engineering, Universiti Sains Malaysia. The last part of the work, testing the produced membrane to remove emulsifier oil from domestic wastewater, was accomplished on a limited budget. An experimental rig and membrane module were required. Also the need for experimental data for the application of the supported membrane may show the real success of this project. [Pg.385]

Pollutant parameters and their concentrations found in the oily waste subcategory streams are shown in Table 9.9. The oily waste subcategory for the metal finishing industry is characterized by both concentrated and dilute oily waste streams that consist of a mixture of free oils, emulsified oils, greases, and other assorted organics. Applicable treatment of oily waste streams is dependent on the concentration levels of the wastes, but oily wastes normally receive specific treatment for oil removal prior to solids removal waste treatment. [Pg.354]

Because emulsified oils and processes that emulsify oils are used extensively in the metal finishing industry, the exclusive occurrence of free oils is nearly nonexistent. [Pg.369]

One of the most important advantages of the bio-based processes is operation under mild conditions however, this also poses a problem for its integration into conventional refining processes. Another issue is raised by the water solubility of the biocatalysts and the biocatalyst miscibility in oil. The development of new reactor designs, product or by-product recovery schemes and oil-water separation systems is, therefore, quite important in enabling commercialization. Emulsification is thus a necessary step in the process however, it should be noted that highly emulsified oil can pose significant downstream separation problems. [Pg.6]

Emulsifiable oil metal-working fluids, 1 22 Emulsification, 10 126 16 211 cosmetics, 7 837-841 hydrophobic-monomer, 14 717 Emulsified wax, in paper manufacture,... [Pg.313]

Annex II lists foodstuffs for which only certain of the annex I additives may be used. Such foodstuffs include cocoa products and chocolate products, fruit juices and nectars, jam, jellies and marmalades and partially dehydrated and dehydrated milk, which are the subjects of EU vertical standards, and a number of other foods including frozen unprocessed fmit and vegetables, quick-cook rice, non-emulsified oils and fats, canned and bottled fruit and vegetables, bread made with basic ingredients only, fresh pasta and beer. [Pg.21]


See other pages where Emulsifiable oils is mentioned: [Pg.84]    [Pg.133]    [Pg.10]    [Pg.261]    [Pg.261]    [Pg.298]    [Pg.535]    [Pg.2043]    [Pg.506]    [Pg.96]    [Pg.101]    [Pg.281]    [Pg.317]    [Pg.318]    [Pg.322]    [Pg.346]    [Pg.129]    [Pg.241]    [Pg.650]    [Pg.672]    [Pg.819]    [Pg.346]    [Pg.681]    [Pg.506]    [Pg.111]    [Pg.216]    [Pg.280]    [Pg.282]    [Pg.731]    [Pg.60]    [Pg.148]    [Pg.353]    [Pg.132]    [Pg.376]    [Pg.147]    [Pg.243]    [Pg.416]   
See also in sourсe #XX -- [ Pg.692 ]




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