Dimethylamide acetate

Synonyms Acetdimethylamide Acetic acid dimethylamide AI3-15276 BRN 1737614 CCRIS 4623 Dimethylacetamide Dimethylacetone amide Dimethylamide acetate A7A-Dimethylethan-amide DMA DMAC EINECS 204-826-4 Hallucinogen NSC 3138 SK 7176 U 5954. 

Dimethyl acetate, see ferf-Butyl acetate Dimethylacetone amide, see iV,iV-Dimethylacetamide Dimethylacetonyl carbinol, see Diacetone alcohol Dimethylacetyl formaldehyde, see Methylal Dimethylamide acetate, see iV,iV-Dimethylacetamide iV,iV-Dimethylamine, see Dimethylamine... 

Acetic Acid, Cupric Salt Acetic Acid, Dimethylamide Acetic Acid, Ethyl Ester Acetic Acid, Isobutyl Ester Acetic Acid, Isopropyl Ester Acetic Acid, Methyl Ester Acetic Acid, Nickel (II) Salt Acetic Acid, Propyl Ester Acetic Acid, Sec-Butyl Ester Acetic Acid, Zinc Salt Acetic Aldehyde Acetic Anhydride Acetic Ester Acetic Ether... 

SYNS ACETDIMETHYLAMIDE D ACETIC ACID DIMETHYLAAHDE DIMETHYLACETAMIDE DLMETHITACETONE AMIDE DIMETHYLAMIDE ACETATE DATA DMAC NSC-3138 U-5954... 

Acetdimethylamide acetic acid dimethylamide acetyldimethy-lamine dimethylacetone amide dimethylamide acetate DMA DMAC. 

DIMETHYLAMIDE ACETATE (127-19-5) Combustible liquid (flash point 158°F/ 70°C). Violent reaction with strong oxidizers, halogenated compounds. Incompatible with mineral acids, strong acids, ammonia, isocyanates, phenols, cresols. Attacks plastics, rubber, and coatings. 

Acetamide, N,N-dimethyl- Acetdimethylamide Acetic acid dimettiylamide Acetyidimethylamine AI3-15276 CBC 510337 CCRIS 4623 Dimethyl acetamide Dimethylamid kyseliny ootove Dimethylamide acetate DMA DMAc EINECS 204-826-4 HSDB 74 NSC 3138 SK 7176 U-5954. Liquid mp = -20 bp = 165" d S =... 

SYNONYMS acetic acid dimethylamide, acetyl dimethylamide, n,n-dimethylacetamide, dimethylacetone amide, dimethylamide acetate, dmac. 

CAS 127-19-5 EINECS/ELINCS 204-826-4 Synonyms Acetdimethylamide Acetic acid dimethylamide Acetyidimethylamine N,N-Dimethylacetamide Dimethylacetone amide Dimethylamide acetate DMA DMAC Empiricai C4H9NO Formuia CH3CON(CH3)2... 

Chemical DesignationsN,N-Dimethylacetamide, Acetic Acid, Dimethylamide Chemical Formula CH3CON(CH3)j. 

Acetamidofluorene, see 2-Acetylaminofluorene 2-Acetaminofluorene, see 2-Acetylaminofluorene Acetanhydride, see Acetic anhydride Acetasol, see Acetic acid Acetdimethylamide, see A,A-Dimethylacetamide Acetic acid, amyl ester, see Amyl acetate Acetic acid anhydride, see Acetic anhydride Acetic acid (aqueous soln), see Acetic acid Acetic acid, 2-butoxy ester, see sec-Butyl acetate Acetic acid, butyl ester, see Butyl acetate Acetic acid, sec-butyl ester, see sec-Butyl acetate Acetic acid, ferf-butyl ester, see ferf-Butyl acetate Acetic acid dimethylamide, see A,A-Dimethylacetamide Acetic acid, 1,3-dimethylbutyl ester, see sec-Hexyl acetate Acetic acid, 1,1-dimethylethyl ester, see ferf-Butyl acetate Acetic acid, ethenyl ester, see Vinyl acetate... 

N8CON(CH3)2 mw 114.11, N 49.10% liq bp 59°(15 torr), expl when heated over a flame. Prepd by boiling NaN3 with chloroformic acid dimethylamide in acet (Ref 2) Refs 1) Beil [5 5l 2) R. Stolle, ... 

The methyl group in 5-methylindolizines is sufficiently active to allow the introduction of functional groups. Indolizines (15) with n-butyllithium followed by A,A-dimethylamides give, after hydrolysis, ketones 16. Cyclodehydration to 1 takes place in glacial acetic acid [Eq. (1)] more severe conditions, such as in hydrogen fluoride, were ineffective, presumably owing to protonation of the indolizine nucleus.1... 

Acetal esters such as diethoxyacetic ester and /3,/S-diethoxypropionic ester are readily converted to amides with concentrated ammonium hydroxide. The former ester gives an N,N-dimethylamide by reaction with dimethylamine. ... 

Reaction with aUyhc alcohols (1, 271 272). The reaction of rran.v-3-penten-2-ol (1) with N, N-dimethylacetamide dimethyl acetal and/or its synthetic equivalent 1 -methoxy-l-dimcthylaminoethylene in refluxing xylene for 17 hr. gives the N,N-dimethylamide of 3-mcthyl-4-trani-hexenoic acid (2) in 80% yield. When the reaction was carried out... 

Adding appropriate nucleophiles with leaving group capabilities, such as phenylselenide (SePh) or dimethylamide (NMe2) gives access to precursors of a variety of modified cyclo-propylideneacetates bearing almost any substituent (X = OSiRj, N3, F, H, SMe, SPh). - ° The chiral methyl 2-cyclopropylidene-2-(phenylsulfinyl)acetate can be prepared from methyl 2-cyclopropylidene-2-(phenylsulfanyl)acetate under strictly anhydrous conditions. This bisac-ceptor-substituted methylenecyclopropane can be isolated, but it rapidly attracts water upon standing in air at room temperature. ... 

Dimethyl- acetamide N,N-Dimethyl-Acetamide, Acetic Acid, Dimethylamide ... 

ACETIC ACID, DIMETHYLAMIDE (127-19-5) C4H9NO Combustible liquid [explosion limits in air (vol %) 1.8 to 13,8 flashpoint 158°F/70°C oc autoignition temp 914°F/490°C Fire Rating 2]. Violent reaction with strong oxidizers, halogenated compounds carbon tetrachloride hexa-chlorocyclohexane. Reacts violently in the presence of iron. Incompatible with mineral acids, strong acids, ammonia, isocyanates, phenols, cresols. Attacks many plastics, rubber, and coatings. When heated to decomposition, emits carbon oxides,... 

CHLOROFORMIC ACID DIMETHYLAMIDE (79-44-7) Combustible liquid (flash point 155°F/68°C). Rapidly hydrolyzed in water to dimethylamine, carbon dioxide, and hydrogen chloride. Violent reaction with strong oxidizers. Acid or acid fumes form toxic chloride fumes. Aqueous solution is incompatible with sulfuric acid, alkalis, ammonia, aliphatic amines, alkanolamines, alkylene oxides, amides, epichlorohydrin, organic anhydrides, isocyanates, vinyl acetate. May increase the explosive sensitivity of nitromethane. Attacks austenitic stainless steels, causing pitting and stress corrosion. 

Methylphenol has been converted by way of the diethylaminothionecarbamate to thediethylaminothiol carbamate, (through the Newman-Kwart rearrangement), which in 80% acetic acid with excess chlorine gave 2-methylbenzene sulphonyi chloride in 95% yield, (characterised in 94% yield as the dimethylamide by reaction with 40% aqueous dimethyiamine) (ref.48). 

There is some resemblance to the two-step formation of cycl[3.2.2]azines (184) when indolizines (182) were treated with butyllithium followed by A,A-dimethylamides to give, after hydrolysis, ketones (183), which were cyclodehydrated by glacial acetic acid (58JA2020 59JA1459) as shown in Scheme 41. 

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