Cathodic protection continued types

For several years now, cable ducts have been manufactured from plastic pipes, which are watertight and form a continuous run of piping. In laying the ducts, low points can occur in which condensed water or water penetrating from the ends can collect. In many cases this water has led to corrosion damage in lead-sheathed cables. Lead-sheathed cables must therefore only be used in such ducts with an additional PE sheath of type A-PM2Y. Cathodic protection of these cables is not possible because of their complete insulation by the plastic pipe. 

In plain tinplate cans for acid foods, tin provides cathodic protection to steel (3,4). The slow dissolution of tin prevents steel corrosion. Many investigators (5-1I) have defined this mechanism in detail and have shown that the tin dissolution rate is a function of the cathodic activity of the base steel, the steel area exposed through the tin and the tin-iron alloy layers, and the stannous ion concentration. Kamm et al. showed that control of the growth of the tin—iron alloy layer provides a nearly continuous tin-iron alloy layer and improves the corrosion resistance of heavily coated (over 45 X 10"6 in. tin) ETP for mildly acid food products in which tin provides cathodic protection to steel (12). The controlled tin-iron alloy layer reduces the area of steel exposed to the product. ETP with the controlled alloy is designated type K, and since 1964, 75 type K ETP has been used to provide the same protection as 100 ETP provided previously (13). 

Domestic or industrial hot-water heaters of galvanized steel through which hot aerated water passes continuously are not protected reliably in all types of water by nontoxic chemical additions such as silicates or polyphosphates. Adjustment of the saturation index to a more positive value, as discussed earlier, is sometimes helpful. Often, cathodic protection or use of nonferrous metals, such as copper or 70% Ni-Cu (Monel), is the best or only practical measure. 

In recent years, continuous zinc ribbon anodes have been used in a variety of underground applications (Kurr, 1973 Peabody, 1976 O Connell, 1977). This type of product has broadened the applications for zinc anodes, for it provides small increments of current continuously along the entire length of a cathode. Its uses are generally considered to lie in specialty applications, where other methods of cathodic protection are either impractical or extremely costly (see later section on induced ac on pipelines). Bagnulo (1973, 1984) has developed a tape with an electrically conducting adhesive as described in the Mechanical Coatings part of Chapter 1. 

A single sacrificial anode attached to one end of a pipe can normally, and in freshly piped seawater, protect the internal surfaces of a pipe only up to 2-3 diameters in depth and installation of a continuous strip anode may be required. In stagnant seawater, however, even 12-50 mm (0.5-2 inches) nominal diameter stainless steel (e.g. Type 304) and copper pipes can obtain effective cathodic protection after an initial polarization period, which can vary between four days, for 5 cm (2 in) diameter stainless steel pipe, and 186 days for 12mm (0.5 inch) diameter copper pipe, by a single sacrificial anode fitted to one end to a depth of approximately 6 m (20 ft). 

With insufficient carbon dioxide of type 3 (and none of type 4) the water will be supersaturated with calcium carbonate and a slight increase in pH (at the local cathodes) will tend to cause its precipitation. If the deposit is continuous and adherent the metal surface may become isolated from the water and hence protected from corrosion. If type 4 carbon dioxide is present there can be no deposition of calcium carbonate and old deposits will be dissolved there cannot therefore be any protection by calcium carbonate scale. 

For these reasons, the cathodic corrosion protection of chemical plant parts is restricted to neutral solutions, service water, and alkalis. Various types of anodes are available for the protection of container interiors. Platinized disk electrodes, bar anodes, and titanium basket anodes are used. They are now supplied ready for installation and are designed in such a way that, in continuous operation, they can emit 8-10 A at a current density of 6-8 A/dm. ... 

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