Copper myristate

Figure 16.35 (Plate 2). All copper myristate. Top left lOOx crossed polars, 70°C - lamellar. Top right lOOx crossed polars, 6.3°C - lamellar. Middle left lOOx crossed polars, 40.0°C - hexagonal. Bottom left 200x crossed polars, ]9S°C - hexagonal. Bottom right lOOx parallel polars, cooled from 190.8°C to room temperature -/ we//ar with remnant hexagonal textures...

Copper Organo-copper compounds with fatty acids Copper myristate... 

Calcium myristate Cerium stearate Copper acetate (ic) Copper bromide (ous) Copper iodide (ous) p-Cresol/dicyclopentadiene butylated reaction product 2,6-Di-t-butyl-4-ethyl phenol... 

Nikkol Batyl Alcohol 100, EX 544-63-8 C-1495 Emery 654 Emery 655 Emery 6355 Hystrene 9014 Hystrene 9514 Kartacid 1495 Kartacid 1498 Myristic acid NAA-142 Philacid 1400 Prifrac 2940 Prifrac 2942 544-76-3 n-Hexadecane 544-92-3 Copper cyanide... 

Several reports of late have described aromatic C-N bond formations using aryl boronic acids and copper catalysis. Initial reports from DuPont on this topic in the late 1990s relied on stoichiometric Cu(OAc)2, but more recently, it has been shown that reduced levels of copper (5-10%) can be used, together with myristic acid (10-20 mol%), forming diarylamines (Eqn. 1-5). ° Representative products, and yields, are shown below (32-35). 

The reaction could also be extended to an interesting two-step process, in which 2-allylaniline was first submitted to an oxidative aryl coupling with phenylboronic acid and copper(II) diacetate and myristic acid to give the N-arylated derivative, which was then submitted to catalytic carboamination reaction by the addition of manganese dioxide and base. 

Birnboim HC (1982) DNA strand breakage in human leukocytes exposed to a tumor promotor, phorbol myristate acetate. Science 215 1247-1249 Bryan SE, Simon SJ, Vizard DL, Hardy KJ (1976) Interaction of mercury and copper with constitutive heterochromatin and euchromatin in vivo and in vitro. Biochemistry 15 1667-1676... 

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