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Cyclohexanols functionalized

It is possible to perform the conversion CH2 C=0 on an alkane, with no functional groups at all, though the most success has been achieved with substrates in which all CH2 groups are equivalent, such as unsubstituted cycloalkanes. One method uses H2O2 and bis(picolinato)iron(II). With this method, cyclohexane was converted with 72% efficiency to give 95% cyelohexanone and 5% cyclohexanol. ... [Pg.1532]

Although kinetic evidence for prior equilibrium inclusion was not obtained, competitive inhibition by cyclohexanol and apparent substrate specificity once again provide strong support for this mechanism. Since the rate of the catalytic reaction is strictly proportional to the concentration of the ionized hydroxamate function (kinetic and spectrophotometric p/Cas are identical within experimental error and are equal to 8.5), the reaction probably proceeds by a nucleophilic mechanism to produce an acyl intermediate. Although acyl derivatives of N-alkylhydroxamic acids are exceptionally labile in aqueous solution, deacylation is nevertheless the ratedetermining step of the overall hydrolysis (Gruhn and Bender, 1969). [Pg.255]

Fig. 4. Extraction of pertechnetate from aqueous solutions with cyclohexanol as a function of acid concentration ... Fig. 4. Extraction of pertechnetate from aqueous solutions with cyclohexanol as a function of acid concentration ...
Chemical/Physical. Cyclohexanol will not hydrolyze in water because it does not contain a hydrolyzable functional group (Kollig, 1993). [Pg.330]

Fig 6.115. Gibbs energy change for adsorption of organic substances on different crystal faces of various metals, as a function of the corresponding potential of zero charge cyclohexanol (1), camphor (2), cyclohexanol (3), diethylether (4), and cyclohexanol (5). (Reprinted from S. Trasatti, Russ. J. Electrochem. 31 713, 1995, Fig. 7.)... [Pg.264]

You can also catalytically reduce aldehydes and ketones to produce 1° and 2° alcohols. Reduction conditions are very similar to those used to reduce alkene double bonds. If a molecule possesses both a double bond and an aldehyde or ketone functional group, reduction of the aldehyde or ketone group is best carried out using sodium borohydride. The reduction of cyclohexanone by hydrogen gas with a platinum catalyst produces cyclohexanol in good yield. [Pg.83]

Recently, a putative olfactory receptor from Drosophila, Or43a (Clyne et al., 1999 Vosshall et al., 1999), has been expressed in Xenopus laevis oocytes (Wetzel et al., 2001). The receptor expressed in a heterologous cell system was activated by four odorants, i.e. cyclohexanone, cyclohexanol, benzaldehyde, and benzyl alcohol (Wetzel et al., 2001). These experiments not only provided direct evidence for the function of the Or gene, but also demonstrated that the olfactory receptor can be stimulated without an odorant-binding protein. It was demonstrated earlier that PBP was not necessary to obtain pheromone-dependent responses in cultured olfactory receptor neurons of Manduca sexta (Stengl et al., 1992). The possibility that OBPs have been produced in vitro and were present in cultured ORNs could not be excluded. The same argument can not be raised for the heterologous expression of the Drosophila olfactory receptor. While the evidence that Xenopus oocytes responded to odorants in the absence of OBPs does not support the OBP-odorant complex model, it also demonstrated that OBPs are essential for the kinetics of the olfactory system (see below). [Pg.456]

Fig. 6.23. Effect of thermal (a) and UV initiation (b), type of comonomer, and percentage of 1-dodecanol in the polymerization mixture on the mode pore diameter of quinidine-functionalized chiral monoliths. (Reprinted with permission from [56]. Copyright 2000 American Chemical Society). Reaction conditions polymerization mixture, chiral monomer 25 8 wt%, glycidyl methacrylate ( ) or 2-hydroxyethyl methacrylate ( ) 16 wt%, ethylene dimethacrylate 16 wt%, porogenic solvent 60 wt% (consisting of 1-dodecanol and cyclohexanol), polymerization time 20 h at 60°C (a) and 16 h at room temperature (b). Fig. 6.23. Effect of thermal (a) and UV initiation (b), type of comonomer, and percentage of 1-dodecanol in the polymerization mixture on the mode pore diameter of quinidine-functionalized chiral monoliths. (Reprinted with permission from [56]. Copyright 2000 American Chemical Society). Reaction conditions polymerization mixture, chiral monomer 25 8 wt%, glycidyl methacrylate ( ) or 2-hydroxyethyl methacrylate ( ) 16 wt%, ethylene dimethacrylate 16 wt%, porogenic solvent 60 wt% (consisting of 1-dodecanol and cyclohexanol), polymerization time 20 h at 60°C (a) and 16 h at room temperature (b).
Although the first preparation of pentacene reported by Clar in 1929 proceeded by the dehydrogenation of a difficult to prepare precursor molecule (9, Scheme 3.1) [23], most modern syntheses of pentacene and its end-functionalized derivatives proceed via the reduction of pentacenequinones, typically by the action of aluminum amalgam in cyclohexanol (Scheme 3.2) [24]. [Pg.60]

Isomerization during hydrogenation may alter the functional groups present in the molecule. For instance, reduction of cyclohexen-2-ol over 5% platinum-on-carbon occurred with rapid absorption of 1 mole of hydrogen at substantially constant rate and quantitative formation of cyclohexanol. On the other hand, reduction over palladium ceased abruptly at about two-thirds of a mole, and the product was a mixture of cyclohexanol and cyclohexanone, the latter arising through double bond migration to the enol of cyclohexanone (29). [Pg.153]

Monocyclic monoterpenes include the fully saturated menthol (5-methyl-2-isopropyl-cyclohexanol) (C6) (peppermint smell), the fully unsaturated analogue thymol (5-methyl-2-isopropylphenol) (G6) (smell of thyme) and the partially unsaturated a-terpinene (5,6-dihydro-4-isopropyltoluene) (G6) (lemon odour). Variants derive from different degrees of unsaturation and substitution and from different functional groups (e.g. alkyl, hydroxyl, aldehyde, peroxy and keto groups). [Pg.35]

The procedure is commendable for its sinq>licity, reduced toxicity (chromium in all its oxidation states is carcinogenic) and achieves good yields of ketones from alcohol, for example, octan-2-ol is oxidized into octan-2-one (92%), cyclohexanol into cyclohexanone (90%) and menthol into menthone (98%). Pyridinium chromate is also a well-known oxidant for allylic oxidations. As a silica gel supported reagent, this is turned into an efficient alcohol oxidant that will leave acid-labile functions unscathed. Another advantage of the reagent is the long shelf-life of more than a year. These solid-supported oxidants also greatly facilitate pr uct work-up, when compared with their solution counterparts. [Pg.845]


See other pages where Cyclohexanols functionalized is mentioned: [Pg.391]    [Pg.541]    [Pg.74]    [Pg.36]    [Pg.104]    [Pg.347]    [Pg.99]    [Pg.64]    [Pg.299]    [Pg.41]    [Pg.121]    [Pg.216]    [Pg.91]    [Pg.413]    [Pg.45]    [Pg.492]    [Pg.492]    [Pg.1190]    [Pg.286]    [Pg.391]    [Pg.130]    [Pg.130]    [Pg.664]    [Pg.290]    [Pg.108]    [Pg.54]    [Pg.135]    [Pg.44]    [Pg.158]    [Pg.100]    [Pg.29]    [Pg.235]    [Pg.625]    [Pg.625]   


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Cyclohexanol

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