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Copper, organo compounds reactions with

Coupling of acetylenes and halides, copper-promoted, 50,100 Cuprous chloride, reaction with an organo-magnesium compound, 50,98... [Pg.77]

Stereoselectivity in Michael additions of organo-copper(I) compounds Trapping the enolate intermediate by silylation Michael Addition followed by Reaction with Electrophiles Tandem Michael/aldol reactions A Double Nucleophile An Interlude without Copper... [Pg.127]

The Cadiot-Chodkiewcz and Glaser reactions are the synthetic reaction with acetylene type compounds. As the acetylene compounds easily form stable organo-copper compounds, these acetylenecopper compounds react directly with halides to afford the acetylene derivatives. This synthetic reaction is called the Castro reaction [43]. For example, as shown in eq. (22.22), aryl compounds having functional groups such as OMe, NO2 and COOH are able to condense with copper acetylides... [Pg.499]

The reaction described is of considerable general utility for the preparation of benzoyloxy derivatives of unsaturated hydrocarbons.2"8 Reactions of 2-butyl perbenzoate with various other classes of compounds in the presence of catalytic amounts of copper ions produce benzoyloxy derivatives. Thus this reaction can also be used to effect one-step oxidation of saturated hydrocarbons,9, 10 esters,6,11 dialkyl and aryl alkyl ethers,12 14 benzylic ethers,11,15 cyclic ethers,13,16 straight-chain and benzylic sulfides,12, 17-19 cyclic sulfides,11,19 amides,11 and certain organo-silicon compounds.20... [Pg.97]

The difficulties of direct oxidative insertion with metals other than Mg or Li mean that o-complexes are often made from organo-lithium or Grignard reagents by metal exchange. This reaction amounts to a nucleophilic substitution at the metal without a change of oxidation state so the metal is used in whatever oxidation state is finally needed. Attack of methyl lithium on a Cu(I) halide gives methyl copper 50, a o-complex of Me- and Cu(I). If an excess of MeLi is present an ate complex is formed, lithium dimethylcuprate 51. This is formally a compound of a copper anion 51a, just as BF4 is a borate. The term ate complex refers to such formally anionic complex in which the metal has one extra anionic ligand. Its true structure is dimeric 51b and it exists as an equilibrium with 52 in solution.20... [Pg.119]


See other pages where Copper, organo compounds reactions with is mentioned: [Pg.224]    [Pg.228]    [Pg.242]    [Pg.132]    [Pg.94]    [Pg.230]    [Pg.616]    [Pg.228]    [Pg.267]    [Pg.214]    [Pg.414]    [Pg.5233]    [Pg.59]    [Pg.7]    [Pg.674]    [Pg.143]    [Pg.285]    [Pg.28]    [Pg.201]    [Pg.154]    [Pg.45]    [Pg.329]    [Pg.45]    [Pg.329]    [Pg.727]    [Pg.346]    [Pg.169]    [Pg.224]    [Pg.501]    [Pg.519]    [Pg.15]    [Pg.3]    [Pg.45]    [Pg.329]    [Pg.167]    [Pg.226]    [Pg.316]    [Pg.1043]    [Pg.436]    [Pg.76]   


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Copper compounds

Copper, organo compounds

Organo compounds

Organo reactions with

Reaction with copper

With Copper

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