Chloroethyl ethyl sulfide

Kinetic studies of various systems have been carried out as follows the reaction of 2,2 -dichlorodiethyl sulfide and of 2-chloroethyl ethyl sulfide with diethylenetriamine and triethylamine in 2-methoxyethanol ° the catalysed reactions of substituted phenols with epichlorohydrin the reactions of para-substituted benzyl bromides with isoquinoline under high pressure the reactions of O-alkylisoureas with OH-acidic compounds [the actual system was N, N -dicyclohexyl-0-(l-methylheptyl)isourea with acetic acid] and tlie ring opening of isatin in aqueous binary mixtures of methanol and acetonitrile cosol vents. 

Groenewold, G.S., J.C. Ingram, A.D. Appelhans, J.E. Delmore, and D.H. Dahl. 1995. Detection of 2-chloroethyl ethyl sulfide and sulfonium ion degradation products on environmental surfaces using static SIMS. Environmental Science and Technology 29 2107-2111. 

Reaction of the sandwich-type POM [(Fc(0H2)2)j(A-a-PW9034)2 9 with a colloidal suspension of silica/alumina nanopartides ((Si/A102)Cl) resulted in the production of a novel supported POM catalyst [146-148]. In this case, about 58 POM molecules per cationic silica/alumina nanoparticle were electrostatically stabilized on the surface. The aerobic oxidation of 2-chloroethyl ethyl sulfide (mustard simulant) to the corresponding harmless sulfoxide proceeded efficiently in the presence of the heterogeneous catalyst and the catalytic activity of the heterogeneous catalyst was much higher than that of the parent POM. In addition, this catalytic activity was much enhanced when binary cupric triflate and nitrate [Cu(OTf)2/Cu(N03)2 = 1.5] were also present [148],... 

R. M. Narske, K. J. Klabunde, and S. Fultz, Solvent effects on the heterogeneous adsorption and reactions of (2-chloroethyl) ethyl sulfide on nanocrystalline magnesium oxide, Langmuir 18, 4819-4825 (2002). 

In 2001, Hill and co-workers (151) used a heterogeneous Ag5PV2Moio04o catalyst to mediate the oxidation of 2-chloroethyl ethyl sulfide to the corresponding sulfoxide at room temperature under 1.0 atm of air (Fig. 37). 

Varma, S.D., Devamanoharan, P.S., Ali, A.H., Henein, M., Petrali, J., Brozetti, J., Lehnert, E. (1998a). Comeal damage by half mustard (2-chloroethyl ethyl sulfide, CEES) in vitro preventive studies a histologic and electron microscopic evaluation. J. Ocul. Pharmacol. Ther. 14 413-21. 

The decontamination efficacy of radioprotective agent aminoethylisothiourea and cystamine on rat skin against SM was comparable to standard decontaminants, such as alco-holate, clay, and Fuller s earth (Knezevic and Tadic, 1996). A mixture containing bovine hemoglobin, gelatin, and poi (a Hawaiian foodstuff) on the hydrolytic kinetics of the mustard simulants, 2-chloroethyl ethyl sulfide, 2-chloro-ethyl methyl sulfide and 2-bromoethyl phenyl sulfide, is reported. The kinetic mechanisms and rate constants were dependent upon the mixtures concentration and viscosity (Cemy and Cemy, 1997). 

Chatteijee, D., Mukheijee, S., Smith, M.G., Das, S.K. (2003). Signal transduction events in lung injury induced by 2-chloroethyl ethyl sulfide, a mustard analog. J. Biochem. Mol. Toxicol. 17 114-21. 

Gautam, A., Vijayaraghavan, R., Sharma, M., Ganesan, K. (2006). Comparative toxicity studies of sulfur mustard (2,2 -dichloro diethyl sulfide) and monofunctional sulfur mustard (2-chloroethyl ethyl sulfide), administered through various routes in mice. J. Med. Chem. Biol. Rad. Def. 4 el-20. 

Kim, Y.B., Lee, Y.S., Choi, D.S., Cha, S.H., Sok, D.E. (1996h). Change in glutathione S-transferase and glyceraldehyde-3-phosphate dehydrogenase activities in the organs of mice treated with 2-chloroethyl ethyl sulfide or its oxidation products. Food Chem. Toxicol. 34 259-65. 

SYNS 2-CHLOROETHYL ETHYL SULFIDE 2-CHLOROETHYL ETHYL THIOETHER l-CHLORO-2-(ETHYLTHIO)ETHANE ETHYL-P-CHLOROETHYL SULFIDE ETHYL-2-CHLOROETHYL SULFIDE p-ETHYLMERKAPTOETHYLCHLORID (CZECH) 2-(ETHYLTHIO)CHLOROETHANE 2-ETHYLTHIO-ETHYL CHLORIDE HALF-MUST.MID GAS h-MG... 

CHLOROETHYL ETHER see DFJ050 CHLOROETHYL ETHYL SULFIDE see CGY750 2-CHLOROETHYL ETHYL SULFIDE see CGY750 2-CHLOROETHYL ETHYL THIOETHER see CGY750 l-(2-CHLOROETHYL)-3-(d-GLUCOPYRANOS-2-YL)-l-NITROSOUREA see CLXOOO... 

Figure 2 Pure rotational speetra for the ehemieal weapon simulants pinaeolone (A), pinaeolyl alcohol (B), 2-chloroethyl ethyl sulfide (C), and dimethyl methylphosphonate (D).

The third panel of Figure 2 shows the rotational spectrum of 2-chloroethyl ethyl sulfide (2CEES) a mustard gas simulant. The rotational constants and inertial projection of the permanent dipole moment have been previously reported and are reproduced in Table 1. The rotational spectrum of 2CEES is highly congested by the addition of the chlorine atom. The 2CEES spectrum is fragmented by the appearance of two nuclear... 

M. J. Tubergen, A. Lesarri, R. D. Suenram, A. C. Samuels, J. O. Jensen, M.W. EUzy, J. M. Lochner, Rotational spectra, nuclear quadrupole hypeifme tensors, and conformational structures of the mustard gas simulant 2-chloroethyl ethyl sulfide, J. Mol. Spec., 233, 180-188 (2005). 

Stone, W.L., Qui, M., and Smith, M. (2003). Lipopolysaccharide enhances the cytotoxicity of 2-chloroethyl ethyl sulfide. BMC Cell Biol 4, 1. 

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