Catalyst physical properties

Important physical properties of catalysts include the particle size and shape, surface area, pore volume, pore size distribution, and strength to resist cmshing and abrasion. Measurements of catalyst physical properties (43) are routine and often automated. Pores with diameters <2.0 nm are called micropores those with diameters between 2.0 and 5.0 nm are called mesopores and those with diameters >5.0 nm are called macropores. Pore volumes and pore size distributions are measured by mercury penetration and by N2 adsorption. Mercury is forced into the pores under pressure entry into a pore is opposed by surface tension. For example, a pressure of about 71 MPa (700 atm) is required to fill a pore with a diameter of 10 nm. The amount of uptake as a function of pressure determines the pore size distribution of the larger pores (44). In complementary experiments, the sizes of the smallest pores (those 1 to 20 nm in diameter) are deterrnined by measurements characterizing desorption of N2 from the catalyst. The basis for the measurement is the capillary condensation that occurs in small pores at pressures less than the vapor pressure of the adsorbed nitrogen. The smaller the diameter of the pore, the greater the lowering of the vapor pressure of the Hquid in it. 

The ash content of the DO is affected by the reactor cyclone s performance and catalyst physical properties. To meet the CBFS ash requirement (maximum of 0.05 wt%), DO product may need to be filtered for the removal of the catalyst fines. 

Once the unit is running well, it is often assumed that the aeration system is sized properly, but changes in the catalyst physical properties and/or catalyst circulation rate may require a different purge rate. It should be noted that aeration rate is directly proportional to catalyst circulation rate. Trends of the E-cat properties can indicate changes in the particle size distribution, which may require changes in the aeration rate. Restriction orifices could be oversized, undersized, or plugged with catalyst, resulting in over-aeration, under-aeration, or no aeration. All these phenomena cause low pressure buildup and low slide valve differential. 

Consider reformulating the catalyst—custom formulations are available. Increasing rare-earth content can reduce the wet gas rate. Catalyst is usually selected for properties other than its ability to flow. However, if it does not flow, it is not going to work well. Catalyst physical properties should be compared with those of catalysts that have circulated well. Evaluate the economics of using metal passivation additives and other catalyst enhancing additives. 

Model formulation. After the objective of modelling has been defined, a preliminary model is derived. At first, independent variables influencing the process performance (temperature, pressure, catalyst physical properties and activity, concentrations, impurities, type of solvent, etc.) must be identified based on the chemists knowledge about reactions involved and theories concerning organic and physical chemistry, mainly kinetics. Dependent variables (yields, selectivities, product properties) are defined. Although statistical models might be better from a physical point of view, in practice, deterministic models describe the vast majority of chemical processes sufficiently well. In principle model equations are derived based on the conservation law ... 

Improved Filtration Rate Filterability is an important powder catalyst physical property. Sometimes, it can become more important than the catalyst activity depending on the chemical process. When a simple reaction requires less reaction time, a slow filtration operation can slow down the whole process. From a practical point of view, an ideal catalyst not only should have good activity, but also it should have good filtration. From catalyst development point of view, one should consider the relationship between catalyst particle size and its distribution with its catalytic activity and filterability. Smaller catalyst particle size will have better activity but will generally result in slower filtration rate. A narrower particle size distribution with proper particle size will provide a better filtration rate and maintain good activity. 

Optimizing the fresh catalyst physical properties including particle density, PSD, and attrition resistance is critical to maintaining acceptable fluidization and resulting circulation of the catalyst inventory. Excessive attrition of the catalyst will lead to nonuniform fluidization and disrupt circulation. Potential sources of attrition include ... 

The circulating catalyst physical properties have a direct impact on fluidization and stable standpipe operation. Mechanical problems may cause a loss of catalyst fines, or a change in catalyst density both of which will impact fluidization and may require adjustment to the standpipe aeration. 

The catalyst has been developed by Intevep, S. A. [4,5] and is being commercialized by AZKO NOBEL Chemie from Holland under the trademark INT-R1 High molecular weight compounds are able to be processed with the catalyst due to its special pore distribution. Therefore, it can be used to treat feedstocks with a significant asphaltene content without losing its high desulfurization and demetallization activity. Also, the catalyst has a high metal retention capacity and allows for moderate conversion of the 510°C fraction. INT-R1 catalyst physical properties are shown in Table 1. 

Ke)words elastomeric polypropylene (ELPP), thermoplastic elastomeric polypropylene, TPE, metallocene catalysts, physical properties, applications, tacticity, elasticity, regioregularity, stereoselectivity. 

This section deals with the methods of preparation of porous SiC and SiO, Al2C and SiC based catalysts. Physical properties of the applied supports are shown in Table 1. 

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