Biogeochemical pathways

Hayes et al. (1999) systematically evaluated the carbon isotope fractionation between carbonates and coeval organic matter for the past 800 Ma. They concluded that earlier assumptions of a constant fractionation between carbonate and organic matter is untenable and that fractionations may vary by about 10%o depending on the dominant biogeochemical pathway as well on environmental conditions. 

The inherent chemical complexity of DOM presents many challenges to understanding the role of DOM in C and N cycling and other processes in aquatic ecosystems. The measurement of trace organic moieties in major fractions of DOM, such as fulvic acids, can provide valuable data for understanding sources and biogeochemical pathways. In field studies, multiple lines of evidence can be critical for definitive interpretation of results. The tracer approaches outlined in this chapter should be used in conjunction with mass balance and flux measurements, for example. 

Radioecology After Chernobyl Biogeochemical Pathways of Artificial Radionuclides... 

Whicker EW and Finder JE (2002) Food chains and biogeochemical pathways contributions offallout and other radiotracers. Health Physics 82 680-689. 

When attempting to assess the biogeochemical pathways and health impact of metals it is crucial to determine the total concentration accurately and where possible to identify and quantify the physical and chemical forms, or species. The analytical determination of metals in sea water has had a difficult history and many measurements reported in the literature prior to about 1985 should be treated with caution. Major strides have been made in the minimization of contamination during sample collection, storage, and preparation and in the application of sensitive analytical techniques, sometimes coupled with methods for the separation of metal species. The concentrations of dissolved metals have been revised downwards in recent years as a consequence of the introduction of these advances, together with improvements in analytical quality assurance, including appropriate use of certified reference materials. 

Once the particle-reactive species have been scavenged, subsequent packaging and/or aggregation can result in the flux of particles and particle-reactive species from the water column. Thorium provides a unique way to study the environmental pathways and the biogeochemical processes that affect particle-reactive species. The four useful thorium isotopes are Th = A x yx), °Th... 

Thus, from the viewpoint of environmental risk assessment (critical loads) the most important exposure pathways are nitrate leaching and denitrification, which are both very sensitive to anthropogenic pollution. These links of biogeochemical nitrogen cycle should be firstly quantitatively parameterized to assessing environmental risk. 

BIOGEOCHEMICAL FLUXES AND EXPOSURE PATHWAYS IN SOIL-WATER SYSTEM OF BOREAL AND SUB-BOREAL ZONES... 

Biogeochemical cycling of elements and pollutants exposure pathways in the tropical ecosystems, which occur between 30°N and 30°S, are both intensive and at high probability of risk for human and ecosystem health. The tropical belt receives about 60% of solar radiation inputting on the Earth s surface. The total area of tropical ecosystems is about 40 x 106 km2, with exception of the High Mountain and Extra-Dry Sandy Deserts with strongly depressed life processes. 

Biogeochemical Cycles and Exposure Pathways of Chemical Species in Tropical Ecosystems... 

The main specificity of biogeochemical cycling and exposure pathways in Tropical Rain Forest ecosystems is related to its almost closed character. This means that almost the total number of nutrients and/or pollutants is re-circulating in biogeochemical cycles (Figure 1). 

Strontium, barium, manganese, copper, molybdenum, and nickel are elements of strong accumulation in plant species of African Savanna ecosystems, in spite of different content in soils and soil-forming rocks. The Cb values are >1. The other elements, like beryllium, zirconium, titanium and vanadium, are less taken up by plants and their Cb values are less than 0.5. These refer to various exposure pathways to both microbes and plants as links in biogeochemical food webs. 

The biogeochemical fluxes and exposure pathways of various macro- and microelements are different from those shown for Tropical Rain Forest ecosystems. The chemical composition of leaves of tree species in Mangrove Forest ecosystems is connected with higher content of Mg, Cl and S-SO4- and lesser content of K and Si as compared to the leaves of trees from Tropical Rain Forest ecosystems. The content of A1 is 3-4 times higher than that of Si and this can be related to the values of hydrogenic accumulation of these elements in soils (Figure 3). 

Many quantitative aspects of exposure pathways and their relevant application during environmental risk assessment depend on regional biogeochemical peculiarities and should be undoubtedly considered on the regional scale. Accordingly this part includes some characteristic examples and case studies from local up to regional and continental dimensions. We discuss the importance of the trans-boundary of pollutant exposure as well as the application of critical load methodology for risk estimates. 

California is the most populated and the most extensively anthropogenically modified area of the USA. Moreover, this is a very complicated natural biogeochemical structure with numerous biogeochemical provinces charactered by different organization of food webs. A typical example is the selenium biogeochemical province in the Joaquin River valley where the exposure pathways have changed dramatically during the last century. 

Eurasia is the biggest continent of the World. Because of the huge size of Eurasia, all types of ecosystems and climatic belts are represented, from arctic deserts up to tropical rain forests. Accordingly, some characteristic examples will be given here with special attention to biogeochemical provinces where biogeochemical exposure pathways induce the relevant diseases. 

---