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Metal catalytic homogeneous acylations

Ionic liquids can be used as replacements for many volatile conventional solvents in chemical processes see Table A-14 in the Appendix. Because of their extraordinary properties, room temperature ionic liquids have already found application as solvents for many synthetic and catalytic reactions, for example nucleophilic substitution reactions [899], Diels-Alder cycloaddition reactions [900, 901], Friedel-Crafts alkylation and acylation reactions [902, 903], as well as palladium-catalyzed Heck vinylations of haloarenes [904]. They are also solvents of choice for homogeneous transition metal complex catalyzed hydrogenation, isomerization, and hydroformylation [905], as well as dimerization and oligomerization reactions of alkenes [906, 907]. The ions of liquid salts are often poorly coordinating, which prevents deactivation of the catalysts. [Pg.323]

Metal hydrides and acyl-like CO insertion products are two types of species likely to be present in any homogeneous or heterogeneous process for the catalytic reduction of carbon monoxide. The discovery and understanding of new types of reactivity patterns between such species are of fundamental interest. As discussed elsewhere (11,22,54-57), bis(pentamethylcyclo-pentadienyl) actinide hydrides (58) are highly active catalysts for olefin hydrogenation as well as H-H and C-H activation. [Pg.70]

Carbonylation-Decarbonylation. These reactions constitute a large and important segment of the homogeneous catalytic literature. Catalysis by most of the group VIII noble metals has been found, and a variety of substrates have been converted. For example, olefins react with CO and PdCl2 or (< 3P)2PdCl2 to yield -chloroacyl chlorides (58) and unsaturated acyl chlorides (59), respectively, a, w-Dienes, such as... [Pg.208]

Ojima and co-workers have undertaken extensive research into the formation of AT-acyl-a-amino acids via amidocarbonylation chemistry [5]. Their focus includes the generation of A -acyl-a-amino acids directly from allyl alcohols, oxiranes, or olefins using homogeneous binary catalyst systems, particularly cobalt octacarbo-nyl - Group VIII transition-metal complex combinations. New catalytic processes feature ... [Pg.157]

The search for new reactivity and new reactions is an important target in homogeneous catalysis. A declared goal is the selective activation of C-H bonds under mild conditions. Although there are numerous examples of stoichiometric C-H bond oxidative additions to transition metal centers, successful examples regarding catalytic functionalization of C-H bonds have been made only during the last five years. Notable advances have been achieved by Moore and coworkers who described in 1992 the ortAo-acylation of pyridine with olefins and carbon monoxide. The cluster compound triruthenium dodecacarbonyl has been used as catalyst (Scheme 10). [Pg.9]

Ionic liquids in combination with supercritical fluids are a versatile tool for the immobilization and recycling of homogeneous catalysts, allowing continuous Friedel-Crafts acylation reactions to be realized. The acylation of anisole with acetic anhydride is carried out in a flow system using a metal triflate immobilized in the ionic liquid 1 -butyl-4-methylpyridinium bis(trifluoro-methylsulfonyl)imide as catalyst and scCO as continuous extraction phase [22]. Different metal triflates are utilized under continuous flow conditions using high pressure yttrium triflate possesses the best balance between sufficient acidity for catalytic activity and softness to release the product and so permits a good catalyst reuse (TONs up to 190). [Pg.63]

Reviews.—Recent reviews involving olefin chemistry include olefin reactions catalysed by transition-metal compounds, transition-metal complexes of olefins and acetylenes, transition-metal-catalysed homogeneous olefin disproportionation, rhodium(i)-catalysed isomerization of linear butenes, catalytic olefin disproportionation, the syn and anti steric course in bi-molecular olefin-forming eliminations, isotope-elfect studies of elimination reactions, chloro-olefinannelation, Friedel-Crafts acylation of alkenes, diene synthesis by boronate fragmentation, reaction of electron-rich olefins with proton-active compounds, stereoselectivity of carbene intermediates in cycloaddition to olefins, hydrocarbon separations using silver(i) systems, oxidation of olefins with mercuric salts, olefin oxidation and related reactions with Group VIII noble-metal compounds, epoxidation of olefins... [Pg.77]

In Section 8.3.3 several examples of cascade systems involving homogeneous catalytic and enzymatic reactions were presented. There are also examples when heterogeneous catalytic reactions are combined with enzymatic catalysis. Fig. 8.35 shows a combination of a heterogeneous catalytic reaction (hydrogenation of a ketone over a supported metal catalyst) and an enzymatic one (acylation of obtained R-alcohol into the corresponding to R-acetate over an immobilized enzyme, Upase). [Pg.478]


See other pages where Metal catalytic homogeneous acylations is mentioned: [Pg.43]    [Pg.284]    [Pg.79]    [Pg.252]    [Pg.13]    [Pg.142]    [Pg.50]    [Pg.533]    [Pg.152]   
See also in sourсe #XX -- [ Pg.54 ]




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