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Bifurcation factor

Comparing this scheme with its common shape expressed by reactions (2.14) and (2.15a), it should be noted that it gives the best display for the role of the intermediate substance X, which is common to both conjugated reactions as the bifurcation factor of the reaction system, and the inducer is expended in amounts providing A expenditure in both reactions. [Pg.28]

Generally it was found that resolution R is practically the same for isoeluotropic mixtures methanol and acetonitrile with water. The dependencies were obtained between capacity factors for derivatives of 3-chloro-l,4-naphtoquinone at their retention with methanol and acetonitrile. Previous prediction of RP-HPLC behaviour of the compounds was made by ChromDream softwai e. Some complications ai e observed at weak acetonitrile eluent with 40 % w content when for some substances the existence of peak bifurcation. [Pg.286]

Lys-9 methyltransferase, DIMS, is similar in sequence to Clr4 and Su(var)3-9 and has a SET domain flanked by cysteine rich elements [191]. Murine ESET (ERG-associated protein with SET domain) has these domains and methylates free H3 [192]. This murine methyltransferase, which has high sequence similarity to human SETDBl (SET domain, bifurcated 1), interacts with the transcription factor ERG. SETBl, a specific H3 Lys-9 methyltransferase, interacts with KAP-1 copressor, which binds to KRAB domain zinc-finger proteins [193]. SETBl methylates Lys-9 when Lys-4 is methylated but enzymatic activity is inhibited when Ser-10 is phosphorylated or when Lys-14 is acetylated. [Pg.223]

Bifurcation analysis in the local Teorell model accounting for negative osmosis and concentration dependence of the electro-osmotic factor as prescribed by (6.4.44). The analysis should be essentially identical to that of 6.3 with the generalized Darcy s law (6.3.11) replaced by the expression... [Pg.247]

It is often important to predict and understand the flame extinction phenomenon in stagnation or opposed flows. As discussed briefly in Sect. 17.5 and illustrated in Fig. 17.11, the extinction point represents a bifurcation where the steady-state solutions are singular. Thus direct solution of the discrete steady problem by Newton s method necessarily cannot work because the Jacobian is singular and cannot be inverted or factored into its LU products. Moreover, in some neighborhood around the singular point, the numerical problem becomes sufficiently ill-conditioned as to make it singular for practical purposes. [Pg.709]

The relevance of the question discussed above to the problem of hydrolytic degradation of cellulose arises from both stereochemical and electronic factors associated with the difference in conformation of the glycosidic linkage as well as with the participation of the C6 oxygen in the bifurcated intramolecular hydrogen bond. The implications of these factors will now be considered. [Pg.72]

In several experiments, in particular the study by Temkin and co-workers [224] of the kinetics in ethylene oxidation, slow relaxations, i.e. the extremely slow achievement of a steady-state reaction rate, were found. As a rule, the existence of such slow relaxations is ascribed to some "side reasons rather than to the purely kinetic ("proper ) factors. The terms "proper and "side were first introduced by Temkin [225], As usual, we classify as slow "side processes variations in the chemical or phase composition of the surface under the effect of reaction media, catalyst deactivation, substance diffusion into its bulk, etc. These processes are usually considered to require significantly longer times to achieve a steady state compared with those characterizing the performance of chemical reactions. The above numerical experiment, however, shows that, when the system parameters attain their bifurcation values, the time to achieve a steady state, tr, sharply increases. [Pg.287]

Finally, in addition to the issues of costs and secondary events, treatment is also lacking for many more at-risk patients who cannot undergo successful angioplasty. These patients, who may have either diffuse, nonstentable, bifurcated lesions, or multivessel disease (i.e., diabetics), are not benefiting as much from DES, and improved treatments here also remain a clear clinical need. Often there is a systemic and local activation of the immune response, followed by a consequent local vascular incident. The role of the systemic immune response in these individuals, as well as in cardiovascular patients in general, is evidenced by the numerous reports of correlation of disease with increases in plasma markers such as CRB tumor necrosis factor, and even circulating white cell counts (87-89). [Pg.320]

In contrast to classical chemical reactors, a fuel cell provides the possibility to control the reaction rate directly from outside by setting the cell current, because the local cell current density and the local reaction rate are related by a constant factor. This operation of a fuel cell at constant cell current is more important than the potentiostatic operation from a technical point of view, as fuel cells typically are characterized by current-voltage plots. Because the integral Eq. (15) has to be included in the analysis, the investigation of the galvanostatic operation is more difficult and requires numerical methods. In the following, numerical bifurcation... [Pg.79]

Bettonvil, B. (1995). Factor screening by sequential bifurcation. Communications in Statistics—Simulation and Computation, 24, 165-185. [Pg.205]

Screening for the Important Factors in Large Discrete-Event Simulation Models Sequential Bifurcation and Its Applications... [Pg.287]

Our case study is introduced in Section 1.4. The assumptions behind, and the steps involved in, sequential bifurcation are described in Sections 2.2 and 2.3 and the steps are illustrated using a first-order polynomial model with random noise. In Section 2.4, a more realistic model involving interactions is used for screening the important factors in the case study. Issues of programming are addressed in Section 3. [Pg.287]

The efficiency of sequential bifurcation, as measured by the number of observations (that is, simulation runs and hence simulation time), increases if the individual factors are renumbered to be in increasing order of importance (see Bettonvil 1990, page 44), so that... [Pg.294]

We introduce the following additional sequential bifurcation notation adapted for replicated random responses. We use y( ) r to represent the observed (simulation) output in replicate r when factors 1 to j are set at their high levels and the remaining factors are set at their low levels (r = 1,..., m). [Pg.295]


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See also in sourсe #XX -- [ Pg.28 ]




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Bifurcate

Bifurcated

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