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Carbonyl bromide cyanide

N,N -carbonyl bis(4-methoxy metanilic acid) disodium salt sal disodica de N,N -carbonil bis(acido 4-metoximetanriico) carbonyl bromide bromuro de carbonilo carbonyl chloride cloruro de carbonilo carbonyl cyanide cianuro de carbonilo carbonyl fluoride fluoruro de carbonilo carbonyl group gmpo carbonilo carbonyl sulfide sulfuro de carbonilo l,l -carbonyldi-imidazole l,l -carbonildi-imidazol... [Pg.52]

Allyl chlorides and bromides are readily carbonylated to unsaturated acids using nickel cyanide and phase transfer catalysis conditions. Mechanistic studies revealed that the key catalytic species in this reaction is the cyanotricarbonylnickelate ion(20). [Pg.13]

Synonym Neatsfoot Oil Necatorina Nechexane Neutral Ahhonium Pluoride Neutral Anhydrous Calcium Hypochlorite Neutral Lead Acetate Neutral Nicotine Sulfate Neutral Potassium Chromate Neutral Sodium Chromatetanhydrous Neutral Verdigris Nickel Acetate Nickel Acetate Tetrahyorate Nickel Ammonium Sulfate Nickel Ammonium Sulfate Hexahydrate Nickel Bromide Nickel Bromide Trihydrate Nickel Carbonyl Nickel Chloride Nickel Chloride Nickel Cyanide Nickel Iiu Fluoborate Nickel Fluoroborate Solution Nickel Fluoroborate Nickel Formate Nickel Formate Dihyorate Nickel Nitrate Nickel Nitrate Hexahydrate Nickel Sulfate Nickel Tetracarbokyl Nickelous Acetate Nickelous Sulfate Nicotine Nicotine Sulfate Nifos Nitralin Nitram O-Nitraniline P-Nitraniline Nitric Acid Nitric Acid, Aluminum Salt Nitric Acid, Iron (111) Salt Compound Name Oil Neatsfoot Carbon Tetrachloride Neohexane Ammonium Fluoride Calcium Hypochlorite Lead Acetate Nicotine Sulfate Potassium Chromate Sodium Chromate Copper Acetate Nickel Acetate Nickel Acetate Nickel Ammonium Sulfate Nickel Ammonium Sulfate Nickel Bromide Nickel Bromide Nickel Carbonyl Nickel Chloride Nickel Chloride Nickel Cyanide Nickel Fluoroborate Nickel Fluoroborate Nickel Fluoroborate Nickel Formate Nickel Formate Nickel Nitrate Nickel Nitrate Nickel Sulfate Nickel Carbonyl Nickel Acetate Nickel Sulfate Nicotine Nicotine Sulfate Tetraethyl Pyrophosphate Nitralin Ammonium Nitrate 2-Nitroaniline 4-Nitroaniline Nitric Acid Aluminum Nitrate Ferric Nitrate... [Pg.69]

Acetone Alkali cyanides, hydrides, metals Aluminum borohydride, carbide, hydride nitride Benzoyl chloride Boron compounds Carbonyls Chlorine Cyanogen Cyanogen bromide Cyanogen chloride... [Pg.1027]

The organoindium reagent, prepared from indium metal and bromoacetonitrile, reacts with carbonyl compounds in the presence of chlorotrimethylsilane to give /3-hydroxy nitriles (Scheme 93),336 337 Similarly, indium-mediated coupling of bromoacetonitrile or 2-bromopropionitrile with a variety of aromatic acyl cyanides affords the corresponding aromatic a-cyanoketones in moderate to good yields under mild and neutral conditions (Equation (86)).338 Carbonyl compounds are efficiently transformed into 2,2-dichloro-3-hydroxynitriles by the action of trichloroaceto-nitrile and indium(i) bromide (Scheme 94).339 Bromocyanomethylation of carbonyl compounds is also achieved by the reaction of dibromoacetonitrile and indium(i) bromide.340... [Pg.708]

We have used nitro groups very extensively so far and that is only right and proper as they are the best at stabilizing the anionic intermediate. Others that work include carbonyl, cyanide, and sulfur-based groups such as sulfoxides and sulfones. Here is a direct comparison for the displacement of bromide ion by the secondary amine piperidine. First the reaction with a carbonyl group. [Pg.595]

Acid-catalyzed addition of aliphatic, aromatic or heteroaromatic cyanohydrins to ethyl vinyl ether, n-butyl vinyl ether or dihydro-4//-pyran provides base stable, protected cyanohydrin derivatives. Phase transfer catalyzed alkylation of aliphatic cyanohydrins with allylic bromides gave a-substituted a-allyl-oxyacetonitrile. Carbonyl compounds react wiA cyanide under phase transfer catalysis to give cyanohydrin anions, which are trapped by an acyl chloride or ethyl chloroformate to give acyl- or alkoxycarbonyl-protected cyanohydrins respectively. The reduction of the carbonyl group of an acyl cyanide by NaBH4 under phase transfer conditions followed by esterification serves as an alternative route to aldehyde-derived cyanohydrin esters. ... [Pg.551]

Phosgene can be used as the starting material for the preparation of other potentially useful carbonyl halides and carbonyl pseudohalides. Reaction of phosgene with fluorspar, for example, gives COCIF (see Section 9.1.1 and Chapter 16). With aluminium(III) bromide, COBrj is formed (Section 9.1.2.6). Reaction of COClj with HF gives COFj (see Section 9.10.4 and Chapter 13), reaction with silver cyanide gives carbonyl dicyanide, CO(CN)j (Section 9.1.7), whereas reaction with a mixture of sodium fluoride and HCN gives the mixed carbonyl halide pseudohalide, COFCN (Section 9.1.7 and Chapter 13). The chemistry of these... [Pg.216]


See other pages where Carbonyl bromide cyanide is mentioned: [Pg.1306]    [Pg.4760]    [Pg.73]    [Pg.160]    [Pg.217]    [Pg.41]    [Pg.1122]    [Pg.104]    [Pg.110]    [Pg.201]    [Pg.201]    [Pg.202]    [Pg.546]    [Pg.631]    [Pg.26]    [Pg.54]    [Pg.33]    [Pg.29]    [Pg.35]    [Pg.82]    [Pg.47]    [Pg.198]    [Pg.89]    [Pg.1761]    [Pg.959]   
See also in sourсe #XX -- [ Pg.57 , Pg.58 ]




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