Bubbling, particle production

Tsutsumi, A., Nieh, J.Y. and Fan, L.S., 1991. Role of the bubble wake in fine particle production of calcium carbonate in bubble column systems. Industrial and Engineering Chemistry Research, 30, 2328-2333. 

In(OH)3 nanopowder was prepared via the sonication of an aqueous solution of InCl3 at room temperature and at 0 °C. At these temperatures, nonsonicated hydrolysis does not occur. The role of the ultrasound radiation and the mechanism of the reaction are discussed. The proposed mechanism is based on the sonohydrolysis of In (III) ions in the outer ring, and the liquid shell, of the collapsing bubble. The product, In(OH)3, was obtained as needle-shaped particles. 

The raw ROM (run of mine) ore is reduced in size from boulders of up to 100 cm in diameter to about 0.5 cm using jaw cmshers as weU as cone, gyratory, or roU-type equipment. The cmshed product is further pulverized using rod mills and ball mills, bringing particle sizes to finer than about 65 mesh (230 p.m). These size reduction (qv) procedures are collectively known as comminution processes. Their primary objective is to generate mineral grains that are discrete and Hberated from one another (11). Liberation is essential for the exploitation of individual mineral properties in the separation process. At the same time, particles at such fine sizes can be more readily buoyed to the top of the flotation ceU by air bubbles that adhere to them. 

A fundamentally different reaction system is under development by Air Products and Chem Systems (23). In this system, synthesis gas is bubbled through a slurry consisting of micrometer-sized methanol catalyst particles suspended in a paraffinic mineral oil. The Hquid phase serves as the heat sink to remove the heat of reaction. 

The flotation process usually iuvolves three steps (/) the conditioning of the coal surface iu a slurry with reagents, (2) adhesion of hydrophobic coal particles to gas bubbles, and (J) the separation of the coal-laden bubbles from the slurry. In the conventional flotation process, when the coal particles become attached to air bubbles, the particles ate allowed to rise to the top of the flotation cell and form a stable froth layer (9). A mechanical scraper is used to remove the froth layer and separate the clean coal product from the refuse-laden slurry. 

On comparing the two flames, it is evident that the flow structure of the lean limit methane flame fundamentally differs from that of the limit propane one. In the flame coordinate system, the velocity field shows a stagnation zone in the central region of the methane flame bubble, just behind the flame front. In this region, the combustion products move upward with the flame and are not replaced by the new ones produced in the reaction zone. For methane, at the lean limit an accumulation of particle image velocimetry (PIV) seeding particles can be seen within the stagnation core, in... 

The study of flotation kinetics relates to a number of mass transfer processes and these are listed in Table 2.8. The term, entrainment which figures in the mass transfer process statements made in Table 2.8 may be elaborated. It is the process by which particles enter the base of a flotation froth and are transferred up and out of the flotation cell suspended in the water between bubbles. Entrainment should be distinguished from true flotation, whereby particles come out of the cell attached to bubble surfaces. True flotation is chemically selective, while the entrainment process recovers both gangue and valuable minerals alike. Entrainment harms the product grade since recovery of the more abundant gangue mineral reduces the quality of the concentrate. This is especially true in the processing of fine ores. Much flotation research has dealt with reducing entrainment in order to improve... 

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