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As was pointed out, an increased specific activity of nucleic acids following injection of formate-C could reflect an increased rate of synthesis of the nucleic acids or an increased specific activity of the precursors. Data on C 02 excretion, following formate-C injections, indicated that the overall formate pool size and specific activity were not influenced by vitamin E deficiency. In an effort to obtain information on the specific activities of the nucleotide precursors, acid-soluble nucleotides were extracted from formate-C Mnjccted animals. It was foimd (Table III) that the acid-soluble nucleotides from the viscera of vitamin E-deficient rabbits previously... [Pg.514]

Figure 9.2-2 shows a data input screen in which general characteristics are input by radio buttons and numerical data is typed. The program calculates distances to specified in.sic concentrations and other requested consequence levels automatically. Results are available in a variety of formats including cloud footprints, sideview, cross section, pool evaporation rate, concentration vs distance and heat flux contours. Figure 9.2-3 shows the calculated results as a toxic plume. superimposed on the map with and without oligomerization. [Pg.359]

Much research has centered on identifying the source of the purine ring in caffeine. Two possible sources are likely methylated nucleotides in the nucleotide pool and methylated nucleotides in nucleic acids. Extensive experimental work by Suzuki and Takahashi27-30 proposes a scheme whereby caffeine is synthesized from methylated purines in the nucleotide pool via 7-methylxanthosine and theobromine. Information relating to the formation of 7-methylxanthine from nucleotides in the nucleotide pool is sparse. They also provide data that demonstrate that theophylline is synthesized from 1-methyladenylic acid through 1-methylxanthine as postulated by Ogutuga and Northcote.31... [Pg.19]

In addition to drinking water, chlorinated oxidants reacting with organic materials will lead to the formation of chloroform in swimming pools. Since swimming pools are not routinely analyzed for their chloroform content, data are limited and derived from special studies. Such studies will often cover the broader family of THMs, and while chloroform levels in blood or alveolar air samples will be reported, the environmental agents will often simply be recorded in terms of THMs. A rule of thumb (Copaken 1990) is... [Pg.211]

From an elemental perspective, most of the mass of POM and DOM is carbon. Thus, DOC and POC concentrations are generally representative of the entire DOM and POM pools. Because DOC and POC concentrations are more easily measured than those of the other elements (nitrogen, phosphorus, oxygen, and hydrogen), far more data has been collected on their concentrations and reactivity as compared to that of DON, PON, DOP, or POP. DOM and POM concentrations are not measured for technical reasons and because the total mass of organic matter provides little insight into the biogeochemical processes responsible for its formation and destruction. [Pg.610]

Figure 9. Schematic of four mechanisms describing the interaction of Ca with films of DPL (1) ionr-dipole interaction (2) ion-exchange mechanism (3) ionr-ion interaction with ionized anionic lipid contaminant and (4) penetration of electrolyte, HgO, and derived ions into the air- vater or the lipid-water interface. A highlight of Mechanism 4 (consistent with the surface radioactivity data, Ref. 3) is the adsorption of the ions of HCl resulting from th ehydrolysis of CaCU. The coexistence of Ca(OH) and aqueous HCl at the interface requires the formation of compartments or pools that permit the separation of the acid from the base. Such a coexistence of acidic and basic pools is conceivable in the light of the Ca(OH), film on the HCl solution following the hydrolysis of CaCU in the absence of DLP films and is probably a characteristic of DPL films, since the adsorption of Cl was nil without DPL. Figure 9. Schematic of four mechanisms describing the interaction of Ca with films of DPL (1) ionr-dipole interaction (2) ion-exchange mechanism (3) ionr-ion interaction with ionized anionic lipid contaminant and (4) penetration of electrolyte, HgO, and derived ions into the air- vater or the lipid-water interface. A highlight of Mechanism 4 (consistent with the surface radioactivity data, Ref. 3) is the adsorption of the ions of HCl resulting from th ehydrolysis of CaCU. The coexistence of Ca(OH) and aqueous HCl at the interface requires the formation of compartments or pools that permit the separation of the acid from the base. Such a coexistence of acidic and basic pools is conceivable in the light of the Ca(OH), film on the HCl solution following the hydrolysis of CaCU in the absence of DLP films and is probably a characteristic of DPL films, since the adsorption of Cl was nil without DPL.
Figure 1. Transformations in the ocean and overlying atmosphere which lead to the production of sulfate from a marine biogenic source (dark arrows). DMS is produced in the ocean after the uptake of seawater sulfate by phytoplankton and the production and breakdown of DMSP. Sulfate formation occurs after DMS is transferred across the sea-air interface and undergoes atmospheric oxidation. The S S values for the individual sulfur pools are indicated in the boxes and measured or estimated discriminations (D) are indicated above the arrows. Clearly, data for the remote atmosphere are limited. Figure 1. Transformations in the ocean and overlying atmosphere which lead to the production of sulfate from a marine biogenic source (dark arrows). DMS is produced in the ocean after the uptake of seawater sulfate by phytoplankton and the production and breakdown of DMSP. Sulfate formation occurs after DMS is transferred across the sea-air interface and undergoes atmospheric oxidation. The S S values for the individual sulfur pools are indicated in the boxes and measured or estimated discriminations (D) are indicated above the arrows. Clearly, data for the remote atmosphere are limited.
Abstract The objective of this chapter is to present some recent developments on nonaque-ous phase liquid (NAPL) pool dissolution in water saturated subsurface formations. Closed form analytical solutions for transient contaminant transport resulting from the dissolution of a single component NAPL pool in three-dimensional, homogeneous porous media are presented for various shapes of source geometries. The effect of aquifer anisotropy and heterogeneity as well as the presence of dissolved humic substances on mass transfer from a NAPL pool is discussed. Furthermore, correlations,based on numerical simulations as well as available experimental data, describing the rate of interface mass transfer from single component NAPL pools in saturated subsurface formations are presented. [Pg.98]

Following the conceptual idea introduced by Milliken [68], Takahashi and Classman [53] have shown, with appropriate assumptions, that, at a fixed temperature, fc could correlate with the number of C—C bonds in the fuel and that a plot of the log vs number of C—C bonds should give a straight line. This parameter, number of C—C bonds, serves as a measure of both the size of the fuel molecule and the C/H ratio. In pyrolysis, since the activation energies of hydrocarbon fuels vary only slightly, molecular size increases the radical pool size. This increase can be regarded as an increase in the Arrhenius pre-exponential factor for the overall rate coefficient and hence in the pyrolysis and precursor formation rates so that the C/H ratio determines the OH concentration [72]. The ijfc vs C—C bond plot is shown in Fig. 14. When these data are plotted as log vs C—C bonds. [Pg.406]


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