Corrosion fatigue cyclic stress

Stress below the proof stress does not normally affect corrosion rates. Cyclic stresses in combination with a corrosive environment (corrosion fatigue) can produce failure at below the ordinary fatigue limit. Alloys susceptible to intergranular attack may corrode faster when stressed (see Section 8.5). 

Corrosion fatigue, resulting from the combined effects of corrosion and cyclic stresses. Racks of Ihis type are characteristically Iranscrystalline. 

Corrosion fatigue is the phenomenon where the strength would be reduced under the conditiOTi of corrosion and cyclic stresses. Also in this case, the life cycle of material is reduced significantly. 

If, however, the material under cyclic stress is subject to a corrosive environment, the endurance limit of the material is sharply reduced. The premature failure of a material from the exposure to the combined action of corrosion and cyclic stress is called "Corrosion Fatigue. ... 

Corrosion fatigue is a type of failure (cracking) which occurs when a metal component is subjected to cyclic stress in a corrosive medium. In many cases, relatively mild environments (e.g., atmospheric moisture) can greatly enhance fatigue cracking without producing visible corrosion. 

Corrosion Fatigue Corrosion fatigue is a reduction by corrosion of the abihty of a metal to withstand cyclic or repeatea stresses. 

Several theories have been proposed to explain the corrosion-fatigue phenomena. One is that cyclic stressing causes repeated rupture of protective coatings. Corrosion-fatigue cracks propagate as the coating is successively reformed and ruptured along a plane. 

No common industrial metal is immune to corrosion fatigue since some reduction of the metal s resistance to cyclic stressing is observed if the metal is corroded, even mildly, by the environment in which the stressing occurs. Corrosion fatigue produces fine-to-broad cracks with little or no branching. They are typically filled with dense corrosion product. The cracks may occur singly but commonly appear as families of parallel cracks (Fig. 10.2). They are frequently associated with pits, grooves, or other forms of stress concentrators. Like other forms of... 

Perhaps the most important stress factor affecting corrosion fatigue is the frequency of the cyclic stress. Since corrosion is an essential component of the failure mechanism and since corrosion processes typically require time for the interaction between the metal and its environment, the corrosion-fatigue life of a metal depends on the frequency of the cyclic stress. Relatively low-stress frequencies permit adequate time for corrosion to occur high-stress frequencies may not allow sufficient time for the corrosion processes necessary for corrosion... 

Alter the environment to render it less eorrosive. This approach may be as simple as maintaining clean metal surfaces. It is well known that the chemistry of the environment beneath deposits can become substantially different than that of the bulk environment. This difference can lead to localized, underdeposit corrosion (see Chap. 4, Underdeposit Corrosion ). The pit sites produced may then induce corrosion fatigue when cyclic stresses are present. The specific steps taken to reduce corrosivity vary with the metal under consideration. In general, appropriate adjustments to pH and reduction or elimination of aggressive ions should be considered. 

Intergranular corrosion-fatigue cracks in copper may he difficult to differentiate from stress-corrosion cracking. The longitudinal orientation of the cracks revealed that the cyclic stresses were induced by fluctuations in internal pressure. 

The simultaneous action of cyclic stress alternating tensile and compressive and corrosive attack is known as corrosion fatigue. Corrosive attack can be in the form of pitting. These pits function as notches, acting as stress risers and initiate cracks. Once a crack is formed, the probability of pipe failure is enhanced by further corrosion as corrosion is accelerated by action of stress. The tip of the crack deep within the fracture, the area under the greatest stress, is anodic to the wider part of the crack. As corrosion progresses, the metal at the tip of the crack goes into the solution, the crack deepens and eventually penetrates the wall of the tube. 

Barsom, J. M., Effect of cyclic stress waveform on corrosion fatigue crack propagation... 

Undue static or cyclic stressing and other features which give rise to stress concentrations should be avoided as these may lead to premature failure by stress-corrosion cracking or corrosion fatigue. 

It is often difficult to conduct laboratory tests in which both the environmental and stressing conditions approximate to those encountered in service. This applies particularly to the corrosive conditions, since it is necessary to find a means of applying cyclic stresses that will also permit maintenance around the stressed areas of a corrosive environment in which the factors that influence the initiation and growth of corrosion fatigue cracks may be controlled. Among these factors are electrolyte species and concentration, temperature, pressure, pH, flow rate, dissolved oxygen content and potential (free corrosion potential or applied). 

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