Bottom explosion

Fig. 5. Photomicrograph of titanium, top, to carbon steel, bottom, explosion clad (100a ).

Bottom explosion. (See "No lift.) This is an accident where a shell explodes in the mortar without ascending. This generally occurs when the lifting charge is missed and the igniter, a Sindoro, is thrown into the mortar. If it is a report shell or chrysanthemum the mortar is broken into pieces, and it is quite dangerous. However if it is a quick firing shell such an accident does not occur. 

Fit a 3-litre rovmd-bottomed flask with a long reflux condenser and a dropping funnel (1). Place a mixture of 400 ml. of concentrated nitric acid and 600 ml. of water in the flask and heat nearly to boiling. Allow 100 g. (116 ml.) of cycZopentanone (Section 111,73) to enter the hot acid dropwise, taking care that the first few drops are acted upon by the acid, otherwise an explosion may occur the addition is complete in 1 hour. Much heat is evolved in the reaction so that the flame beneath the flask must be considerably lowered. Omng to the evolution of nitrons fumes, the reaction should be carried out in the fume cupboard or the fumes... 

Fit up a 1 -litre round-bottomed flask for steam distillation (Fig. II, 40,1) and place in it 22 g. of iodosobenzene (Section IV.25) made into a thin paste with water (1). Steam distil until almost all the iodobenzene has been removed (about 9 g.) cool the residue in the flask at once, filter the white solid with suction and dry in the air. Wash it with a little chloroform, filter with suction, and dry in the air upon filter paper. The yield is 10-5 g. It may be recrystallised from 800-900 ml. of water, lodoxybenzene melts with explosive decomposition at 237°,... 

Allowing DRI to become wet does not necessatily cause it to overheat. When large pdes of DRI are wetted with rain, the corrosion reactions are limited to the outer surface area of the pde and the resultant heat from the corrosion reactions is dissipated into the atmosphere. However, if water penetrates into the pde from the bottom, or if wet DRI is covered with dry DRI, the heat from corrosion reactions can budd up inside the pde to the point where rapid reoxidation begins. Corrosion occurs significantly faster with salt water than with fresh water. DRI saturated with water can cause steam explosions if it is batch charged into an electric arc furnace. 

U gine- Kuhlmann steel steel bottom, titanium top mbber as explosion hatch titanium... 

Through-ckculation compartments employ perforated or screen bottom trays and suitable flow baffles so gas is forced through the material. If material is not inherently pervious to gas flow, it may be mechanically shaped iato noodles, pellets, or briquettes. These dryers are used ia small-scale operations to dry explosives, foods, and pigments. Dryer efficiency is 50—70%. Based on tray area, water vaporization rates are 1—10 kg/(h-m ). 

In a 2-1. round-bottomed, 3-necked flask fitted with a stirrer and two large-bore condensers are placed 200 cc. of 50 per cent nitric acid and 0.25 g. of vanadium pentoxide. The flask is heated to 65-70° in a water bath (thermometer in water), and I cc. of cyclopentanone added. Oxidation is indicated by the production of brown fumes. The water bath is removed, and 42 g. (less the i cc.) of the cyclic ketone added from a dropping funnel through the condenser at the rate of a drop every three seconds. The heat of the reaction keeps the flask at about 70°. If the temperature drops, oxidation ceases until the ketone has accumulated, when it may proceed almost explosively. In such a case, or if the temperature is higher, much succinic acid is formed. After addition has been completed, the water bath... 

Application of a welding torch or burner to a tank or drum containing flammable material, either as solid, liquid or vapour or their residues, can cause an explosion. Such vessels, although apparently empty , may have residue in the bottom and/or in seams and crevices. 

Suitability of vehicles and containers and limits on quantities for the carnage of explosives by road Approved requirements for the construction of vehicles intended for the carnage of explosives by road Approved tank requirements the provisions for bottom loading and vapour recovery systems of mobile containers caiTymg petrol... 

An old 100-m pressure vessel, a vertical cylinder, designed for a gauge pressure of 5 psi (0.3 bar), was being used to store, at atmospheric pressure, a liquid of flash point 40°C. The fire heated the vessel to above 40°C and ignited the vapor coming out of the vent the fire flashed back into the tank, where an explosion occurred. The vessel burst at the bottom seam, and the entire vessel, except for the base, and contents went into orbit like a rocket [4]. 

Explosive chemicals tend to be governed by separate legislation, e.g., in the UK, The Classification and Labelling of Explosives Regulations 1983. These require the HSE to classify any explosive before it may be supplied. Under the scheme, explosives are labelled according to a classification based on hazard division (Table 12.7), and on compatibility (Table 12.8), which takes into account their sensitivity, explosivity and chemical nature. Labels are diamond shaped the top half is reserved for the pictograph and division number, the bottom half shows the hazard code and the classification number. Figure 12.1 shows the label for Class 1, Division 1.1, 1.2 or 1.3 explosive. 

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