Copper® acetate-iron sulfate

Subsequent reaction of porphyrazines 170 and 171 with Cu(OAc)2 resulted in the selective metalation within the macrocyclic cavity to provide the corresponding copper complexes 166 (62%) and 172 (47%). Treatment of pz 170 with manganese acetate and iron sulfate in dimethyl sulfate gave the dmso adducts 173 (70%) and 174 (85%), respectively (168). Axial ligation was also observed when other metals were incorporated such as cobalt acetate, nickel acetate, and zinc acetate to give the metal complexes 175 (83%), 176 (70%), and 177 (90%) as the hydrates. The axial ligand of... 

Synonym Neatsfoot Oil Necatorina Nechexane Neutral Ahhonium Pluoride Neutral Anhydrous Calcium Hypochlorite Neutral Lead Acetate Neutral Nicotine Sulfate Neutral Potassium Chromate Neutral Sodium Chromatetanhydrous Neutral Verdigris Nickel Acetate Nickel Acetate Tetrahyorate Nickel Ammonium Sulfate Nickel Ammonium Sulfate Hexahydrate Nickel Bromide Nickel Bromide Trihydrate Nickel Carbonyl Nickel Chloride Nickel Chloride Nickel Cyanide Nickel Iiu Fluoborate Nickel Fluoroborate Solution Nickel Fluoroborate Nickel Formate Nickel Formate Dihyorate Nickel Nitrate Nickel Nitrate Hexahydrate Nickel Sulfate Nickel Tetracarbokyl Nickelous Acetate Nickelous Sulfate Nicotine Nicotine Sulfate Nifos Nitralin Nitram O-Nitraniline P-Nitraniline Nitric Acid Nitric Acid, Aluminum Salt Nitric Acid, Iron (111) Salt Compound Name Oil Neatsfoot Carbon Tetrachloride Neohexane Ammonium Fluoride Calcium Hypochlorite Lead Acetate Nicotine Sulfate Potassium Chromate Sodium Chromate Copper Acetate Nickel Acetate Nickel Acetate Nickel Ammonium Sulfate Nickel Ammonium Sulfate Nickel Bromide Nickel Bromide Nickel Carbonyl Nickel Chloride Nickel Chloride Nickel Cyanide Nickel Fluoroborate Nickel Fluoroborate Nickel Fluoroborate Nickel Formate Nickel Formate Nickel Nitrate Nickel Nitrate Nickel Sulfate Nickel Carbonyl Nickel Acetate Nickel Sulfate Nicotine Nicotine Sulfate Tetraethyl Pyrophosphate Nitralin Ammonium Nitrate 2-Nitroaniline 4-Nitroaniline Nitric Acid Aluminum Nitrate Ferric Nitrate... 

Diethylamino)sulfur trifluoride, 110 Formylation (see also Carbonylation) Vilsmeier reagent, 341 Fragmentation reactions Cerium(IV) ammonium nitrate, 67 Copper(II) acetate-Iron(II) sulfate, 85 Lead tetraacetate, 155 Friedel-Crafts alkylation Aluminum chloride, 15... 

Copper(II) acetate-Iron(II) sulfate, 85 Dicyclohexylcarbodiimide- 4- Dimethyl-aminopyridine, 107... 

Cobalt(III) fluoride, 397 Cobalt(II) phthalocyanine, 102-103 Collman s reagent, 174-175 6-Coniceine, 398 Coniferyl alcohol, 351 Cope rearrangement, 31,311 Copper(ll) acetate, 103, 211 Copper(fl) acetate-Iron(II) sulfate, 103-104 Copper(I) bromide-Diinethyl sulfide, 104-105... 

RH+)-p-Tolylsulfmylacetic acid. MACROLIDES Copper(ll) acetate-Iron(II) sulfate. Copper(I) trifluoro-methylsulfonate. Cyanuric chloride. Di-n-butyltin oxide. N-Methyl-N-phenylaminocthynyllithium. Oxygen, singlet... 

Related Reagents. Copper(I) Acetate Copper(II) Acetate-Iron(n) Sulfate lodine-Copper(II) Acetate Lead(IV) Acetate-Copper(II) Acetate Manganese(III) Acetate-Copper(II) Acetate Sodium Hydride-Copper(II) Acetate-Sodium f-Pentoxide Zinc-Copper(II) Acetate-Silver Nitrate. 

Write the formula for each of the following compounds (a) hydrogen iodide, (b) calcium chloride, (c) lithium oxide, (d) silver nitrate, (e) iron(II) sulfide, (/) aluminum chloride, (g) ammonium sulfate, (h) zinc carbonate, (/) iron(lll) oxide, ( ) sodium phosphate, (k) iron(H) acetate, (/) ammonium cyanide, and (m) copper(II) chloride. 

For patients who are unable to tolerate penicillamine, trientine, another chelating agent, may be used in a daily dose of 1-1.5 g. Trientine appears to have few adverse effects other than mild anemia due to iron deficiency in a few patients. Zinc acetate administered orally increases the fecal excretion of copper and is sometimes used for maintenance therapy. The dose is 50 mg three times a day. Zinc sulfate (200 mg/d orally) has also been used to decrease copper absorption. Zinc blocks copper absorption from the gastrointestinal tract by induction of intestinal cell metallothionein. Its main advantage is its low toxicity compared with that of other anticopper agents, although it may cause gastric irritation when introduced. 

A powder which burns with a green flame is obtained by the addition of nitrate of baryta to chlorate of potash, nitrate of potash, acetate of copper. A white flame is made by the addition of sulfide of antimony, sulfide of arsenic, camphor. Red by the mixture of lampblack, coal, bone ash, mineral oxide of iron, nitrate of strontia, pumice stone, mica, oxide of cobalt. Blue with ivory, bismuth, alum, zinc, copper sulfate purified of its sea water [sic]. Yellow by amber, carbonate of soda, sulfate of soda, cinnabar. It is necessary in order to make the colors come out well to animate the combustion by adding chlorate of potash.15... 

The function of the chelator is to complex the ferrous ion and thus limit the concentration of free iron. Redox systems appear very versatile, permitting polymerization at ambient temperatures and the possibility of control of the rate of radical initiation versus polymerization time. This would thus permit control of heal generation and the minimization of reaction time. The use of the redox system ammonium persulfate (2 mmol) together with sodium pyrosulfite (Na S Oj 2.5 mmol) together with copper sulfate (0.002 mmol) buffered with sodium bicarbonate in I liter of water form an effective redox system for vinyl acetate emulsion polymerization. The reaction was started at 25 C and run nonisothermally to 70 C. The time to almost complete conversion was 30 min (Warson, 1976 and Edelhauser, 1975). 

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