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Dispersion-type shape

In the contrast to the irreversible adsorption of amphiphilic ions on the reversed-phase surface, the liophiUc ions shows relatively weak interactions with the alkyl chains of the bonded phase. Liophilic means oil-loving. These liophilic ions are usually small inorganic ions and they possess an important ability for dispersive type interactions. They are (a) characterized by significant delocalization of the charge, (b) primarily symmetrical, (c) usually spherical in shape, and (d) absence in surfactant properties. [Pg.204]

Contrary to the situation in polarization spectroscopy, where for slightly uncrossed polarizers the line shape of the polarization signal is a superposition of Lorentzian and dispersion profiles, with saturated interference spectroscopy pure Lorentzian profiles are obtained because the phase shift is compensated by the feedback control. Measuring the first derivative of the profiles, pure dispersion-type signals appear. To achieve this, the output of the lock-in amplifier that controls the... [Pg.139]

For a judicious control of the macroscopic properties of polymer blends, phase morphology constitutes a key parameter for many specific applications. The blending process of immiscible polymers in the melt state results in a heterogeneous morphology that is characterized by the shape, the size, and the distribution of the component phases. Depending on the composition, the homopolymer characteristics and the processing conditions used to mix them, two main types of morphologies are obtained, a dispersed type (a particle can be of any shape rod, platelet, flacks, disc, sphere, etc.) or a co-continuous one. [Pg.419]

Commercial PVC is generally produced by addition polymerization. It may be produced by a variety of techniques such as suspension, emulsion, micro suspension and bulk. PVC, as normally prepared, is a white granular material, ranging in particle size from 5-400 microns and with apparent bulk densities of 0.5-0.8 g/cc. Emulsion type PVC is usually smaller in particle size. This type of PVC is also called dispersion type. Dispersion type PVC is grounded to further decrease particle size and this type of PVC is called paste type. Paste PVC particles are irregular in shape and have relatively high surface area. Both dispersion and paste type PVC are suitable for plastisol applications. [Pg.39]

Once again, the use of tracer response experiments is a critical element in the development of a compartment model. As with the Dispersion and CIS models, the parameters of a compartment model may have to be calculated from the moments of the external-age distribution function. Moreover, the shapes of the E t) curve must he used to help choose the types and arrangement of compartments that will comprise the model. In order to conceptualize a compartment model from the measured E t) curve at the reactor outlet, it is important to inject the tracer as a sharp pulse, as close to the reactor inlet as possible. If the tracer that enters the reactor is too dispersed, the shape of the tracer curve that leaves the reactor will not reflect its behavior in sufficient detail to formulate an accurate model. [Pg.427]

Microscopes are also classified by the type of information they present size, shape, transparency, crystallinity, color, anisotropy, refractive indices and dispersion, elemental analyses, and duorescence, as well as infrared, visible, or ultraviolet absorption frequencies, etc. One or more of these microscopes are used in every area of the physical sciences, ie, biology, chemistry, and physics, and also in their subsciences, mineralogy, histology, cytology, pathology, metallography, etc. [Pg.328]

Catalytic Properties. In zeoHtes, catalysis takes place preferentially within the intracrystaUine voids. Catalytic reactions are affected by aperture size and type of channel system, through which reactants and products must diffuse. Modification techniques include ion exchange, variation of Si/A1 ratio, hydrothermal dealumination or stabilization, which produces Lewis acidity, introduction of acidic groups such as bridging Si(OH)Al, which impart Briimsted acidity, and introducing dispersed metal phases such as noble metals. In addition, the zeoHte framework stmcture determines shape-selective effects. Several types have been demonstrated including reactant selectivity, product selectivity, and restricted transition-state selectivity (28). Nonshape-selective surface activity is observed on very small crystals, and it may be desirable to poison these sites selectively, eg, with bulky heterocycHc compounds unable to penetrate the channel apertures, or by surface sdation. [Pg.449]

Knox and Piper (13) assumed that the majority of the adsorption isotherms were, indeed, Langmuir in form and then postulated that all the peaks that were mass overloaded would be approximately triangular in shape. As a consequence, Knox and Piper proposed that mass overload could be treated in a similar manner to volume overload. Whether all solute/stationary phase isotherms are Langmuir in type is a moot point and the assumption should be taken with some caution. Knox and Piper then suggested that the best compromise was to utilize about half the maximum sample volume as defined by equation (15), which would then reduce the distance between the peaks by half. They then recommended that the concentration of the solute should be increased until dispersion due to mass overload just caused the two peaks to touch. [Pg.120]

The morphology of the ABA-type linear block copolymers is strongly influenced by the volume fraction of the two components. For example, in PS-EB-PS-type block copolymer as the volume fraction of PS is increased, the shape of the dispersed PS phase changes from spherical (comprising body-centered cubic spheres of PS dispersed in continuous soft phase) to cylindrical form (hexagonal packed cylinders of PS) [10,133,134]. When the volume fraction of the two phases... [Pg.126]

There are generally three types of peaks pure 2D absorption peaks, pure negative 2D dispersion peaks, and phase-twisted absorption-dispersion peaks. Since the prime purpose of apodization is to enhance resolution and optimize sensitivity, it is necessary to know the peak shape on which apodization is planned. For example, absorption-mode lines, which display protruding ridges from top to bottom, can be dealt with by applying Lorentz-Gauss window functions, while phase-twisted absorption-dispersion peaks will need some special apodization operations, such as muliplication by sine-bell or phase-shifted sine-bell functions. [Pg.180]


See other pages where Dispersion-type shape is mentioned: [Pg.113]    [Pg.113]    [Pg.610]    [Pg.611]    [Pg.66]    [Pg.113]    [Pg.386]    [Pg.243]    [Pg.206]    [Pg.91]    [Pg.422]    [Pg.428]    [Pg.233]    [Pg.1058]    [Pg.1069]    [Pg.1990]    [Pg.1145]    [Pg.640]    [Pg.18]    [Pg.350]    [Pg.431]    [Pg.180]    [Pg.512]    [Pg.351]    [Pg.1639]    [Pg.2173]    [Pg.660]    [Pg.1145]    [Pg.587]    [Pg.769]    [Pg.541]    [Pg.536]    [Pg.204]    [Pg.135]    [Pg.37]    [Pg.40]    [Pg.274]    [Pg.29]    [Pg.546]   
See also in sourсe #XX -- [ Pg.113 , Pg.116 , Pg.118 , Pg.128 , Pg.185 , Pg.188 , Pg.191 ]




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Dispersants types

Shapes types

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