Chemical reaction cation exchange

Sodium nitrite has been synthesized by a number of chemical reactions involving the reduction of sodium nitrate [7631-99-4] NaNO. These include exposure to heat, light, and ionizing radiation (2), addition of lead metal to fused sodium nitrate at 400—450°C (2), reaction of the nitrate in the presence of sodium ferrate and nitric oxide at - 400° C (2), contacting molten sodium nitrate with hydrogen (7), and electrolytic reduction of sodium nitrate in a cell having a cation-exchange membrane, rhodium-plated titanium anode, and lead cathode (8). 

Ion exchange may be thought of as a reversible reaction involving chemically equivalent quantities. A common example for cation exchange is the familiar water-softening reaction... 

In recent years, the rate of information available on the use of ion-exchange resins as reaction catalysts has increased, and the practical application of ion-exchanger catalysis in the field of chemistry has been widely developed. Ion-exchangers are already used in more than twenty types of different chemical reactions. Some of the significant examples of the applications of ion-exchange catalysis are in hydration [1,2], dehydration [3,4], esterification [5,6], alkylation [7], condensation [8-11], and polymerization, and isomerization reactions [12-14]. Cationic resins in form, also used as catalysts in the hydrolysis reactions, and the literature on hydrolysis itself is quite extensive [15-28], Several types of ion exchange catalysts have been used in the hydrolysis of different compounds. Some of these are given in Table 1. 

Formation damage caused by clay migration may be observed when the injected brine replaces the connate water during operations such as water-flooding, chemical flooding including alkaline, and surfactant and polymer processes. These effects can be predicted by a physicochemical flow model based on cationic exchange reactions when the salinity decreases [1665]. Other models have also been presented [345,1245]. 

Several chemical geothermometers are in widespread use. The silica geothermometer (Fournier and Rowe, 1966) works because the solubilities of the various silica minerals (e.g., quartz and chalcedony, Si02) increase monotonically with temperature. The concentration of dissolved silica, therefore, defines a unique equilibrium temperature for each silica mineral. The Na-K (White, 1970) and Na-K-Ca (Fournier and Truesdell, 1973) geothermometers take advantage of the fact that the equilibrium points of cation exchange reactions among various minerals (principally, the feldspars) vary with temperature. 

Solvent exchange reactions on metal cations are among the most simple chemical reactions a solvent molecule situated in the first coordination shell of the ion is replaced by another one, normally entering from the second shell. They are generally considered as fundamental reactions for metal ions in solution, since they constitute an important step in complex-formation reactions on metal cations. The reaction is... 

L-Cysteine is a high value a-amino acid used world-wide in a scale of 1200-15001 year-1 as additive in foodstuffs, cosmetics or as intermediate or active agent (as antidote to several snake venoms) in the pharmaceutical industry. Chemical routes generally lack the efficiency of electrochemical techniques, or they produce mixtures of l- and d- forms rather than the L-isomer. The most common electrochemical route is the cathodic reduction of L-Cystine in acid (usually HC1) solution to produce the stable hydrochloride. In Table 10, the charateristic data for a laboratory bench, laboratory pilot and a product pilot reaction using a DEM filter press are compared [13]. A production scale study was carried out in a filterpress reactor divided by a cation exchange membrane with a total area of 10.5 m2. The typical product inventory was 450 kg/24-hour batch time. For more details see Ref. [13]. 

Under saturated or very wet conditions, soils tend to have increased amounts of OM. This results in dark colors and dramatically changes the chemical characteristics of a soil. OM increases a soil s sorptive and cation exchange capacities and thus alters the movement and extraction of components present. OM increases ped formation and stability, thus increasing both aeration and percolation, but under saturated conditions, reduction reactions prevail (see Figure 2.12). 

Cation-exchange resins are used as catalysts in the produdion of MTBE (methyl tertiary-butyl ether, 2-methoxy-2-methylpropane) and various other oxygenates and, lately, also in the dimerization of isobutene [30]. Other commercial applications of the cation-exchange resins indude dehydration of alcohols, alkylation of phenols, condensation readions, alkene hydration, purification of phenol, ester hydrolysis and other reactions [31]. The major producers of ion-exchange resins are Sybron Chemicals Incorporated [32] (Lewatit resins), Dow Chemical Company [33] (DOWEX resins), Purolite [28] (Purolite resins), and Rohm and Haas Company [27] (Amberlyst resins). 

Zeolite catalysts play a vital role in modern industrial catalysis. The varied acidity and microporosity properties of this class of inorganic oxides allow them to be applied to a wide variety of commercially important industrial processes. The acid sites of zeolites and other acidic molecular sieves are easier to manipulate than those of other solid acid catalysts by controlling material properties, such as the framework Si/Al ratio or level of cation exchange. The uniform pore size of the crystalline framework provides a consistent environment that improves the selectivity of the acid-catalyzed transformations that form C-C bonds. The zeoHte structure can also inhibit the formation of heavy coke molecules (such as medium-pore MFl in the Cyclar process or MTG process) or the desorption of undesired large by-products (such as small-pore SAPO-34 in MTO). While faujasite, morden-ite, beta and MFl remain the most widely used zeolite structures for industrial applications, the past decade has seen new structures, such as SAPO-34 and MWW, provide improved performance in specific applications. It is clear that the continued search for more active, selective and stable catalysts for industrially important chemical reactions will include the synthesis and application of new zeolite materials. 

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