Chirality-spin-magnetism

Magnetic circular dicliroism (MCD) is independent of, and thus complementary to, the natural CD associated with chirality of nuclear stmcture or solvation. Closely related to the Zeeman effect, MCD is most often associated with orbital and spin degeneracies in cliromophores. Chemical applications are thus typically found in systems where a chromophore of high symmetry is present metal complexes, poriihyrins and other aromatics, and haem proteins are... 

Then, there are model Hamiltonians. Effectively a model Hamiltonian includes only some effects, in order to focus on those effects. It is generally simpler than the true full Coulomb Hamiltonian, but is made that way to focus on a particular aspect, be it magnetization, Coulomb interaction, diffusion, phase transitions, etc. A good example is the set of model Hamiltonians used to describe the IETS experiment and (more generally) vibronic and vibrational effects in transport junctions. Special models are also used to deal with chirality in molecular transport junctions [42, 43], as well as optical excitation, Raman excitation [44], spin dynamics, and other aspects that go well beyond the simple transport phenomena associated with these systems. 

We have considered here the influence of dispersion asymmetry and Zee-man splitting on the Josephson current through a superconductor/quantum wire/superconductor junction. We showed that the violation of chiral symmetry in a quantum wire results in qualitatively new effects in a weak superconductivity. In particularly, the interplay of Zeeman and Rashba interactions induces a Josephson current through the hybrid ID structure even in the absence of any phase difference between the superconductors. At low temperatures (T critical Josephson current. For a transparent junction with small or moderate dispersion asymmetry (characterized by the dimensionless parameter Aa = (vif — v2f)/(vif + V2f)) it appears, as a function of the Zeeman splitting Az, abruptly at Az hvp/L. In a low transparency (D Josephson current at special (resonance) conditions is of the order of yfD. In zero magnetic field the anomalous supercurrent disappears (as it should) since the spin-orbit interaction itself respects T-symmetry. However, the influence of the spin-orbit interaction on the critical Josephson current through a quasi-ID structure is still anomalous. Contrary to what holds... 

The preparation of chiral magnetic materials is not limited to those that show paramagnetism and magnetic ordering. Another important phenomenon is that of spin crossover, as it can lead to bistable systems, that in addition can be switched by light [213,214]. A homochiral spin crossover... 

Two effects were detected in the present study, the spin-selective electron transmission through monolayers made from ds-DNA and the large magnetization measured for these layers. In addition, it has been found that there is a clear difference between monolayers made from ss-DNA and those made from ds-DNA. This difference exists despite the fact that both types of molecules are chiral. 

Abstract Understanding the origin of chirality in nature has been an active area of research since the time of Pasteur. In this chapter we examine one possible route by which this asymmetry could have arisen, namely chiral-specific chemistry induced by spin-polarized electrons. The various sources of spin-polarized electrons (parity violation, photoemission, and secondary processes) are discussed. Experiments aimed at exploring these interactions are reviewed starting with those based on the Vester-Ulbricht hypothesis through recent studies of spin polarized secondary electrons from a magnetic substrate. We will conclude with a discussion of possible new avenues of research that could impact this area. 

Other sources of spin-polarized electrons. Low-energy SPEs may be produced in other ways such as circularly-polarized UV light irradiation of a surface, spin-polarized electron guns, and spin-polarized tunneling from a magnetic tip. Provided that these sources could be stabilized so that quantitative cross sections could be determined, it should be possible to perform chiral-selective surface chemistry measurements. 

Rosenberg RA, Abu Haija M, Ryan PJ (2008) Chiral-selective chemistry induced by spin-polarized secondary electrons from a magnetic substrate. Phys Rev Lett 101 178301... 

---