Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Composition fixed

A solution containing a relatively high concentration of inert electrolytes such that its composition fixes the ionic concentration of all solutions to which it is added. [Pg.487]

During flash-fire propagation, the cloud s location is assumed to be stationary, and its composition fixed and homogeneous. [Pg.153]

Equation (5.16) can be integrated. We expect the partial molar properties to be functions of composition, and of temperature and pressure. For a system at constant temperature and constant pressure, the partial molar properties would be functions only of composition. We will start with an infinitesimal quantity of material, with the composition fixed by the initial amounts of each component present, and then increase the amounts of each component but always in that same fixed ratio so that the composition stays constant. When we do this. Z, stays constant, and the integration of equation... [Pg.208]

Two variables can be varied independently. Specifying the pressure and temperature fixes the composition, specifying the pressure and composition fixes the temperature, or specifying the temperature and composition fixes the pressure. [Pg.238]

Three variables are specified the feed flow and composition fixes the flow of each component in the feed. [Pg.44]

The standard free energy is therefore determined by measurement of the mixture CMC holding the micellar composition fixed. This analysis assumes that a is known as a function of temperature and micellar composition and is independent of the electrolyte composition. The heat of micellization cannot be determined from measurement of the temperature dependence of CMCj( without knowledge of the micellar composition and of a. Interpretation of calorimetric data is not possible without information regarding micellar composition. Ultrafiltration techniques designed to measure micellar compositions, take an added importance when considering heats of micellization. [Pg.34]

Site composition fixed at 0.90 Tl + 0.10 Ca. However, site can also be modeled as containing only thallium with 7.5% vacancies. [Pg.509]

Calculated atomic positions lattice parameters taken from reference 25. Atom displaced from la sites to 41 sites with quarter occupancy. SOccupancy factor refined to 0.94(1) atom/site. hSite composition fixed at 0.83 Ca + 0.17 Tl. [Pg.511]

Composite fixing cements were prepared based on a standard methacrylate mixture and incorporating either the step 1 product or a mixture of camphorquinone and p-N, -d i met h I am i n be nzoic acid ethyl ester using an Exakt Apparatebau model roll mill. Testing results are summarized in Table 1. [Pg.423]

A 128-unit flexible-chain heteropolymer with a HP composition fixed at 1 1 was simulated for the condition when hydrophobic H monomers strongly attract each other, thus stabilizing a dense globular core, whereas the attraction energy epp between hydrophilic P monomers was considered as a parameter (the interaction between H and P monomers is given by hp = V hh pp). For this model system, various conformation-dependent and sequence-dependent properties, including information-theoretic-based quantities, can be calculated. [Pg.27]

Rates of reactions are functions of the thermodynamic state of the system. For a simple system, fixing temperature and composition fixes the rest of the thermodynamic quantities or the state. Thus, the rate can be written in terms of a temperature-dependent term called the rate constant k (constant at fixed temperature) and a concentration term or terms C). a. Example... [Pg.469]

Since Pf is a function of temperature only, Raoult s law is a set of N equations in the variables T, P, y,, and, . There are, in fact, N - 1 independent vapor-phase mole fractions (the y,- s), N - 1 independent liquid-phase mole fractions (the x, s), and T and P. This makes a total of 21V independent variables related by N equations. The specification of N of these variables in the formulation of a vapor/liquid equilibrium problem allows the remaining N variables to be determined by the simultaneous solution of the N equilibrium relations given here by Raoult s law. In practice, one usually specifies either T or P and either the liquid-phase or the vapor-phase composition, fixing 1 + N - 1) = N variables. [Pg.452]

Other than possibly for the insensible perspiration they absorb, transdermal patches tend to operate as thermodynamically static systems, meaning as compositionally fixed systems, from the moment they are applied until their removal. Compositional steadfastness is still the rule, however, and it is this feature that bestows the zero-order delivery attribute on the ordinary transdermal patch. Drag is present within the patches in resravoir amounts irrespective of whether or not the reservoir compartment is easily distinguished for there must be enough drag to sustain dehvery over the full course of patch wear. [Pg.87]

We call the class of component (e.g. diluent) the mqjor, or M-component. Each member of that class (lactose, cellulose, calcium phosphate) is a minor component (m-component). Instead of there being individual restrictions on each excipient, L, < x, < t/ let there be an overall restriction on the class. So if there are three polymers in a sustained release formulation, X, Xj, Xj j 3, we may, in optimizing the composition, fix the total amount of polymer between 10 and 25%, but allow the individual polymers to vary freely within that range. Therefore ... [Pg.451]

For isobaric changes in temperature, we choose the ideal gas as the reference state in (4.3.12), divide (4.3.12) by RT, and take the temperature derivative of both sides with pressure and composition fixed. On applying the Gibbs-Helmholtz equation (3.4.17), we find... [Pg.141]

As expected in a binary constant-pressure system, fixing the composition fixes the temperature. So the temperatures at the top and at the bottom do not change. In theory. [Pg.133]

TPO can be prepared either by melt mixing PP and elastomer in an extruder or by copolymerization of olefins in a series of reactors to give a blocklike structure. The reactor-made TPO produces a fine and stable morphology due to controlled reaction parameters however, they have an elastomer composition fixed by the polymerization process. On the other hand, extruder-made TPOs provide wide flexibility in... [Pg.1496]

The following techniques are useful for analysis and charaterization for the sizing on the fibres SEM, IR and 6PC of extracts, IGC and DMA (T ) for the fibre-matrix bond micro bond, micro failure with SEM [2], confocal laser scanning microscopy [3] DMA, flexural strength, ILSS and impact of the uni-directional composites (fixed fibre length, orientation and volume fraction distributions). After this detailed analysis, the fibres are tested in their application, which is an injection moulded compound for thermoplasts, where the microstructure (fibre length, fibre orientation and fibre-fibre distance distributions) as well as the fibre- matrix adhesion determine the mechanical properties. [Pg.412]

It should be noted that the content of these compounds varies considerably, but always within the rank of composition fixed by the COI standard, according to several factors, being the most important ones the olive variety [76-78] and the ripening degree of olives [79,80]. The determination of these compounds is also of major interest because their composition can be used to detect adulteration and genuineness or to check geographical origin and varietal authenticity [81]. Thereby, the study of the VOO phytosterols composition usually represents a subject of interest and... [Pg.222]

For a composition fixed close to the apex of the parabola (e.g., x = 0.4, where x is the weight ratio of 60CB/80CB) with decreasing temperature we meet the nematic, the smectic A, and again the nematic phase. The parabolic shape of the phase diagram is accounted for in terms of modern phase transition theory with a competition of the orientational and translational orders taken into account [32]. A microscopic explanation is based on the frustration phenomenon taking into account the competition between the steric and dipole-dipole interactions [38-40]. [Pg.21]

Vallittu, P.K. (2004) Survival rates of resin-bonded, glass fiber-reinforced composite fixed partial dentures with a mean follow-up of 42 months a pilot study./. Prosthet. Dent., 91, 241-6. [Pg.512]

In these transformations, the only difference between the initial and the final state is the composition of the sohd phase. The final state is characterized by a new equilibrium composition fixed by the temperature and the partial pressures of gases remained constant during the reaction. [Pg.640]


See other pages where Composition fixed is mentioned: [Pg.780]    [Pg.509]    [Pg.511]    [Pg.513]    [Pg.513]    [Pg.515]    [Pg.515]    [Pg.515]    [Pg.515]    [Pg.423]    [Pg.1133]    [Pg.257]    [Pg.430]    [Pg.107]    [Pg.110]    [Pg.263]    [Pg.60]    [Pg.30]    [Pg.532]    [Pg.709]    [Pg.1005]    [Pg.201]   
See also in sourсe #XX -- [ Pg.127 ]




SEARCH



Composition, biomass fixed carbon

Fixed-liquid compositions

Mixture of fixed composition

© 2024 chempedia.info