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Conservative elements determinations

Because D-AspRS and AsnRS select tRNA and tRNA , respectively, they recognize distinct elements in each tRNA whereas ND-AspRS that aspartylates both tRNAs recognizes elements common to the two tRNAs. Most tRNA P identity elements are conserved in the various species " recognition of tRNA by AspRS occurs by a similar pattern. "" Study of the tRNA elements determining aspartylation by the D- and ND-AspRSs from T. thermophilus, AspRS 1 and AspRS2 respectively, has shown that with only one exception the same nucleotides determine aspartylation by the two AspRSs. " Specificity of each AspRS is related to distinct... [Pg.406]

Such conserved elements can be identified by comparing the sequences of RTs from different retrovimses the functions and relative importance of these conserved elements can be determined by mutagenesis and biochemical and structural analyses. It is our hope that application of stmcture-based drug design strategies may aid in the development of novel HIV-1 RT inhibitors for a more effective treatment of HIV-1 infection. [Pg.70]

Analytical Chemical Data for Natural Waters. While elemental compositions of various natural waters usually can be determined with good reliability, analytical methods to distinguish between free and complex-bound species, oxidized and reduced forms, simple and polynuclear metal ion forms, and even between dissolved and colloidal or suspended phases are often lacking. Data on the nature and amounts of the individual substances which make up the total concentrations of organic material found in different natural waters are not yet extensive. These analytical deficiencies relate almost solely to the highly reactive, non-conservative elements—e.g., iron, manganese, phosphorus, carbon, nitrogen, aluminum, and other metal ions. [Pg.17]

To within a few percent, conservative elements in seawater have constant concentration salinity ratios. That is, their concentrations are not greatly affected by processes other than precipitation and evaporation the same processes that control salinity in the ocean. This definition is of course operational since the ability to determine the effect of biological and chemical processes on concentration depends on the accuracy and precision of the measurement method. Elements of high concentration tend to be conservative because they are relatively unreactive however, conservative elements are present in all concentration ranges because some of them are both low in crustal abundance and relatively unreactive. There are of course... [Pg.12]

A direct geochemical check on the particle flux of organic matter from the euphotic zone determined by sediment traps is achieved by using the mass balance of thorium isotopes in surface waters. Since decay systematics and chemistry of the uranium series isotopes were introduced in Chapter 5, we will only briefly reiterate them here. is relatively unreactive in oxic seawater and exists in the ocean as a conservative element, i.e. the concentration normalized to salinity is everywhere the same to within measurement error. decays to which is very reactive to particles and has a relatively short radioactive half life of 24.1 d ... [Pg.193]

For the application of this method on sediment parameters it will be necessary to determine an enrichment factor corrected for grain size on the basis of conservative elements (Chapter 3.3). [Pg.110]

S04 see Conservative Elements). The analytical results reported by W. Dittmar in 1884 for waters collected during the British RMS Challenger Expedition (1872-1876) from the world s oceans were almost the same as today s values. The constancy of major chemical composition has led oceanographers to define salinity as a fundamental property together with temperature to calculate the density of sea water. It was routine for classic physical oceanographers to titrate sea water for chloride (plus bromide) ion with silver nitrate standard solution, until the mid 1960s when salinity could be determined more practically by measurement of conductivity. [Pg.7]

At the wider level, it is crucial that safety assessment experts communicate their belief that their calculated results, although imperfect, provide sufficiently reliable input for decision makers. Numerical results of analyses extending out to geological times, if presented without sufficient discussion of their significance, lead understandably to accusations of over-optimism, immodesty or even irrationality. On the other hand, failiure to emphasise the conservative nature of safety analyses and the existence of a broad base of scientific facts which make estimates scientifically justifiable would dqprive decision makers and public of a crucial element determining their confidence in and acceptance of waste repositories. [Pg.248]

Dividing computational geometry into primitive shapes is needed to solve the conservation equations explained in Section 6.2 for each mesh element. The number of elements in a computational mesh and chosen numerical technique to solve conservation equations determines the accuracy of a computational model. If the computational mesh consists of many mesh elements, the computational... [Pg.223]

Quantitative Calculations When needed, the relationship between the analyte and the analytical signal is given by the stoichiometry of any relevant reactions. Calculations are simplified, however, by applying the principle of conservation of mass. The most frequently encountered example of a direct volatilization gravimetric analysis is the determination of a compound s elemental composition. [Pg.260]

The equation that expresses conservation of energy can also be determined by considering Fig. 2.3. Since the piston moves a distance u At, the work done by the piston on the fluid during this time interval is Pu At. The mass of material accelerated by the shock wave to a velocity u is PqU At. The kinetic energy acquired by this mass element is therefore (pqUu ) At/2. If the specific internal energies of the undisturbed and shocked material are denoted by Eq and E, respectively, the increase in internal energy is ( — o)Po V At per unit mass. The work performed on the system is equal to the sum of kinetic and... [Pg.10]

We can use the ideal gas equation to calculate the molar mass. Then we can use the molar mass to identify the correct molecular formula among a group of possible candidates, knowing that the products must contain the same elements as the reactants. The problem involves a chemical reaction, so we must make a connection between the gas measurements and the chemistry that takes place. Because the reactants and one product are known, we can write a partial equation that describes the chemical reaction CaC2(. ) +H2 0(/) Gas -I- OH" ((2 q) In any chemical reaction, atoms must be conserved, so the gas molecules can contain only H, O, C, and/or Ca atoms. To determine the chemical formula of the gas, we must find the combination of these elements that gives the observed molar mass. [Pg.302]

The finite-element method (FEM) is based on shape functions which are defined in each grid cell. The imknown fimction O is locally expanded in a basis of shape fimctions, which are usually polynomials. The expansion coefficients are determined by a Ritz-Galerkin variational principle [80], which means that the solution corresponds to the minimization of a functional form depending on the degrees of freedom of the system. Hence the FEM has certain optimality properties, but is not necessarily a conservative method. The FEM is ideally suited for complex grid geometries, and the approximation order can easily be increased, for example by extending the set of shape fimctions. [Pg.148]

The electron is excited from a filled initial state f below the Fermi level F to an empty final state f above F. Momentum conservation will be provided by a lattice vector or in some cases by a surface vector. The transition probability is mainly determined by the optical excitation matrix element containing the joint density of states. [Pg.78]

In the case of an equilibrium system the Hamiltonian is the same as that of an ensemble of conservative systems in statistical equilibrium. If the energy of the system is measured to lie between Ek and EK + AE, then the representative ensemble is also restricted to the energy shell [AE K. From the hypotheses of equal a priori probabilities and random a priori phases it then follows that the diagonal elements of the density matrix lying inside [AE]k are all equal and that all others vanish. The density matrix of the quantum statistical microcanonical ensemble is thereby determined as... [Pg.466]


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See also in sourсe #XX -- [ Pg.13 ]




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