Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

DRIFTS, analytical method Applications

Methods to determine the a.i., and/or relevant metabolites in air during or shortly after the application must be submitted unless it can be justified that exposure of operators, workers, or bystanders does not occur. In SANCO/825/00 it is stated that spray drift and particle-associated as well as gaseous substances have to be taken into consideration because both can cause relevant exposure of operators, workers, or bystanders. Therefore, an analytical method must also be submitted for relevant substances with a low vapor pressure (< 10-5 Pa). [Pg.31]

Lignocellulosic material can also be analyzed by IR spectrometry. This analytical method was used for characterization of modified lignin and cellulose in various ways <>. Quantification by infrared spectrometry has been reported, for example, in analysis of the three basic constituents in sweet gum and white oak chips pretreated at temperatures ranging from 140 to 280 C. > using the diffuse reflectance FTIR spectrometry (DRIFT). The technique is simple and applicable to powdered solids and dark samples and... [Pg.139]

Selectivity and versatility of measnrements have been enhanced through the use of a range of ion sources operated at ambient pressure and easily combined with drift tubes. Techniques to measure samples as liquids and solids, not only gases, have been incorporated significantly into IMS technology during the past decade and have transformed IMS from a vapor analyzer with niche applications to a measurement technique broadly applicable to semivolatile or nonvolatile substances. Indeed, a reason for the increase in visibility of mobility spectrometry as an analytical method is the combination of electrospray ionization (ESI) with drift tubes and the combination of mobility analyzers with mass spectrometers. This combination of ESI-IMS-MS with drift tnbes at ambient pressure and at reduced pressures of... [Pg.5]

Anions have also been determined using conventional IMS with an FSI ion source and included arsenate, phosphate, sulfate, nitrate, nitrite, chloride, formate, and acetate. Distinct peak patterns and reduced mobility constants were observed for respective anions. Application to authentic water samples for the determination of nitrate and nitrite demonstrated the feasibility of using FSI-IMS as a rapid analytical method for monitoring nitrate and nitrite in water systems. The method was used for on-site measurement by exchanging air for nitrogen as the drift gas without complications. The linear dynamic range was 1,000, and detection limits were 10 ppb for nitrate and 40 ppb for nitrite. [Pg.358]

The advantages of point analyzers include a high level of analytical performance and a record of service that is unparalleled in some facets. StiU, the record or evidence is that drift tube refinements or developments of fast analytical devices based on IMS or DMS will be continued into the foreseeable future. The need for improvements in minimization of false positives, false negatives, and matrix interferences is a significant concern and innovations in inlet methods or improved analytical separation can be anticipated. Several questions about IMS loom on the horizon of application-technology as seen by the authors and these include ... [Pg.198]

Consideration of the analyses performed on the 8-channel and both models of the 12-channel Technicon equipment in relation to the earlier discussion means that these latest developments in the field of Auto-Analyzer instrumentation demand standardized sera for calibration purposes. In fact, the successful operation of the SMA-12 instrument is entirely dependent upon the careful analysis and subsequent stability of the standardizing serum, since this is used both for the initial calibration of the various analytical channels and for the subsequent monitoring for drift and application of any correction needed as a result of instrumental drift. Apart from this large demand for standardizing serum (about 70 ml in an 8-hour day), the performance of the SMA-12 should in addition be checked by means of control sera, as for any other method or combination of methods in clinical chemistry. The expense of the standardizing (and to a lesser extent the control) sera used in SMA-12 operation constitutes an important but nevertheless essential fraction of the operating costs of these instruments. [Pg.88]

Standard addition calibration is more robust and reliable than conventional external calibration, but is more time consuming and costly if it is applied separately for each sample. A major advantage of standard addition is the correction of multiplicative matrix effects, for example alteration of nebuli-sation efficiency. The intensities of all samples (and spiked samples) change by the same factor, which leads to an altered cahbration slope. However, for additive effects, such as interferences caused by the matrix, the calibration line is shifted parallel and the intercept changes, which results in biased analyte concentrations. In some cases, this bias can be avoided (or indeed identified) by choosing another isotope and comparing the results for each. Standard addition has no inherent compensation for instrumental drift in the ICP-MS system. However, reduction of the drift, whieh limits the applicability of standard addition for ICP-MS, has been achieved by applying a chemometric method (a bracket approach, where the spiked sample is measured between two different measurements of the sample). ... [Pg.43]


See other pages where DRIFTS, analytical method Applications is mentioned: [Pg.982]    [Pg.21]    [Pg.678]    [Pg.207]    [Pg.2947]    [Pg.43]    [Pg.533]    [Pg.131]    [Pg.72]    [Pg.26]    [Pg.355]    [Pg.68]    [Pg.247]    [Pg.421]    [Pg.635]    [Pg.106]    [Pg.942]    [Pg.15]    [Pg.71]    [Pg.131]    [Pg.373]    [Pg.432]    [Pg.576]    [Pg.5337]    [Pg.538]    [Pg.178]    [Pg.410]    [Pg.33]    [Pg.1369]    [Pg.104]    [Pg.35]    [Pg.20]    [Pg.312]    [Pg.14]    [Pg.33]    [Pg.212]    [Pg.262]    [Pg.367]    [Pg.38]   
See also in sourсe #XX -- [ Pg.27 ]




SEARCH



Applications analytical

Drift

Drifting

© 2024 chempedia.info