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Chemicals pyrrole

Uses Chemical intermediate in the mfg. of herbicides, pharmaceuticals, plastics, and fine chemicals (pyrrole, tetrahydrofuran, thiophene) coating asphaltic pavements, foundry sand cores solvent for resins and in the formation of lacquers... [Pg.1124]

These facts can be explained if we consider the coexistence of a chemical pyrrole polymerization parallel to the formation of the polymer on the electrode. It is known that acidification of a pyrrole solution in an organic solvent gives a polymeric powder with alternating saturated and unsaturated pjnrole rings [21,136-9] (Figure 10.12). The kinetics of this homogeneous chemical proton-catalyzed polymerization of... [Pg.433]

Cyclic compounds that contain at least one atom other than carbon within their ring are called heterocyclic compounds, and those that possess aromatic stability are called het erocyclic aromatic compounds Some representative heterocyclic aromatic compounds are pyridine pyrrole furan and thiophene The structures and the lUPAC numbering system used m naming their derivatives are shown In their stability and chemical behav lor all these compounds resemble benzene more than they resemble alkenes... [Pg.460]

Analytical and Test Methods. In addition to the modem spectroscopic methods of detection and identification of pyrroles, there are several chemical tests. The classical Runge test with HCl yields pyrrole red, an amorphous polymer mixture. In addition, all pyrroles with a free a- or P-position or with groups, eg, ester, that can be converted to such pyrroles under acid conditions undergo the Ehrlich reaction with p-(dimethylamino)henzaldehyde to give purple products. [Pg.357]

Chemical antiozonants comprise the second general class of commercial antiozonants. Of the many compounds reported to be chemical antiozonants, nearly all contain nitrogen. Compound classes include derivatives of l,2-dihydro-2,2,4-trimethylquinoline, A/-substituted ureas or thioureas, substituted pyrroles, and nickel or zinc dithiocarbamate salts (see also Antioxidants). The most effective antiozonants, however, are derivatives of -phenylenediamine... [Pg.237]

Polyheterocycles. Heterocychc monomers such as pyrrole and thiophene form hiUy conjugated polymers (4) with the potential for doped conductivity when polymerization occurs in the 2, 5 positions as shown in equation 6. The heterocycle monomers can be polymerized by an oxidative coupling mechanism, which can be initiated by either chemical or electrochemical means. Similar methods have been used to synthesize poly(p-phenylenes). [Pg.36]

Entrapment of biochemically reactive molecules into conductive polymer substrates is being used to develop electrochemical biosensors (212). This has proven especially useful for the incorporation of enzymes that retain their specific chemical reactivity. Electropolymerization of pyrrole in an aqueous solution containing glucose oxidase (GO) leads to a polypyrrole in which the GO enzyme is co-deposited with the polymer. These polymer-entrapped GO electrodes have been used as glucose sensors. A direct relationship is seen between the electrode response and the glucose concentration in the solution which was analyzed with a typical measurement taking between 20 to 40 s. [Pg.45]

The classical structures of pyrrole, furan and thiophene (31) suggest that these compounds might show chemical reactions similar to those of amines, ethers and thioethers (32) respectively. On this basis, the initial attack of the electrophile would be expected to take place at the heteroatom and lead to products such as quaternary ammonium and oxonium salts, sulfoxides and sulfones. Products of this type from the heteroaromatic compounds under consideration are relatively rare. [Pg.42]

The chemical consequences of /3-protonation are illustrated further by the ring-opening reactions of furans with methanolic hydrogen chloride and of (V-substituted pyrroles with hydroxylamine hydrochloride (Scheme 11) (82CC800). [Pg.48]

For the NH azoles (Table 3), the two tautomeric forms are usually rapidly equilibrating on the NMR timescale (except for triazole in HMPT). The iV-methyl azoles (Table 4) are fixed chemical shifts are shifted downfield by adjacent nitrogen atoms, but more by a pyridine-like nitrogen than by a pyrrole-like iV-methyl group. [Pg.13]

Two new sections on the protection for indoles, imidazoles, and pyrroles, and protection for the amide — NH are included. They are separated from the regular amines because their chemical properties are sufficienth different to affect the chemistry of protection and deprotection. The Reactivity Charts in Chapter 8 are identical to those in the first edition. The chart number appears beside the name of each protective group when it is first discussed. [Pg.475]

In contrast to H shifts, C shifts cannot in general be used to distinguish between aromatic and heteroaromatic compounds on the one hand and alkenes on the other (Table 2.2). Cyclopropane carbon atoms stand out, however, by showing particularly small shifts in both the C and the H NMR spectra. By analogy with their proton resonances, the C chemical shifts of k electron-deficient heteroaromatics (pyridine type) are larger than those of k electron-rieh heteroaromatic rings (pyrrole type). [Pg.13]

Apart from the A-methyl group, three double-bond equivalents and three multiplets remain in the chemical shift range appropriate for electron rich heteroaromatics, Sh = 6.2 to 6.9. A-Methyl-pyrrole is such a compound. Since in the multiplets at Sh = 6.25 and 6.80 the Jhh coupling of 4.0 Hz is appropriate for pyrrole protons in the 3- and 4-positions, the pyrrole ring is deduced to be substituted in the 2-position. [Pg.181]

Dewar pyrrole [756] and Dewar thiophene stabilized by the presence of fluormated substituents have been successfully isolated, and their chemical pro perties have been studied [757, 1S8, 159, 160, 161] The olefinic bond m these... [Pg.926]

Chemical evidence led to the conclusion that the conjugate acids of pyrrole probably exist predominantly as 16 or 17 rather than as X52,4,5 Although infrared spectra were initially interpreted on the... [Pg.3]

Chemical Name 1-(hexahydrocyclopenta(c] pyrrol-2(1 H)-yl)-3-(p-tolylsulfonyl)urea Common Name N-(4-methylbenzenesulfonyl)-N -(3-azabicyclo(3.3.0] -3-octyl)urea Structural Formula ... [Pg.729]

Chemical Name 6-(dimethylamino)-2- [2-(2,5-dimethyl-1-phenyl-1 H-pyrrol-3-yl)ethenyl] -1-methylquinolium salt with pamoic acid (2 1)... [Pg.1341]

Chemical Name a-[ [Bisd -methylpropyOamino] methyl] -1 -[ (2-chlorophenyl)methyl] -1 H-pyrrole-2-methanol... [Pg.1578]

Although pyrrole appears to be both an amine and a conjugated diene, its chemical properties are not consistent with either of these structural features. Unlike most other amines, pyrrole is not basic—the pKa of the pyrrolin-ium ion is 0.4 unlike most other conjugated dienes, pyrrole undergoes electrophilic substitution reactions rather than additions. The reason for both these properties, as noted previously in Section 15.5, is that pyrrole has six 77 electrons and is aromatic. Each of the four carbons contributes one... [Pg.946]

The porphyrin ring system (the parent compound 1 is also known as porphin) consists of four pyrrole-type subunits joined by four methine ( = CH-) bridges to give a macrotetracycle. The macrocycle contains 227i-electrons from which 1871-electrons form a delocalized aromatic system according to Huckel s 4n + 2 rule for aromaticity. The aromaticity of the porphyrin determines the characteristic physical and chemical properties of this class of compounds. The aromatic character of porphyrins has been confirmed by determination of their heats of combustion.1"3 X-ray investigations4 of numerous porphyrins have shown the planarity of the nucleus which is a prerequisite for the aromatic character. [Pg.577]


See other pages where Chemicals pyrrole is mentioned: [Pg.242]    [Pg.242]    [Pg.67]    [Pg.81]    [Pg.106]    [Pg.424]    [Pg.43]    [Pg.31]    [Pg.354]    [Pg.36]    [Pg.39]    [Pg.45]    [Pg.30]    [Pg.30]    [Pg.30]    [Pg.78]    [Pg.5]    [Pg.16]    [Pg.195]    [Pg.6]    [Pg.513]    [Pg.8]    [Pg.180]    [Pg.116]    [Pg.332]    [Pg.299]    [Pg.578]    [Pg.580]   
See also in sourсe #XX -- [ Pg.26 ]




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