Convection, strong

In considering the effect of mass transfer on the boiling of a multicomponent mixture, both the boiling mechanism and the driving force for transport must be examined (17—20). Moreover, the process is strongly influenced by the effects of convective flow on the boundary layer. In Reference 20 both effects have been taken into consideration to obtain a general correlation based on mechanistic reasoning that fits all available data within 15%. 

For various reasons, this type of anemometer is not a suitable instrument for practical measurements in the industrial environment. The thin wire probe is fragile and sensitive to contamination and is unsuited to rough industrial environments. The wire temperature is often too high for low-velocity measurements because a strong natural convection from the wire causes errors. Temperature compensation, to correct for ambient air temperature fluctuations may not be available or may not cover the desired operating range. 

Be meeker Price (B P) (Ref 69a) present strong evidence for the convective flame front—... 

For the region near the attachment point, Mullis found a strong effect of axial position on flux, but no satisfactory general correlation for this effect. In addition, he found no quantitative relation for the heat-transfer characteristics of jets directed toward the propellant surface. Under most conditions studied by Mullis, the radiation contribution is approximately 10% of the convective flux. The effects of solid-particle impingement were not investigated. 

The detail experimental study of flow boiling heat transfer in two-phase heat sinks was performed by Qu and Mudawar (2003b). It was shown that the saturated flow boiling heat transfer coefficient in a micro-channel heat sink is a strong function of mass velocity and depends only weakly on the heat flux. This result, as well as the results by Lee and Lee (2001b), indicates that the dominant mechanism for water micro-channel heat sinks is forced convective boiling but not nucleate boiling. 

The large viscosity increases that accompany increased polymer concentrations have a strong effect on reactor performance. This phenomenon is illustrated through a simplified yet realistic example (also used in Reference 1 to study the effects of radial convection). In this case the polymerization rate is first order in monomer concentration and the physical properties are constant, except for viscosity, which is given by the following expression ... 

It is important to note that even in a strongly stirred solution, a thin layer of stagnant liqnid is present directly at the electrode surface, within which convection is absent so that snbstances involved in the reaction are transported in it only by diffnsion and migration. Here the concentration gradient (grad c ) =o steepest and (in the absence of convection) determined by the balance equation... 

This discrepancy arises primarily from the fact that spontaneous liquid flows will always develop in any hquid even without artificial stirring (e.g., under the action of density gradients caused by local temperature or concentration fluctuations). This phenomenon has been termed natural convection. Electrochemical reactions reinforce natural convection, since the concentrations of substances involved in the reaction will change near the electrode surfaces, and also since heat is evolved. Gas evolution attending the reactions has a particularly strong effect on naturaf convection. 

Natural convection depends strongly on cell geometry. No convection can arise in capillaries or in the thin liquid layers found in narrow gaps between electrodes. The rates of natural convective flows and the associated diffusion-layer thicknesses depend on numerous factors and cannot be calculated in a general form. Very rough estimates show that the diffusion-layer thickness under a variety of conditions may be between 100 and 500 pm. 

In steady-state measurements at current densities such as to cause surface-concentration changes, the measuring time should be longer than the time needed to set up steady concentration gradients. Microelectrodes or cells with strong convection of the electrolyte are used to accelerate these processes. In 1937, B. V. Ershler used for this purpose a thin-layer electrode, a smooth platinum electrode in a narrow cell, contacting a thin electrolyte layer. 

Experimental gas-solid mass-transfer data have been obtained for naphthalene in CO2 to develop correlations for mass-transfer coefficients [Lim, Holder, and Shah, Am. Chem. Soc. Symp. Ser, 406, 379 (1989)]. The mass-transfer coefficient increases dramatically near the critical point, goes through a maximum, and then decreases gradually. The strong natural convection at SCF conditions leads to higher mass-transfer rates than in liquid solvents. A comprehensive mass-transfer model has been developed for SCF extraction from an aqueous phase to CO2 in countercurrent columns [Seibert and Moosberg, Sep. Sci. Techrwl, 23, 2049 (1988) Brunner, op. cit.]. 

An entirely different type of transport is formed by thermal convection and conduction. Flow induced by thermal convection can be examined by the phaseencoding techniques described above [8, 44, 45] or by time-of-flight methods [28, 45]. The latter provide less quantitative but more illustrative representations of thermal convection rolls. The origin of any heat transport, namely temperature gradients and spatial temperature distributions, can also be mapped with the aid of NMR techniques. Of course, there is no direct encoding method such as those for flow parameters. However, there are a number of other parameters, for example, relaxation times, which strongly depend on the temperature so that these parameters can be calibrated correspondingly. Examples are described in Refs. [8, 46, 47], for instance. 

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