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Deviant behaviour

In summary, for the most active of catalysts, the copper(II) ion, the diamine ligands that were investigated seriously hamper catalysis mainly by decreasing the efficiency of coordination of the dienophile. With exception of the somewhat deviant behaviour of N,N -dimethylethylenediamine, this conclusion also applies to catalysis by Ni" ions. Hence, significant ligand-accelerated catalysis using the diamine ligands appears not to be feasible. [Pg.85]

Hydroformylation results in Table 8.3 show that, with the exception of ligands 28 and 30, the rate of the reaction increases with decreasing phosphine basicity. An explanation for the deviant behaviour of 28 and 29 can be that catalyst formation is incomplete or deactivation of the catalyst occurs. Decreasing phosphine basicity facilitates CO dissociation from the (diphosphine)Rh(CO)2H complex and enhances alkene coordination to form the (diphosphine)Rh(CO)H(alkene) complex, and therefore, the reaction rate increases. [Pg.158]

The clinical picture is characterized by xanthomas, particularly on the tendons (especially the Achilles tendon). Xanthomas consist of cholesterol and cholestanol. The enzyme defect also results in disturbed vitamin D metabolism. Osteoporosis is thus observed quite often, with a tendency towards spontaneous fractures. (208) Striking clinical features are cerebral functional disorders (from deviant behaviour to severe dementia, motor disturbances and convulsions) as well as peripheral neurological symptoms caused by cholestanol deposits. (211) High concentrations of apolipoprotein B and cholestanol are found in the CSF. (213) Treatment is based on the administration of chenodeoxycholic acid (750 mg/day). Effectiveness is improved if HMG-CoA reductase inhibitors (e. g. pravastatin) are used concomitantly. (207, 212)... [Pg.599]

Although the parity plots do not allow a direct comparison of calculated results with experimental readings, they do allow us to examine the fit between predicted rates and those extracted from the TS-PFR experiment and used in the parameter optimization. Deviant behaviour is evidenced on parity plots as excessive scatter from the diagonal or by trends in the scatter. Unsatisfactory correlations will exhibit well-defined trends on parity plots, even if the SSR for the whole data set is deemed to be acceptable. Such trends can then be used to identify the shortcomings of the proposed rate expression. [Pg.243]

Non-thermodynamically Limited Steric Stabilization Dispersions Displaying Deviant Behaviour... [Pg.160]

Complexity introduces additional challenges when it comes to evaluating faults and live service incidents. A key element in undertaking a root cause analysis is to be able to faithfully reproduce deviant behaviour. Faults in complex systems are more likely to be intermittent, unpredictable, non-deterministic and seemingly random. In particular it can be challenging to predict combinations of failures which might impact the system as a whole. Without an accurate set of pre-conditions on which to base the analysis any attempts to fix the issue will be severely hampered. [Pg.213]

The mass media, in fact, devote a great deal of space to deviance sensational crimes, scandals, bizarre happenings and strange goings on. The more dramatic confrontations between deviance and control in manhunts, trials and punishments are recurring objects of attention. As Erikson notes, a considerable portion of what we call news is devoted to reports about deviant behaviour and its consequences . This is not just for entertainment or to... [Pg.10]

The triggering-off, sensitization and other such effects of mass communication described so far, deal with the way in which the likelihood of deviant behaviour during the impact was increased one almost had to attempt to see or take part in trouble. The inventory and subsequent opinion themes, though, also affected the form and content of the behaviour. The societal reaction not only increases the deviant s chance of acting at all, it also provides him with his lines and stage directions. [Pg.186]

In summary, the societal reaction may be thought to have affected the nature, extent and development of the deviant behaviour during the impact phase in the following ways ... [Pg.199]

Seejohn I. Kitsuse, Societal Reaction to Deviant Behaviour Problems of Theory and Method , Social Problems 9 (Winter 1962), pp. 247-56. [Pg.253]

Albert K. Cohen, The Study of Social Disorganization and Deviant Behaviour , in R. K. Merton etal. (Eds), Sociology Today Problems and Prospects (New York Basic Books, 1959), p. 465. [Pg.258]

Young adults-Great Britain-Case studies. 2. Deviant behaviour. 3. Subculture-Great Britain. 4. Moral panics. I. Title. [Pg.287]


See other pages where Deviant behaviour is mentioned: [Pg.19]    [Pg.2]    [Pg.85]    [Pg.204]    [Pg.121]    [Pg.106]    [Pg.378]    [Pg.148]    [Pg.161]    [Pg.163]    [Pg.165]    [Pg.169]    [Pg.171]    [Pg.173]    [Pg.177]    [Pg.179]    [Pg.106]    [Pg.5]    [Pg.90]    [Pg.186]    [Pg.232]    [Pg.259]    [Pg.317]    [Pg.318]    [Pg.400]    [Pg.317]    [Pg.318]    [Pg.130]    [Pg.131]    [Pg.224]    [Pg.85]   


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