Dispersion spinning

A distinction is made between melt, wet, dry, gel extrusion, and dispersion spinning. In all cases, one can start with polymer granulate, or in principle, with the polymerizate direct from the reactor. Split fiber formation is completely different. Fleece is generally produced by a thermally or chemically generated interfiber adhesion. 

Dispersion spinning is a special spinning process for insoluble and nonmelting polymers. The dispersions of the polymers for spinning have other organic polymers added to increase their viscosity and to stabilize the fibers. This polymer is then burned off after the filaments have been... 

NMR spin-lattice relaxation NMR spin-spin/Rotating-frame relaxation Nuclear spin relaxation dispersion (Spin-lattice/spin-spin/Rotating-frame)... 

Both ESR and fluorescence spectroscopy give an indirect measure of motion in polymers as they make use of either spin label or probe methods. In the case of ESR, nitroxyl radicals dispersed (spin probe) in a polymer matrix or covalently bonded to the polymer chains (spin label) are employed to probe the local environment. Therefore, ESR spectra provide information on molecular motion and microstructure of polymer matrices. Similarly, fluorescent probes are sensitive to the glass structure. This is because photon emission increases when non-radiative processes are hindered by lack of mobUity of the probe. Interestingly, studies on poly (vinyl acetate) (PVAc) have shown that changes in the fluorescence intensities with aging time and temperature follow closely those observed by volumetric relaxation [85]. 

Synperonk PE/L31 dispersant, spin finishes Hypermer 1031 Hypermer 1032 dispersant, sport drinks... 

The third alternative is a more robust, sensitive and specialized fonn of the first, in that only hydrogen nuclei indirectly spin-spin coupled to in a specific molecular configuration are imaged. In achieving selectivity, the technique exploits the much wider chemical shift dispersion of compared to H. The metliod involves cyclic transfer from selected H nuclei to indirectly spin-spin coupled C nuclei and back according to the sequence... 

Acrylonitrile and its comonomers can be polymerized by any of the weU-known free-radical methods. Bulk polymerization is the most fundamental of these, but its commercial use is limited by its autocatalytic nature. Aqueous dispersion polymerization is the most common commercial method, whereas solution polymerization is used ia cases where the spinning dope can be prepared directly from the polymerization reaction product. Emulsion polymerization is used primarily for modacryhc compositions where a high level of a water-iasoluble monomer is used or where the monomer mixture is relatively slow reacting. 

Stabilizers, pigments, and other additives are milled in spinning solvent, normally along with small amounts of the urethane polymer to improve dispersion stabiUty this dispersion is then blended to the desired concentration with polymer solution after chain extension. Most producers combine prepolymerization, chain extension, and additive addition and blending into a single integrated continuous production line. 

Because of the high melt viscosity of polyolefins, normal spinning melt temperatures are 240—310°C, which is 80—150°C above the crystalline melting point. Because of the high melt temperatures used for polyolefin fiber spinning, thermal stabilizers such as substituted hindered phenols are added. In the presence of pigments, the melt temperature must be carefully controlled to prevent color degradation and to obtain uniform color dispersion. 

Aqueous dispersions are used for spinning PTEE fibers. The dispersion is mixed with a matrix-forming medium (116,117) and forced through a spinneret into a coagulating bath. The matrix material is removed by heating and the fibers are sintered and drawn molten to develop their full strength. 

Bicomponent technology has been used to introduce functional and novelty effects other than stretch to nylon fibers. For instance, antistatic yams are made by spinning a conductive carbon-black polymer dispersion as a core with a sheath of nylon (188) and as a side-by-side configuration (189). At 0.1—1.0% implants, these conductive filaments give durable static resistance to nylon carpets without interfering with dye coloration. Conductive materials such as carbon black or metals as a sheath around a core of nylon interfere with color, especially light shades. 

Global AMI.5 sun illumination of intensity 100 mW/cm ). The DOS (or defect) is found to be low with a dangling bond (DB) density, as measured by electron spin resonance (esr) of - 10 cm . The inherent disorder possessed by these materials manifests itself as band tails which emanate from the conduction and valence bands and are characterized by exponential tails with an energy of 25 and 45 meV, respectively the broader tail from the valence band provides for dispersive transport (shallow defect controlled) for holes with alow drift mobiUty of 10 cm /(s-V), whereas electrons exhibit nondispersive transport behavior with a higher mobiUty of - 1 cm /(s-V). Hence the material exhibits poor minority (hole) carrier transport with a diffusion length <0.5 //m, which puts a design limitation on electronic devices such as solar cells. 

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