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Batch absorbers

Example 24.6 illustrates this procedure for batch absorber-reactors. [Pg.551]

However, if contaminating antibodies do interfere with specificity, affinity absorption of the antiserum is usually performed. Batch-absorbed antisera almost always contain residual levels of contaminating antibodies (mostly of the non-precipitating type) and will cause nonspecific staining of tissue if used at excessively high concentration (8). [Pg.118]

A gas that contains CO2 is contacted with liquid water in an agitated batch absorber. The equilibrium solubility of CO2 in water is given by Henry s law (Section 6.4b)... [Pg.570]

Fig. 1 Capture of carbon dioxide by a 50 g/L solution of absorbent in a 500 ml batch absorber. The gas being treated was ambient air, at a carbon dioxide concentration of 403 pmoles/mole and a flow rate of 0.96 slpm. The fact that this absorbent can reduce CO2 levels to less than that of ambient air shows that a properly designed countercurrent scrubbing unit could use this solution to keep CO2 levels in a combustion gas stream from exceeding the normal levels present in the atmosphere. It should be noted that, under these conditions, the ability of pure water to absorb carbon dioxide was negligible. Fig. 1 Capture of carbon dioxide by a 50 g/L solution of absorbent in a 500 ml batch absorber. The gas being treated was ambient air, at a carbon dioxide concentration of 403 pmoles/mole and a flow rate of 0.96 slpm. The fact that this absorbent can reduce CO2 levels to less than that of ambient air shows that a properly designed countercurrent scrubbing unit could use this solution to keep CO2 levels in a combustion gas stream from exceeding the normal levels present in the atmosphere. It should be noted that, under these conditions, the ability of pure water to absorb carbon dioxide was negligible.
There are direct contact preheaters [I, 5] (direct contact between flue gas and batch/cullet) and indirect preheaters [2, 3, 4] on the market. The direct contact preheaters offer the possibility to act as a scrubber device raw materials in the batch absorb acid species (SO2, SO3, HF, HCI, SeOz) from the flue gases. But direct preheaters often show high dust loads in the flue gases downstream the preheater system. This asks for a high efficient filtering (ESP or bag filter) system. [Pg.7]

The process options reflect the broad range of compositions and gas volumes that must be processed. Both batch processes and continuous processes are used. Batch processes are used when the daily production of sulfur is small and of the order of 10 kg. When the daily sulfur production is higher, of the order of 45 kg, continuous processes are usually more economical. Using batch processes, regeneration of the absorbant or adsorbant is carried out in the primary reactor. Using continuous processes, absorption of the acid gases occurs in one vessel and acid gas recovery and solvent regeneration occur in a separate reactor. [Pg.172]

A hst of polyol producers is shown in Table 6. Each producer has a varied line of PPO and EOPO copolymers for polyurethane use. Polyols are usually produced in a semibatch mode in stainless steel autoclaves using basic catalysis. Autoclaves in use range from one gallon (3.785 L) size in research faciUties to 20,000 gallon (75.7 m ) commercial vessels. In semibatch operation, starter and catalyst are charged to the reactor and the water formed is removed under vacuum. Sometimes an intermediate is made and stored because a 30—100 dilution of starter with PO would require an extraordinary reactor to provide adequate stirring. PO and/or EO are added continuously until the desired OH No. is reached the reaction is stopped and the catalyst is removed. A uniform addition rate and temperature profile is required to keep unsaturation the same from batch to batch. The KOH catalyst can be removed by absorbent treatment (140), extraction into water (141), neutralization and/or crystallization of the salt (142—147), and ion exchange (148—150). [Pg.353]

Storage of heat is a temporary operation since perfect thermal insulators are unknown thus, heat is absorbed in solids or liquids as sensible or latent heat to be released later at designated times and conditions. The collection and release of heat can be achieved in two modes on a batch basis, as in the checkerbrick regenerator for blast furnaces, or on a continuous basis, as in the Ljungstrom air heater. [Pg.2406]

BBT solution on unmodified sorbents of different nature was studied. Silica gel Merck 60 (SG) was chosen for further investigations. BBT immobilization on SG was realized by adsoi ption from chloroform-hexane solution (1 10) in batch mode. The isotherm of BBT adsoi ption can be referred to H3-type. Interaction of Co(II), Cu(II), Cd(II), Ni(II), Zn(II) ions with immobilized BBT has been studied in batch mode as a function of pH of solution, time of phase contact and concentration of metals in solution. In the presence of sodium citrate absorbance (at X = 620 nm) of immobilized BBT grows with the increase of Cd(II) concentration in solution. No interference was observed from Zn(II), Pb(II), Cu(II), Ni(II), Co(II) and macrocomponents of natural waters. This was assumed as a basis of soi ption-spectroscopic and visual test determination of Cd(II). Heavy metals eluted from BBT-SG easily and quantitatively with a small volume of HNO -ethanol mixture. This became a basis of soi ption-atomic-absoi ption determination of the total concentration of heavy metals in natural objects. [Pg.292]

The oxidation of Fe(CN)g to Fe(CN)g by peroxidisulfate, SjOg", can be monitored spectrophotometrically by observing die increase in absorbance at 420 nm, D 2o well-mixed batch system. Assume dial die kinetic scheme is ... [Pg.177]

Batch with Constant Reflux Ratio, 48 Batch with Variable Reflux Rate Rectification, 50 Example 8-14 Batch Distillation, Constant Reflux Following the Procedure of Block, 51 Example 8-15 Vapor Boil-up Rate for Fixed Trays, 53 Example 8-16 Binary Batch Differential Distillation, 54 Example 8-17 Multicomponent Batch Distillation, 55 Steam Distillation, 57 Example 8-18 Multicomponent Steam Flash, 59 Example 8-18 Continuous Steam Flash Separation Process — Separation of Non-Volatile Component from Organics, 61 Example 8-20 Open Steam Stripping of Heavy Absorber Rich Oil of Light Hydrocarbon Content, 62 Distillation with Heat Balance,... [Pg.497]

Thermochemistry is concerned with the study of thermal effects associated with phase changes, formation of chemical compouncls or solutions, and chemical reactions in general. The amount of heat (Q) liberated (or absorbed) is usually measured either in a batch-type bomb calorimeter at fixed volume or in a steady-flow calorimeter at constant pressure. Under these operating conditions, Q= Q, = AU (net change in the internal energy of the system) for the bomb calorimeter, while Q Qp = AH (net change in the enthalpy of the system) for the flow calorimeter. For a pure substance. [Pg.351]

Dry polymers can be stored for up to 2 years, but are hygroscopic and absorb moisture from the air. Keep them in sealed bags in a cool, dry storeroom. Batches of polymer solutions made from dry polymers should be used within 24 hours. [Pg.319]

Sulfonation with chlorosulfonic acid requires special corrosion-proof equipment either glass-lined steel or all glass. The latter is especially suitable for small batch size sulfonation. The HC1 absorber also is built of either glass-lined steel or all glass. [Pg.653]

Purpose Find correlations in a data table the data table is organized into M columns, each of which corresponds to a dimension, e.g., concentrations of impurities, pH, absorbance at various wavelengths, etc. Each row corresponds to a sample, e.g., a batch of material analyzed according to M methods. [Pg.366]

Porphyridium species are the sources of fluorescent pink color. The main Porphyridium phycobiliproteins are B-phycoerythrin and b-phycoerythrin. Maximum absorbance of a 1% solution of B-phycoerythrin in a 1-cm cuvette is at 545 inn, and the fluorescence emission peak is at 575 inn molecular weight is 240 kda. Batch culture of Porphyridium species outdoors yields approximately 2(X) mg of colorant per liter of culture after 3 days the phycoerythrin level in the colorant is about 15%. A higher concentration of phycoerythrin, up to 30%, can be achieved under optimal algal culture conditions. [Pg.411]

Pectolytic activity was also studied in batch reactors, following the reaction progress in thermostated quartz cuvettes. The reaction medium (3 cm ) was prepared with 1.5 g/L pectin in the standard buffer and 0.063 mg of enzyme. The absorbance of the reaction mixture against the substrate blank was continuously recorded at the spectrophotometer (Perkin Elmer Lambda 2, USA). Typical reaction time was 15 minutes, but initial reaction rates were estimated considering only the absorbances recorded during the first 200 seconds, range of totally linear response. [Pg.443]

Vinas et al. [47] determined penicillamine routinely by using batch procedures and FIA. A capsule was dissolved in water, diluted to 250 mL, and a suitable portion of the solution treated with 1 mM Co(II) solution (2.5 mL) and 2 M ammonium acetate (2.5 mL). The mixture was diluted to 25 mL and the absorbance of the yellow complex was determined at 360 nm. Calibration graphs were linear for 0.02-0.3 mM of penicillamine. The method was modified for flow injection analysis using peak-height or peak-width methods, but in both cases the flow rates were maintained at 3.3 mL/min. For the peak-height technique, calibration graphs were linear for 0.1-2 mM, and the sampling frequency was 150 samples per hour. For the peak-width method, the response was linear for 50 pM to 0.1 M, and this method was particularly useful for routine determinations. [Pg.142]


See other pages where Batch absorbers is mentioned: [Pg.412]    [Pg.172]    [Pg.312]    [Pg.457]    [Pg.233]    [Pg.257]    [Pg.275]    [Pg.393]    [Pg.40]    [Pg.471]    [Pg.465]    [Pg.180]    [Pg.177]    [Pg.795]    [Pg.81]    [Pg.211]    [Pg.262]    [Pg.195]    [Pg.464]    [Pg.514]    [Pg.443]    [Pg.379]    [Pg.393]    [Pg.30]    [Pg.135]    [Pg.136]    [Pg.189]    [Pg.210]    [Pg.45]    [Pg.227]   
See also in sourсe #XX -- [ Pg.15 , Pg.31 ]




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