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Hydrogenation of benzene, catalytic

The solid is used as a heterogeneous catalyst or as a water-soluble system in biphasic conditions in the hydrogenation of benzene and pheny-lacetylene [65]. The heterogeneous system Rh-PVP is investigated in the solid/liquid catalytic hydrogenation of benzene with a ratio of 1/34000 at 80 °C and 20 bar H2. The conversion into cyclohexane is about 60% after 200 h of reaction time. In a water/benzene biphasic condition at 30 °C and under 7 bar H2, complete hydrogenation (Scheme 2) for a molar ratio of 2000 is observed after 8 h giving a TOF = 675 h (related to H2 consumed), never-... [Pg.266]

The rhodium cyclopentadienyl complex [T75-C5(CH3)5RhCl2]2, in the presence of base at 50 atm H2, also effects stereoselective catalytic hydrogenation of benzenes. Substrates with unprotected —OH or —C02H groups were not effectively hydrogenated, but aryl ethers, esters, and ketones and N,iV -dimethylaniline were all reduced, some-... [Pg.377]

Adipic acid (1,4-butanedicarboxylic acid) is used for the production of nylon-6,6 and may be produced from the oxidation of cyclohexane as shown in structure 17.1. Cyclohexane is obtained by the Raney nickel catalytic hydrogenation of benzene. Both the cyclohexanol and cyclohexanone are oxidized to adipic acid by heating with nitric acid. [Pg.530]

Catalytic hydrogenation of benzene cannot be stopped at cyclohexene or cyclohexadiene it proceeds to cyclohexane. This is because the rate of the first addition step is much slower than of the subsequent steps ... [Pg.1074]

Catalytic hydrogenation of benzene to cyclohexane takes place at elevated temperatures and pressures, often catalyzed by ruthenium or rhodium-based catalysts. Substituted benzenes react to give substituted cyclohexanes disubstituted benzenes usually give mixtures of cis and trans isomers. [Pg.796]

Catalytic hydrogenation of benzene is the commercial method for producing cyclohexane and substituted cyclohexane derivatives. The reduction cannot be stopped at an intermediate stage (cyclohexene or cyclohexadiene) because these alkenes are reduced faster than benzene. [Pg.797]

Application Produce high-purity cyclohexane by liquid-phase catalytic hydrogenation of benzene. [Pg.51]

If one measures the net rate of reaction near equilibrium and plots the results against AF/RTj the points should fall on a straight line whose slope is equal to sRb- If one now repeats such measurements with different starting concentrations of the reacting species, one can deduce the dependence of Rb on concentrations and hence the form of the rate laws for the system. Such measurements have been made for the catalytic hydrogenation of benzene by Prigogine et al. with confirmation of the relationships shown. [Pg.75]

Catalytic hydrogenation of benzene under pressure by using Raney Ni as a catalyst results in the addition of three molar equivalents of hydrogen. First, benzene is converted into cyclohexadiene, which is reduced to cyclohexene. The hydrogenation of cyclohexadiene and cyclohexene is faster than the hydrogenation of benzene (aromatic compound). Similarly, catalytic hydrogenation of naphthalene in the presence of a Ni catalyst gives tetralin and then decalin. [Pg.231]

Separation of benzene/cyclohexane mixture is investigated most extensively. This is not surprising because separation of this mixture is very important in practical terms. Benzene is used to produce a broad range of valuable chemical products styrene (polystyrene plastics and synthetic rubber), phenol (phenolic resins), cyclohexane (nylon), aniline, maleic anhydride (polyester resins), alkylbenzenes and chlorobenzenes, drugs, dyes, plastics, and as a solvent. Cyclohexane is used as a solvent in the plastics industry and in the conversion of the intermediate cyclohexanone, a feedstock for nylon precursors such as adipic acid. E-caprolactam, and hexamethylenediamine. Cyclohexane is produced mainly by catalytic hydrogenation of benzene. The unreacted benzene is present in the reactor s effluent stream and must be removed for pure cyclohexane recovery. [Pg.257]

Derivation (1) Catalytic hydrogenation of benzene. (2) Constituent of crude petroleum. [Pg.358]

Finally, we discuss briefly how the neutron seattering results eontribute to our understanding of the catalytic hydrogenation of benzene. [Pg.328]

Catalytic hydrogenation of benzene to cyclohexane (see Section 12.1), normally in the liquid phase, around 200°C, at 4.10 Pa absolute, in the presence of a uckel or platinum base catalyst, which is highly sensitive to the existence of shlfur compounds in the raw material... [Pg.122]

The catalytic hydrogenation of benzene has been carried out as a model reaction to increase the hydrogenated cyclic compounds from aromatics. Catalyst samples containing nickel on different supports were prepared and tested. It was found that a-Al203 supported nickel showed the best activity for benzene conversion reaction. Nickel metal area, its dispersion and nickel crystal size were determined. The best activity is obtained with 40% nickel concentration (as oxide) and at the optimum nickel crystallite size of 196A° and optimum metal area of 10.8m2/g. [Pg.793]

Among four different supports, a - AI2O3, y - AI2O3, Kieselguhr and MgO, nickel on a-Al203 is the best choice for catalytic hydrogenation of benzene. The activity of benzene hydrogenation increases with the increase of nickel concentration upto 40% NiO, after which increase of concentration the opposite trend is noticed. Similarly, an optimum value of nickel dispersion, metal area and its crystallite size have also been observed. [Pg.797]

Over 1.2 billion lbs of cyclohexane are produced annually, mostly from the catalytic hydrogenation of benzene. 60% of this cyclohexane is used to make adipic acid and 30% to make caprolactam, both of which are used to make nylon apparel and carpets. Cyclohexane also is used as a solvent and in making derivatives of cyclohexanol and cyclohexanone, which are used in making dyes, pesticides, and other specialties. [Pg.516]

MC Shoenmaker-Stolk, JW Verwijs, JA Don, JJF Scholten. The catalytic hydrogenation of benzene over supported metal catalysts. 1. Gas-phase hydrogenation of benzene over ruthenium-on-silica. Appl Catal 29 73-90, 1987. [Pg.480]

H, A. Smith University of Tennessee)-. Dr. Siegel (Lecture 4) suggests that his experiments indicate that a cyclohexene-type intermediate is formed in the catalytic hydrogenation of benzene. Further evidence for this is found in the hydrogenation of phenols, for when these are reduced under a variety of conditions and over a number of catalysts, cyclohexanone is formed as an intermediate and is readily isolated. The best explanation for this appears to be the addition of two moles of hydrogen per mole of phenol to form a cyclohexenol which isomerizes to cyclohexanone before further hydrogenation takes place. The cyclohexanone is desorbed from the catalyst, and may be subsequently reduced to cyclohexanol. [Pg.85]

Cyclohexane is produced by the catalytic hydrogenation of benzene. The chemistry is shown in Eq. (1). [Pg.199]

Catalytic hydrogenation of benzene rings is also dependent on the substituent, but the order of reactivity depends on the nature of the catalyst. ... [Pg.78]

Cyclohexane is a petroleum product obtained by distilling C4- 400°F boiling range naphthas, followed by fractionation and superfractionation also formed by catalytic hydrogenation of benzene. It is used extensively as a solvent for lacquers and resins, as a paint and varnish remover, and in the manufacture of adipic acid, benzene, cyclohexanol, and cyclohexanone. [Pg.508]


See other pages where Hydrogenation of benzene, catalytic is mentioned: [Pg.97]    [Pg.151]    [Pg.136]    [Pg.125]    [Pg.46]    [Pg.47]    [Pg.378]    [Pg.377]    [Pg.15]    [Pg.192]    [Pg.203]    [Pg.2975]    [Pg.28]    [Pg.378]    [Pg.264]    [Pg.120]    [Pg.227]    [Pg.228]    [Pg.64]    [Pg.793]    [Pg.49]    [Pg.33]    [Pg.337]    [Pg.2974]    [Pg.757]    [Pg.85]    [Pg.318]   
See also in sourсe #XX -- [ Pg.645 ]




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