Diols dicarboxylic acids

The rate of oxidation of various diols, dicarboxylic acids, and a-hydroxycar-boxylic acids by silver(II) has been investigated in aqueous perchlorate media. Reactions in the presence of excess substrate (S) were found to be first order in [Ag(II)], the rate law showing pathways attributable to Ag " and AgOH as oxidants. However for S = 1,2-ethanediol and 1,3-propanediol, marked curvature in the kinetics profiles is consistent with prior complex formation. The Cr(V) chelate, bis(2-ethyl-2-hydroxybutanato)oxochromate(V), oxidizes the arenediols hydroquinone and 2,3-dihydroxybenzoic acid to form the related quinone and... 

Diols Dicarboxylic acids Monohydric alcohols Monocarboxylic acids... 

Biodegradable Aliphatic Polyesters with a Diol/Dicarboxylic Acid Repetitive Unit... 

Unfortunately, apart from aliphatic polyesters of this group based on succinic acid, the majority have a very low melting point, which can range from nearly 40-70 °C depending on the diol/dicarboxylic acid coupling. This characteristic precludes their use at an industrial level. 

The industrialisation of 1,4-butanediol and succinic acid production from biomass is in progress. Hence, aliphatic-biopolyesters containing a diol/dicarboxylic acid repetitive unit from 100% renewable resources will be available. 

Aliphatic polyesters based on various combinations of diols/dicarboxylic acids Ethylene-vinyl acetate copolymers (65-80 wt% VAc)... 

Other polyesters that have been studied include hydroxy branched polyethers [20], methacrylic trimers [9], bntyl acrylate, methylmethacrylate and polyesters [21], and diol-dicarboxylic acid polyesters [22]. 

Paredes N, Casas M T, Puiggali J. (2000), Packing of sequential poly(ester amide)s derived from diols, dicarboxylic acids, and amino acids . Macromolecules, 33 (24), 9090-9097. 

Polyesters from diols and dicarboxylic acids (polyester fibres). 

Polyesters are a second class of condensation polymers and the principles behind their synthesis parallel those of polyamides Ester formation between the functional groups of a dicarboxylic acid and a diol... 

Plasticizers can be classified according to their chemical nature. The most important classes of plasticizers used in rubber adhesives are phthalates, polymeric plasticizers, and esters. The group phthalate plasticizers constitutes the biggest and most widely used plasticizers. The linear alkyl phthalates impart improved low-temperature performance and have reduced volatility. Most of the polymeric plasticizers are saturated polyesters obtained by reaction of a diol with a dicarboxylic acid. The most common diols are propanediol, 1,3- and 1,4-butanediol, and 1,6-hexanediol. Adipic, phthalic and sebacic acids are common carboxylic acids used in the manufacture of polymeric plasticizers. Some poly-hydroxybutyrates are used in rubber adhesive formulations. Both the molecular weight and the chemical nature determine the performance of the polymeric plasticizers. Increasing the molecular weight reduces the volatility of the plasticizer but reduces the plasticizing efficiency and low-temperature properties. Typical esters used as plasticizers are n-butyl acetate and cellulose acetobutyrate. 

Polyesters can be produced by an esterification of a dicarboxylic acid and a diol, a transesterification of an ester of a dicarboxylic acid and a diol, or by the reaction between an acid dichloride and a diol. 

Some of the typical conditions of polycondensations used for aliphatic and aromatic monomers are not suitable for furan derivatives, e.g., the melt polycondensation of 2,5-furan dicarboxylic acid chloride with 2,5-b/s(hydroxymethyl) furan at about 80 °C only yields a black insoluble product5. The hydrochloric acid liberated in the reaction is clearly responsible for the charring of the furanic diol which like its simpler homologue furfuryl alcohol, resinifies rapidly in acidic media (see below). 

From the preceding discussion, it is easily understood that direct polyesterifications between dicarboxylic acids and aliphatic diols (Scheme 2.8, R3 = H) and polymerizations involving aliphatic or aromatic esters, acids, and alcohols (Scheme 2.8, R3 = alkyl group, and Scheme 2.9, R3 = H) are rather slow at room temperature. These reactions must be carried out in the melt at high temperature in the presence of catalysts, usually metal salts, metal oxides, or metal alkoxides. Vacuum is generally applied during the last steps of the reaction in order to eliminate the last traces of reaction by-product (water or low-molar-mass alcohol, diol, or carboxylic acid such as acetic acid) and to shift the reaction toward the... 

Activating agents, such as trifluoroacetic anhydride 1,1 -carbonyldiimidazolc carbodiimides sulfonyl, tosyl, and picryl chlorides and a range of phosphorus derivatives can promote direct solution reactions between dicarboxylic acids and diols or diphenols in mild conditions. The activating agents are consumed during the reaction and, therefore, do not act as catalysts. These so-called direct polycondensation or activation polycondensation reactions proceed via the in situ transformation of one of the reactants, generally the carboxylic acid, into a more... 

Trinitrochlorobenzene (piciyl chloride) in pyridine-A -mcthylpyrrolidi-none (NMP) solutions were later used for the preparation of polyesters from dicarboxylic acids and diphenols or aliphatic diols,309 but better results have been obtained with sulfonyl chlorides and phosphorus compounds. 

Polyester polyols (Scheme 4.4) are prepared by condensation polymerization of dicarboxylic acids and diols. An excess of diol ensures OH functional product, minimizing die possibility of residual acid groups which react with isocyanates to generate C02 and act as inhibitors in catalyzed urethane reactions. The reactants are heated at 200-230°C under vacuum to remove the water by-product and drive the reaction to completion. The most common coreactants include adipic... 

Dicarboxylic acids or esters thereof are recovered from solid phase polyester materials, such as post-consumer products and factory scrap, by subjecting the polyester to at least two hydrolysis stages in at least the first of which the amount of water used is substantially less than needed to effect total conversion of the polyester to the dicarboxylic acid. Also the diol content is controlled in the course of carrying out the hydrolysis. The hydrolysis reactions may be preceded by reaction of the polyester with a diol, the resulting depolymerisation products then being hydrolysed. 

A novel chemoenzymatic route to polyester polyurethanes was developed without employing highly toxic isocyanate intermediates. First, diurethane diols were prepared from cyclic carbonates and primary diamines, which were subsequently polymerized with dicarboxylic acids and glycols by using lipase CA as catalyst, yielding the polyurethanes under mild reaction conditions. 

Polymerisation of a diol with a dicarboxylic acid is exemplified by the production of a polyester from ethylene glycol and terephthalic acid either by direct esterification or by a catalysed ester-interchange reaction. The resulting polyester Terylene) is used for the manufacture of fibres and fabrics, and has high tensile strength and resiliency its structure is probably ... 

A dispersant that can be used in drilling fluids, spacer fluids, cement slurries, completion fluids, and mixtures of drilling fluids and cement slurries controls the rheologic properties of and enhances the filtrate control in these fluids. The dispersant consists of polymers derived from monomeric residues, including low-molecular-weight olefins that may be sulfonated or phosphonated, unsaturated dicarboxylic acids, ethylenically unsaturated anhydrides, unsaturated aliphatic monocarboxylic acids, vinyl alcohols and diols, and sulfonated or phosphonated styrene. The sulfonic acid, phosphonic acid, and carboxylic acid groups on the polymers may be present in neutralized form as alkali metal or ammonium salts [192,193]. 

M. Hofinger and H. Schellenberg. Process for the preparation of polycondensation products from alkoxylated fatty amines, diols and aliphatic dicarboxylic acids (Verfahren zur Herstellung von Polykon-densationsverbindungen aus oxalkylierten Fettaminen, Diolen und Aliphatischen Dicarbonsauren). Patent EP 299348,1989. 

High boiling polar compounds, diols, phenols, methyl esters of. dicarboxylic acids, amines, diamines, ethanolamines, amides, aldehydes and ketones. 

If the carboxylic acid has two carboxyl functional groups (a dicarboxylic acid) and if the alcohol has two hydroxyl functional groups (a diol), a polyester will result nHOOC—R—COOH + nHO—R —OH —> +OOC—R—COO—R +n + nH20. 

Esterification of a dicarboxylic acid such as terephthalic acid via the diimidazolides with diols readily leads to the corresponding polyesters.[12]... 

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