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Building Bonds

JwJm any atoms are prone to public displays of affection, pressing themselves igainst other WWW atoms in an intimate electronic embrace called bonding. Atoms bond with one another by playing various gcimes with their valence electrons. In this chapter, we describe the basic rules of those games. [Pg.59]

To determine the electron dot structure of any element, count the number of electrons in that element s valence shell. Then draw that number of dots around the chemical symbol for the element. To do so, imagine the chemical symbol as a square. Start from the top of the symbol and, going clockwise, put one dot on each side until you run out of valence electrons. Don t double up on any side until you ve gone around the square once. [Pg.59]

Chapter 4 describes some of the factors that determine whether atoms gain or lose electrons to form ions. Make sure you understand those patterns before attacking this chapter. [Pg.59]

Electron dot structures for elements in the first two rows of the periodic table. [Pg.59]

The transfer of an electron from sodium to chlorine to form an ionic bond between the Na+ cation and the Cl anion. [Pg.60]


Step 2 Use matching valence-shell atomic orbitals to build bonding and antibonding molecular orbitals and draw the resulting molecular orbital energy-level diagram (Figs. 3.31 and 3.32). [Pg.244]

Chira (1993) suggests that teachers in these schools have the opportunity for building bonds that are particularly vital during the troubled years of adolescence. Even students from troubled homes respond to smaller, more caring schools. They are shining stars you thought were dull, said a New York City teacher. If you re under a lot of pressure and stress, they help you through that, said a student. They won t put you down or put you on hold (Chira, 1993). [Pg.279]

Once the nonproductive stock is mixed in an internal mixer in the second-stage cross-linking agents, accelerators are added to the nonproductive stock, which can then be shaped into final form and cured. The curing process is a chemical cross-linking reaction that builds bonds between rubber molecules. [Pg.7955]

Clusters are intennediates bridging the properties of the atoms and the bulk. They can be viewed as novel molecules, but different from ordinary molecules, in that they can have various compositions and multiple shapes. Bare clusters are usually quite reactive and unstable against aggregation and have to be studied in vacuum or inert matrices. Interest in clusters comes from a wide range of fields. Clusters are used as models to investigate surface and bulk properties [2]. Since most catalysts are dispersed metal particles [3], isolated clusters provide ideal systems to understand catalytic mechanisms. The versatility of their shapes and compositions make clusters novel molecular systems to extend our concept of chemical bonding, stmcture and dynamics. Stable clusters or passivated clusters can be used as building blocks for new materials or new electronic devices [4] and this aspect has now led to a whole new direction of research into nanoparticles and quantum dots (see chapter C2.17). As the size of electronic devices approaches ever smaller dimensions [5], the new chemical and physical properties of clusters will be relevant to the future of the electronics industry. [Pg.2388]

In practice, each CSF is a Slater determinant of molecular orbitals, which are divided into three types inactive (doubly occupied), virtual (unoccupied), and active (variable occupancy). The active orbitals are used to build up the various CSFs, and so introduce flexibility into the wave function by including configurations that can describe different situations. Approximate electronic-state wave functions are then provided by the eigenfunctions of the electronic Flamiltonian in the CSF basis. This contrasts to standard FIF theory in which only a single determinant is used, without active orbitals. The use of CSFs, gives the MCSCF wave function a structure that can be interpreted using chemical pictures of electronic configurations [229]. An interpretation in terms of valence bond sti uctures has also been developed, which is very useful for description of a chemical process (see the appendix in [230] and references cited therein). [Pg.300]

There is the possibility of building up an extensive systematic chemistry of compounds containing boron-nitrogen bonds, analogous to the chemistry of carbon-carbon bonds but the reactivity of the B—bond is much greater than that of the C—C bond, so that we get physical, but not chemical, resemblances between analogous compounds. [Pg.146]

As was said in the introduction (Section 2.1), chemical structures are the universal and the most natural language of chemists, but not for computers. Computers woi k with bits packed into words or bytes, and they perceive neither atoms noi bonds. On the other hand, human beings do not cope with bits very well. Instead of thinking in terms of 0 and 1, chemists try to build models of the world of molecules. The models ai e conceptually quite simple 2D plots of molecular sti uctures or projections of 3D structures onto a plane. The problem is how to transfer these models to computers and how to make computers understand them. This communication must somehow be handled by widely understood input and output processes. The chemists way of thinking about structures must be translated into computers internal, machine representation through one or more intermediate steps or representations (sec figure 2-23, The input/output processes defined... [Pg.42]

One can start building up a list of MM3 parameters by use of the TINKER analyze command. Don t expect to build up the entire set, which occupies about 100 pages in the MM3 user s manual, but do obtain a few representative examples to get an idea of how a parameter set is constr ucted. From previous exercises and projects, you should have input and output geometries for an alkene, an alkane, and water. From these, the object is to determine the stretching and bending parameters for the C—C, C=C, C—H, and O—H bonds. The C—H bond parameters are not the same... [Pg.117]

Assisted model building with energy refinement (AMBER) is the name of both a force field and a molecular mechanics program. It was parameterized specifically for proteins and nucleic acids. AMBER uses only five bonding and nonbonding terms along with a sophisticated electrostatic treatment. No cross terms are included. Results are very good for proteins and nucleic acids, but can be somewhat erratic for other systems. [Pg.53]

ChemSketch has some special-purpose building functions. The peptide builder creates a line structure from the protein sequence defined with the typical three-letter abbreviations. The carbohydrate builder creates a structure from a text string description of the molecule. The nucleic acid builder creates a structure from the typical one-letter abbreviations. There is a function to clean up the shape of the structure (i.e., make bond lengths equivalent). There is also a three-dimensional optimization routine, which uses a proprietary modification of the CHARMM force field. It is possible to set the molecule line drawing mode to obey the conventions of several different publishers. [Pg.326]

The telomer obtained from the nitromethane 65 is a good building block for civetonedicarboxylic acid. The nitro group was converted into a ketone, and the terminal alkenes into carboxylic acids. The acyloin condensation of protected dimethyl dvetonedicarboxylate (141) afforded the 17-membered acyloin 142, which was modified to introduce a triple bond 143. Finally, the triple bond was reduced to give civetone (144)[120). [Pg.444]


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