Cohesion definitions

In terms of intermolecular cohesion, definitions of molecular shape can be introduced through some effects on experimental bulk properties. These operational definitions are particularly useful for comparisons among isomers rather than on an absolute basis. In isomers, the chemical composition is the same but the distribution in space of molecular components is different. A typical example is provided by disubstituted benzenes [20] every practicing organic chemist knows that 1,4-isomers are almost invariably the highest melting ones. Figure 1.6 shows that differences in... 

Thermodynamic Properties The variation in solvent strength of a supercritical fluid From gaslike to hquidlike values may oe described qualitatively in terms of the density, p, or the solubihty parameter, 6 (square root of the cohesive energy density). It is shown For gaseous, hquid, and SCF CO9 as a function of pressure in Fig. 22-17 according to the rigorous thermodynamic definition ... 

The performance of a product where adhesion plays a role is determined both by its adhesive and cohesive properties. In the case of silicones, the promotion of adhesion and cohesion follows different mechanisms [37]. In this context, adhesion promotion deals with the bonding of a silicone phase to the substrate and reinforcement of the interphase region formed at the silicone-substrate interphase. The thickness and clear definition of this interphase is not well known, and in fact depends on many parameters including the surface physico-chemistry of... 

The ideal soil is defined as a loose, granular medium that is devoid of cohesion but possesses internal friction. In contrast, an ideal cohesive medium is one that is devoid of internal friction. Real soils generally fall between the foregoing two limiting definitions. 

The degree of realism of these model structures can be assessed by comparison of computed properties with experimental ones. The cohesive energy is, by definition, the difference in energy per mole of substance between a parent chain in its bulk environment and the same parent chain in vacuo, i.e., when all intermolecular forces are eliminated. This difference is readily computed from the minimized... 

Hardness is a somewhat ambiguous property. A dictionary definition is that it is a property of something that is not easily penetrated, spread, or scratched. These behaviors involve very different physical mechanisms. The first relates to elastic stiffness, the second to plastic deformation, and the third to fracturing. But, for many substances, the mechanisms of these are closely related because they all involve the strength of chemical bonding (cohesion). Thus discussion of the mechanism for one case may provide some understanding of all three. 

There have been a number of past attempts to unify hardness measurements but they have not succeeded. In several cases, hardness numbers have been compared with scalar properties that is, with cohesive energies (Plendl and Gielisse, 1962) or bulk moduli (Cohen, 1988). But hardness is not based on scalar behavior, since it involves a change of shape and is anisotropic. Shape changes (shears) are vector quantities requiring a shear plane, and a shear direction for their definition. In this book, the fact that plastic... 

It is not clear where cohesive forces will become important. The use of very dense particles (for the models of the one atmospheric bed) will cause a shift of the boundary of cohesive influence as given, for example, by Geldart s classification. However, adequate experimental data is still lacking with such dense fine particles to definitely set the limits of cohesive influence. 

If, when a liquid drop is placed on a smooth surface, the forces of adhesion between the solid and the liquid are greater than the forces of cohesion of the liquid, then the liquid will spread and will perfectly wet the surface spontaneously. If the forces reach an intermediate balance determined by the interfacial energies ylv, ysj and ysv, then the liquid drop will form a definite contact angle (0) with the solid surface (Figure 4.12). 

We define the cohesive energy Ecoh (Johansson, Skriver ) as the difference between the energy of an assembly of free atoms in their ground state (see Table 1 of Chap. A) and the energy of the same assembly in the condensed phase (the solid at 0 °K), (this definition yields a positive number for Ecoii). It coincides with the enthalpy of sublimation AHj (see Chap. A) (which is usually extrapolated at room temperature). 

Structurally, a more specific definition would be that a molecule is a local assembly of atomic nuclei and electrons in a state of dynamic siahility. The cohesive forces are electrostatic, but. in addition, relatively small electromagnetic interactions may occur between (he spin and orbital motions of (he electrons, especially in the neighborhood of heavy nuclei. The intcrnuclear separations are of the order of 1-2 x 10" meter, and the energies required to dissociate a stable molecule into smaller fragments... 

The part of Earth s geosphere that is accessible to humans is the crust, which, ranging from 5 to 40 km in thickness, is extremely thin compared to the diameter of the earth. Most of the solid earth crust consists of rocks. Rocks are composed of minerals, where a mineral is a naturally occurring inorganic solid with a definite internal crystal structure and chemical composition. A rock is a solid, cohesive mass of pure mineral or an aggregate of two or more minerals. 

Constitutional formulae were designed "on paper", primarily to be "in harmony" with known chemical properties and without pretension to "represent the symmetrical or spatial arrangement of the atom in a compound" [22], Not only was this stipulation gradually relaxed to represent three-dimensional structures, but the connecting lines were also soon after assumed to represent definite electronic links between atoms. This assumption opened the door for the introduction of semi-empirical quantum-mechanical characterization of chemical bonds. It is important to realize that chemical bonds have never been observed in any experiment and that they only exist as conjectures to interpret primitive molecular graphs. Their value as heuristic aids in the study of chemical change and composition is beyond dispute, but as a basis for the theoretical understanding of chemical cohesion they are of little value. 

Innovators. Thinks in risky, unexpected ways. Little respect for past custom - seen as irrelevant. Trades off detail for over-view. Questions definition of problem. Often challenges the rules solves problems despite rule. Can appear insensitive, even abrasive, to group cohesion. Does things differently. Provides dynamics for radical change. 

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