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Chlorhydrine

Fumigation with ethylene oxide does indeed lead to a considerable reduction in the germ count (and at the same time destruction of insects), but the process, because of the formation of toxic reaction products (ethylene chlorhydrin, ethylene glycol) has been banned throughout the European Community since 01.01.1990 Ionizing irradiation a declaration of the treatment is obligatory, but such drugs find little acceptance by the public who expect nature s products as such. [Pg.35]

Epichlorhydrin.—It is a noteworthy fact that althoug-h hydiochloric acid can leplace hydroxyl by chlorine in the case of the monohydric alcohols, the number of hydroxyl groups which are substituted in the case of polyhydric alcohols is strictly limited. Like glyceiol, ethylene glycol gives a chlorhydrin, CIi..OH.CILOII 1- IICl CHnOH.CILCl -1- ILO. [Pg.260]

This is the basis of the iodofonn test for the CHiCO group. In addition to the.se reactions tliere is considerable industrial use for HOCl and hyfHxrhlorites in the manufacture of hydrazine (p. 427), chlorhydrins and or-glycols ... [Pg.860]

Fluoroalkanephosphonic acid can be obtained by addition of iodine perfluoroalkane to vinylphosphonic acid dichloride followed by saponification and deiodination by sodium amalgam [141]. Fluoroalkanephosphonic acids can be transformed to fluoroalkanephosphonic acid glycil esters by 2 mol of epi-chlorhydrin in a water-free solution followed by reaction with alkalines or amines [142]. Compounds of this kind with an alkyl chain of 8-20 carbon at-... [Pg.581]

Der dipolare Mechanismus liefert dagegen mehr t/ireo-Diastereomere, aus 2-Chlor-ke-tonen erhalt man z.B. threo- Chlorhydrine als Hauptprodukte10. [Pg.323]

Chloroethanol, see Ethylene chlorhydrin Chloroelhylene, see Vinyl chloride Chloroform (trichloromethane) bis-Chloromethyl ether... [Pg.248]

II. The molecular structure of ethylene chlorhydrin. Bull. Chem. Soc. Japan 29, 865 (1956). [Pg.52]

Zur praparativen Anwendung dieser Methode wurde LXXX in sein Acetat (XC) iibergefiihrt, das bei der Reaktion mit N-Chlorsuccinimid in tert.-Butanol das Aethusanol-B-acetat-chlorhydrin (XCI) liefert. Bei der anschlieBenden Behandlung mit Alkali wird das gewiinschte Epoxyd LXXXVI gebildet. [Pg.172]

Bei der Umsetzung des Hydroxyacetats CCXVII mit Thionylchlorid erhalt man unter Allylumlagerung direkt das Chloracetat CCV, das bei der sauren Umesterung das Chlorhydrin CCVII ergibt. [Pg.199]

Propene oxide is also manufactured by the chlorhydrin route (186) ... [Pg.83]

The chlorhydrin route is also used in the manufacture of epichlorohydrin from allyl chloride (187) ... [Pg.84]

The specific rate is k = 5.2 1 iter/gmol-hr at 82 C. Equal molal quantities the reactants are to be used. They are supplied as aqueous solutions, bicarbonate as 15 wt% and the chlorhydrin as 30 wt%. Production of glycol to be 20 kg/hr at 95% conversion. Specific gravity of the feed mixture 1.02. Find the required reactor volumes of a PFR and of a CSTR. [Pg.374]

Thus ethylene chlorhydrin is obtained by passing ethylene and carbon dioxide together into bleaching powder solution. [Pg.111]

On a large scale ethylene chlorhydrin is prepared by the addition of hypochlorous acid to ethylene, by passing C02 and ethylene simultaneously into a solution of bleaching powder. Concentrated potassium hydroxide solution converts chloroethyl alcohol into ethylene oxide, by removal of HC1 ... [Pg.116]

Special mention should be made of the ready conversion of the chlorhydrin, by means of tnmethylamine, to choline, a substance of great physiological importance. Choline chloride is obtained very easily when equimolecular amounts of the two components are made to interact for some time under the influence of heat a concentrated solution of the amine in absolute alcohol is used. [Pg.116]

Ein Dihydropjrran-Derivat koramt in den Wurzeln von Anaphalis margaritaceae vor (4). Das Chlorderivat CXIX durfte biogcnetisch aus dem Chlorhydrin CXX entstehen. Bisher ist jedoch nur das trans-Iso-mere von CXX isoliert worden. [Pg.81]

Synonyms AI3-52326 BRN 0878139 CCRIS 859 2-Chloroethanol 5-Chloroethanol 2-Chloroethyl alcohol p-Chloroethyl alcohol EINECS 203-457-7 Ethylene chlorhydrin Glycol chlorohydrin Glycol monochlorohydrin 2-Hydroxyethyl chloride 2-Monochloroethanol NCI-C50135 UN 1135. [Pg.570]

Ethylene carboxamide, see Acrylamide Ethylene chlorhydrin, see Ethylene chlorohydrin Ethylene chloride, see 1,2-Dichloroethane... [Pg.1486]

Abies halsamea Phyllosticta sp. hydro- and heptelidic acid, heptelidic acid chlorhydrin 203... [Pg.521]

Hydrin is the reaction product of a polyhydric alcohol and an inorganic acid, eg a chlorhydrin is formed from HOCH2CH(OH)CH2OH + HC1 =... [Pg.212]

In reactions with organic compounds, the acid may act not only as an oxidizer (see above) but also as a chlorinating agent (in the case of saturated compounds) or the addition of HO-C1 to the double linkage C=C to form a chlorhydrin ... [Pg.260]

Ethers and esters of various glycols-See Cunne Johnston, PP 305, 306, 309, 311, 313, 322 2-Ethyl 2-buryl-l, 3-propanediol 3 0 Ethylene chlorhydrin 0.095 (3.5g inhaled from the atmosphere killed a man) Propylene glycol 26.4 Propylene oxide 1.14 Propylene oxide tetratner 1.8 Tri ethyleneglycol 22.1 Trim ethylenegly col (about twice as toxic to small animals as propylenegly col) ... [Pg.755]

Ethoxyethanol Ethyl chloride Epichlorhydrin 2-Ethoxyethylacetate Ethyl acetate Ethyl acrylate Ethyl alcohol Ethyl benzene Ethyl bromide Ethyl chloride Ethyl butyl ketone Ethyl ether Ethyl formate Ethylene chlorhydrin Ethylene dibromide Ethylene dichloride Ethylene oxide... [Pg.185]

The same inventor patented (GerP 2007 of 1893) the following prepn of a-trinitrophenol-dinitroglycerine and dinitronaphthol-dinitro-glycerin One dissolves 20 p of dinitro-a-chlorhydrin in 60 p of alcohol, and the soln is mixed with 27 p of K picrate. After heating at 70—80° until the pptn of K chloride ceases, the soln is coned and then cooled to achieve crystn Ref Daniel (1902), 796... [Pg.296]

Chlorohydrin(Called Chlorpropandiol, Mono-chlorhydrin, Glycerinchlorhydrin or Chlor-propylenglykol in Ger), Cl.CsHs(OH)2 mw 110.54. Two isomers are known, both of which are present in the commercial product 3-Chloropropane-1,2-diol or a-Chlorohydrin, Cl.CH2.CH(OH).CH2.OH, col to pale-yel si viscous liq having a pleasant odor, bp 213°... [Pg.48]

See other pages where Chlorhydrine is mentioned: [Pg.374]    [Pg.860]    [Pg.401]    [Pg.1147]    [Pg.1147]    [Pg.8]    [Pg.383]    [Pg.172]    [Pg.198]    [Pg.200]    [Pg.200]    [Pg.502]    [Pg.76]    [Pg.78]    [Pg.96]    [Pg.115]    [Pg.231]    [Pg.282]    [Pg.289]    [Pg.50]    [Pg.75]    [Pg.766]    [Pg.625]    [Pg.145]   
See also in sourсe #XX -- [ Pg.112 , Pg.113 ]



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