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Complex polymers characterization

The intent of the effort described in this paper was to obtain insight into the structure of this complex polymer and to characterize the structures present using NMR. [Pg.157]

John J. Meister, A Review of Synthesis, Characterization, and Properties of Complex Polymers for Use in the Recovery of Petroleum and Other Natural Resources, Chapter 2 in the Book Water-Soluble Polymers for Petroleum Recovery, Dr.D.N. Schulz, Dr.G.A. Stahl, Editors, Plenum Publishing Corp. 1988 ISBN 0-306-42915-2. [Pg.207]

In conclusion one can say that SEC is a very powerful method for polymer characterization, especially in combination with other composition sensitive or absolute calibration methods. A big advantage is also that the sample amount is fairly small, typically 10 mg. For more complex polymers, such as polyelectrolytes, enthalpic effects often become dominant and also for rather high molecular weight polymers chromatographic methods such as field-flow fraction (FFF) techniques might be more suitable. For fast routine measurements linear columns are often used. [Pg.232]

Imanaka—heterogenization of Rh complexes. In 1991, Imanaka and coworkers124 reported the heterogenization of Rh complexes by binding them to aminated polymers. As discussed previously, these findings led to fruitful research by Ford, Pardey, and others. The isolated polymer-bound Rh carbonyl anion complex was found to be reusable for reactions such as water-gas shift and reduction of nitro compounds. The polymer-bound Rh complexes were characterized by infrared spectroscopy. Water-gas shift activity (80 mol H2 per mol Rh6(CO)i6 in 24 hours) was recorded using the Rh complexes at 100 °C with 0.92 atm of CO, 2.16 ml H20, 0.05 mmol Rh6(CO)16, aminated polystyrene, 5.0 mmol of N, 5.56 ml ethoxyethanol and reduction of nitro-compounds (e.g., aliphatic nitro compounds to nitriles, oximes to nitriles, hydroxylamines to nitriles, and N-oxides to amines) occurred at 40 °C. [Pg.170]

Semiconducting black polymers characterized as 44 have been prepared via slow heating of triple-decker (allyl)nickel diborolyl triple-decker complexes.44 EXAFS studies reveal an Ni-Ni distance of 3.35 A and a powder conductivity of ca. 10-2 S cm-1. When doped with iodine or oxygen, the conductivity of these polymers... [Pg.15]

The combination of cis-trans isomerism with iso-syndio and erythro-threo dispositions gives complex stractures as exemplified by the 1,4 polymers of 1-or 4-monosubstituted butadienes, such as 1,3-pentadiene (72, 73), and 2,4-pentadienoic acid (74, 75) and of 1,4-disubstituted butadienes, for example, sorbic acid (76). This last example is described in 32-35 (Scheme 6, rotated Fischer projection). Due to the presence of three elements of stereoisomerism for each monomer unit (two tertiary carbons and the double bond) these polymers have been classed as tritactic. Ignoring optical antipodes, eight stereoregular 1,4 structures are possible, four cis-tactic and four trans-tactic. In each series (cis, trans) we have two diisotactic and two disyndiotactic polymers characterized by the terms erythro and threo in accordance with the preceding explanation. It should be noted that here the erythro-threo relationship refers to adjacent substituents that belong to two successive monomer units. [Pg.11]

Abraham GA, Gallardo A, Lozano AE, San RJ (2000) E-caprolactone/ZnCL complex formation characterization and ring-opening polymerization mechanism. J Polym Sci A Polym Chem 38 1355-1365... [Pg.211]

As explained in Sections 16.4 and 16.5, the comprehensive characterization of complex polymer systems is hardly possible by the SEC alone. SEC employs only one retention mechanism which simnltaneonsly responds to all molecular characteristics of sample. Similarly, also the coupling of the different retention mechanisms within one single column only exceptionally allows fulfilling this task. Evidently several retention mechanisms should be applied in a tandem approach that is within at least two different on-line chromatographic systems. This is the basic idea of the two- and multidimensional polymer HPLC. In the present section, the principles of two-dimensional polymer HPLC, 2D polymer HPLC or (2D-LC) will be briefly elucidated. There are several reviews available [23-31,249,250] dealing with the 2D polymers. It is anticipated that also the three- and multidimensional polymer HPLC will be developed in future. [Pg.487]

A useful approach to detection in polymer HPLC presents the on-line hyphenation of different measurement principles. For example, an RI detector combined with a UV photometer produces valuable additional information on the composition of some copolymers. Further progress was brought with the triple detection RI plus LALS plus VISCO [313], which is especially suitable for branched macromolecules and the tetra detection UV plus RI plus LALS plus VISCO, which enables characterization of some complex polymer systems, exhibiting a distribution not only in their molar mass and architecture, but also in their chemical composition such as long chain branched copolymers. [Pg.496]

HE FIELD OF SIZE EXCLUSION CHROMATOGRAPHY (SEC) remains a viable and lively area of polymer characterization. Over the past several years, there has been considerable research activity in the area of SEC detection and data analysis in order to obtain more comprehensive information concerning the composition and molecular architecture of complex polymer systems. [Pg.1]

The characterization of complex polymers requires at least one detector per desired property. Obviously, some of the molecular properties will be inter-related and the response from any given detector will Include, in general, contributions from one or more properties. Thus, the response from ultraviolet and infrared spectrophotometers are known to contain information on the composition and the mi crostruotur e of the polymer chains (3, 1 1 5,28,29), the... [Pg.221]

Actually, polymer relaxations are complex processes characterized by a relaxation spectrum (coexistence of many relaxation time). Their Cole-Cole plots are generally nonsymmetric (Fig. 11.11). [Pg.353]

A more detailed study of the phase diagram of the polyelectrolyte complex must take into account the non-electrostatic interactions between the two polymers characterized by the Flory interaction parameter %. This inter-... [Pg.162]

This study was a preliminary effort to detect and characterize structures in the lignin polymer that result from condensation reactions during alkaline treatment. The only method capable of observing this complex polymer with the necessary detail on an atomic scale is 13C-NMR spectroscopy. Enormous progress has been made in the capabilities of NMR especially in the last few years, and very few of the modern techniques have yet been applied to lignin. [Pg.31]

The structural complexity of synthetic polymers can be described using the concept of molecular heterogeneity (see Fig. 1) meaning the different aspects of molar mass distribution (MMD), distribution in chemical composition (CCD), functionality type distribution (FTD) and molecular architecture distribution (MAD). They can be superimposed one on another, i.e. bifunctional molecules can be linear or branched, linear molecules can be mono- or bifunctional, copolymers can be block or graft copolymers, etc. In order to characterize complex polymers it is necessary to know the molar mass distribution within each type of heterogeneity. [Pg.4]

To summarize, for the complete analysis of complex polymers a minimum of two different characterization methods must be used. It is most desirable that each method is sensitive towards a specific type of heterogeneity. Maximum efficiency can be expected when, similar to the two-dimensional distribution in properties, two-dimensional analytical techniques are used. A possible approach in this respect is the coupling of different chromatographic modes in... [Pg.5]

As was pointed out in the introduction, complex polymers are distributed in more than one direction. Copolymers are characterized by the molar mass distribution and the chemical heterogeneity, whereas functional homopolymers are distributed in molar mass and functionality. Hence, the experimental evaluation of the different distribution functions requires separation in more than one direction. [Pg.24]

Balke ST (1991) Characterization of complex polymers by SEC and HPLC. In Barth HG,Mays JM (eds) Modern methods in polymer characterization, chap 1. Wiley Interscience, New York... [Pg.61]

As more complex polymers systems have been studied it is evident that subtle effects in the interpretation of data and the underlining theory have come to the fore. Advances in polymerization chemistry, as well as, the enormous advances in techniques used in polymer characterization, has meant that PAL polymer studies can now be conducted on well characterized and controlled systems. There is no doubt that PAL will continue to be a valuble tool for the polymer scientist. The application of monoenergitic slow positron beams to polymers surfaces will be discussed in the next chapter. [Pg.277]

CP-MAS P NMR can be used to characterize supported complexes, for example, the polypropylene-j -styryldiphenylphosphine-bound rhodium complex [(polymer)-PPh2]Rh(acac)(CO) has been characterized in this manner. Free and complexed phosphines are clearly... [Pg.4721]


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