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Complex mixtures, analysis

In chromatography-FTIR applications, in most instances, IR spectroscopy alone cannot provide unequivocal mixture-component identification. For this reason, chromatography-FTIR results are often combined with retention indices or mass-spectral analysis to improve structure assignments. In GC-FTIR instrumentation the capillary column terminates directly at the light-pipe entrance, and the flow is returned to the GC oven to allow in-line detection by FID or MS. Recently, a multihyphenated system consisting of a GC, combined with a cryostatic interfaced FT1R spectrometer and FID detector, and a mass spectrometer, has been described [197]. Obviously, GC-FTIR-MS is a versatile complex mixture analysis technique that can provide unequivocal and unambiguous compound identification [198,199]. Actually, on-line GC-IR, with... [Pg.458]

There is a need for increased chromatography-FTIR sensitivity to extend IR analysis to trace mixture components. GC-FTIR-MS was prospected as the method of choice for volatile complex mixture analysis [167]. HPLC-FT1R, SFC-FTIR and TLC-FTIR are not as sensitive as GC-FTIR, but are more appropriate for analyses involving nonvolatile mixture components. Although GC-FTIR is one of the most developed and practised techniques which combine chromatography (GC, SFC, HPLC, SEC, TLC) and FUR, it does not find wide use for polymer/additive analysis, in contrast to HPLC-FTIR. [Pg.458]

Erhardt-Zabik, S., J.T. Watson, and M.J. Zabik. 1990. Selective sensitivity of highly chlorinated species in negative ion mass spectrometry implications for complex mixture analysis. Biomedic. Environ. Mass Spectrom. 19 101-108... [Pg.1326]

The model 1020 software package includes interactive programmes specifically designed for complex mixture analysis and advanced automated programmes for routine analysis. All system functions are computer controlled with minimal knowledge of mass spectrometry. [Pg.77]

Two pattern recognition techniques are applied to the analysis of the library of FTIR spectra compiled by the US EFA> The patterns which emerge demonstrate the influence of molecular structure on the spectra in a way familiar to chemical spectroscopists They are also useful in evaluation of the library, which is not error free, and in assessing the difficulties to be expected when using FTIR spectra for complex mixture analysis. [Pg.160]

There are two necessary and related preconditions which must be satisfied for complex mixture analysis by pattern recognition to be successful. First, we must obtain an adequate data base of FTIR spectra from which we can derive the spectral patterns we need to recognize. Second, we must demonstrate that there Is a suitable measure or metric of similarity between the spectra. It Is these two conditions which were evaluated by the work presented here. Pattern recognition techniques were most suitable for the evaluation. [Pg.161]

Quantitative results were produced for each compound on the basis of internal standard method calculations. A three-point calibration curve was generated for each compound by using peak areas of a quantitation ion extracted from the mass spectrum of the compound. The ion was selected on the basis of it being a uniquely characteristic mass of the compound. The use of extracted ion quantitation produces more accurate results than total ion-current quantitation in cases in which two or more components are not completely resolved chromatographically. This situation is generally the case in complex mixture analysis. The quantitation ions selected for each of the compounds in the mix are listed in the box. [Pg.358]

Progress in the application of sensor arrays to gas analysis will be made through increasingly independent data channels using novel combinations of sensors and operating modes. Computational approaches will be modified to suit specific types of sensor arrays and to make economical use of computational space for portable instrument applications. The primary challenges of the near future will be to solve the "needle-in-the-haystack" problem and to proceed to complex mixture analysis using a plurality of sensor responses. [Pg.307]

Figure 7. Comparison of different prefractionation steps in typical LC-MALDl workflows for complex mixture analysis. Adapted from Hattan et al. (2005). Copyright 2005 American Chemical Society. Figure 7. Comparison of different prefractionation steps in typical LC-MALDl workflows for complex mixture analysis. Adapted from Hattan et al. (2005). Copyright 2005 American Chemical Society.
One of the instruments obtained by ERDA will be evaluated at ORNL to assess its potential as a monitor for hazardous by-products from alternative energy sources. Investigations to determine the desirability of a membrane inlet system for concentrating organic vapors are planned. The feasibility of using a portable gas chromatograph with the portable mass spectrometer, when a complex mixture analysis is required, is also being studied. [Pg.97]

Complex Mixture Analysis. High-performance organic coatings are extremely complex formulations. Specifically, waterborne automo-... [Pg.51]

Zhang EL, Robinette SL, Bruschweiler-Li L, Bruschweiler R (2009) Web server suite for complex mixture analysis by covariance NMR. Magn Reson Chem 47 S118-S122... [Pg.166]

Alexander AJ, Xu F, Bernard C. The design of a multidimensional LC-SPE-NMR system (LC2-SPE-NMR) for complex mixture analysis. Magn Reson Chem 2006 44(l) l-6. [Pg.405]

Crawford, C.L. Graf, S. Gonin, M. Fuhrer, K. Zhang, X. and Hill, H.H., Jr., The novel use of gas chromatography-ion mobility-time of flight mass spectrometry with secondary electrospray ionization for complex mixture analysis, Int. J. Ion Mobil. Spectrom. 2010, 14, 23-30. [Pg.69]


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Complex analysis

Complex mixtures

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