Crystal cooling device

Hajdu, J., McLaughlin, P. J., Helliwell, J. R., Sheldon, J., and Thompson,. 4 W. Universal crystal cooling device for precession cameras, rotation camera and diffractometer. J. Appl. Cryst. 18, 528-532 (1985). 

Figure 5.32 Crystal cooling device for temperatures down to 100 K. From Bartunik and Schubert (1982) with permission.

Fig. 9.1. Modern area detector diffractometer (Bruker-Nonius Kappa APEX II) with sealed-tube Mo-radiation source and low-temperature cooling device in Jyvaskyla University X-ray diffraction laboratory. The blow-up picture shows the goniometer head into which the crystal under study has been mounted.

There are several process requirements for the preparation of polypropylene staple with permanent three-dimensional helical curvature. Specifically, a rectangular spinneret-pack assembly is used to produce flow perturbation and to impart high internal stress. A specially designed cooling device cools the fiber quickly to form a paracrystalline structure in the fiber. The process principle is that the flow perturbed in the polypropylene melt creates internal stress on one side of the fiber section. Because of the stress memory of polypropylene, the internal stress difference at the interface of streamlined and perturbed flows can sustain in the fiber after it has been cooled and solidified. This leads to different crystal structures and shrink properties, and thus a fiber in the shape of a three-dimensional helix. 

The mother liquor of the last repeated crystallization step, which cannot be further worked up for sucrose, is - sucrose molasses. For white sugar production, the raw sugar in the centrifuge is stripped with hot water to remove the brown syrups and thereafter transferred for drying into air-drying cooling devices. 

Where substances are sufficiently stable, removal of solvent from recrystallised materials presents no problems. The crystals, after filtering at the pump (and perhaps air-drying by suction), are heated in an oven above the boiling point of the solvent (but below this melting point of the crystals), followed by cooling in a desiccator. Where this treatment is inadvisable, it is still often possible to heat to a lower temperature under reduced pressure, for example in an Abderhalden pistol. This device consists of a small chamber which is heated externally by the vapour of a boiling solvent. Inside this chamber, which can be evacuated by a water pump or some other vacuum pump, is... 

M Preparation of isopropyiidene peniciiiamine hydrochioride To the filtrate obtained In step (b) is added at 20°C to 25°C a total of 85 g of hydrogen sulfide. The precipitated HgS is filtered off and the filtrate is concentrated under reduced pressure to a volume of 200 to 500 ml. Following e polish filtration, the product-rich concentrate is mixed with 1.5 liters of isobutyl acetate. The mixture is refluxed at about 40 C under reduced pressure in equipment fitted with a water separation device. When no further water separates, the batch is cooled to 30t and filtered. The reactor is washed with 1 liter of acetone, which Is used also to wash the cake. The cake is further washed with 200 ml of acetone. The acetone washes are added to the isobutyl acetate filtrate and the mixture is refluxed for 20 to 30 minutes. After a holding period of one hour at 5°C, the crystals of isopropyiidene penicillamine hydrochloride are filtered and washed with 200 m of acetone. On drying for twelve hours at 25°C this product, containing 1 mol of water, weighs about 178 g (73%). 

In order to study dynamic aspects of biomolecular structure, it is necessary to perform measurements over an appropriate temperature range. This is accomplished by directing dry air downward over the sample cell from the nozzle of a device used to cool protein crystals in X-ray... 

---