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Azomethan

Figure B2.5.7. Oscilloscope trace of the UV absorption of methyl radical at 216 mn produced by decomposition of azomethane after a shock wave (after [M]) at (a) 1280 K and (b) 1575 K. Figure B2.5.7. Oscilloscope trace of the UV absorption of methyl radical at 216 mn produced by decomposition of azomethane after a shock wave (after [M]) at (a) 1280 K and (b) 1575 K.
Heterocyclics of all sizes, as long as they are unsaturated, can serve as dipolarophiles and add to external 1,3-dipoles. Examples involving small rings are not numerous. Thiirene oxides add 1,3-dipoles, such as di azomethane, with subsequent loss of the sulfur moiety (Section 5.06.3.8). As one would expect, unsaturated large heterocyclics readily provide the two-atom component for 1,3-dipolar cycloadditions. Examples are found in the monograph chapters, such as those on azepines and thiepines (Sections 5.16.3.8.1 and 5.17.2.4.4). [Pg.28]

Both symmetrical and unsymmetrical azo compounds can be made, so that a single radical or two different ones may be generated. The energy for the decomposition can be either thermal or photochemical. In the thermal decomposition, it has been established that the temperature at which decomposition occurs depends on the nature of the substituent groups. Azomethane does not decompose to methyl radicals and nitrogen until temperatures above 400°C are reached. Azo compounds that generate relatively stable radicals decompose at much lower temperatures. Azo compounds derived from allyl groups decompose somewhat above 100°C for example ... [Pg.673]

Benzyl ethers of phenols can also be prepared by reaction with phenyldi-azomethane. [Pg.266]

Azomethane decomposes into nitrogen and ethane at high temperatures according to the following equation ... [Pg.316]

Azomethane. CA Registry No 503-28-6. The following supplements the article in Vol 1, A655-R under Azomethane Preparation. It has been prepd by the oxidn of N,N -dimethylhydrazine with K dichromate (Ref 2). The action of Cu(II) sulfate in aq Na acetate contg HC1, Na chloride, or Cu(II) chloride on the same hydrazine gives the Cu(l) chloride complex of azomethane (Refs 3 13)... [Pg.84]

Its addn at a level of 0.1—5.0% was found to improve the octane rating of diesel fuels (Ref 10) Cuprous Chloride Complex. For prepn see above. It is a red cryst solid, readily decompd into its components at 135—40° (Refs 4 13). X-ray diffraction showed that the azomethane mols lie betw the infinite folded sheets of the Cu(I) chloride (Ref 11). The complex is used in the prepn of highly pure samples of azomethane (Ref 7)... [Pg.85]

Self-Test 13.6B Azomethane, CH N2CH3, decomposes to ethane and nitrogen gas in the reaction CH N2CH (g) - CH CH3(g) + N2(g). The reaction was followed at 460. K by measuring the partial pressure of azomethane over time ... [Pg.663]

Confirm that the reaction is first order of the form Rate = kP, where P is the partial pressure of azomethane, and find the value of k. [Pg.663]

Azoxy-Verbindungen werden durch Pentacarbonyleisen3,4 bzw. Dinatrium-decacarbo-nyl-dichrom5 zu den entsprechenden Azo-Verbindungenreduziert. So erhalt manz. B. aus Hexafluor-azoxymethan 50% d.Th. Hexafluor-azomethan (Kp7,l0 -320)3 bzw. aus 2,2 -Dimethyl-azoxybenzol 65% d.Th. 2,2 -Dimethyl-azobenzol4. [Pg.538]

Phenyldiazonium-Salze bilden mit Methyl-magnesiumjodid ein Gemisch aus Biphenyl, Jodbenzol und Ben-zol-azomethan (s.ds. Handb., Bd. X/3, S. 167). [Pg.541]

Recently, Stair and coworkers [10, 11] developed a method to produce gas-phase methyl radicals, and used this to study reactions of methyl groups on Pt surfaces [12] and on molybdenum oxide thin films [13]. In this approach, methyl radicals are produced by pyrolysis of azomethane in a tubular reactor locat inside an ulttahigh vacuum chamber. This method avoids the complications of co-adsorbcd halide atoms, it allows higher covraages to be reached, and it allows tiie study of reactions on oxide and other surfaces that do not dissociate methyl halides effectively. [Pg.327]

Methyl radicals were produced by pyrolysis of azomethane (CH3N2CH3). Azomethane was synthesized as describe earlier [18]. It was purified periodically by fteeze-pump cycles at 77 K, and the gas purity verified by RGA. The methyl radical source was similar to that developed by Stair and coworkers. [10, 11] The source was made of a quartz tube with 3 mm OD and 1 mm ID, resistive heating was supplied by means of a 0.25 mm diameter tantalum wire wrapped outside the quartz tube. The len of the heating zone was 4 cm, recessed from the end of the tube by 1 cm. An alumina tube around the outside of the heating zone served as a radiation shield. Azomethane was admitted to the hot tube at a pressure of 1x10-8 to 1x10-7 Torr via a high-vacuum precision leak valve. The pyrolysis tube was maintained at about 1200 K, adequate to decrease the major peaks in the mass sp trum of the parent azomethane at 58 and 43 amu by at least a factor of 100. [Pg.328]

In a separate set of experiments designed to follow the gas phase reactions of CHj-radicals with NO, CHj- radicals were generated by the thermal decomposition of azomethane, CHjN NCHj, at 980 °C. The CH3- radicals were subsequently allowed to react with themselves and with NO in a Knudsen cell that has been described previously [12]. Analysis of intermediates and products was again done by mass spectrometry, using the VIEMS. Calibration of the mass spectrometer with respect to CH,- radicals was carried out by introducing the products of azomethane decomposition directly into the high vacuum region of the instrument. [Pg.713]

Shortly after, Doetschman and Hutchison reported the first example of a reactive carbene in the crystalline solid state, by preparing diphenylcarbene from diphenyldi-azomethane in mixed crystals with 1,1-diphenylethylene 84 (Scheme 7.23). When the mixed crystals were irradiated, carbene 85 was detected by electron paramagnetic resonance (EPR) and the disappearance of the signal was monitored to determine its kinetic behavior. Two reactions were shown to take place under topochemical... [Pg.319]

The photochemistry of the simplest member of the azo family, azomethane, has been extensively investigated in the vapor phase(1) and in solution(2) ... [Pg.250]

Photolysis in the gas phase leads to the quantitative production of nitrogen and methyl radicals. Photolysis in solution, however, results in a shift in the absorption spectrum to longer wavelengths due to the production of a new species, which is identified as the cw-azomethane (the trcms configuration is the normal isomer). Similarly, irradiation of tro/u-azoisopropane<3) results in trans-cis isomerization to the cis isomer ... [Pg.250]

Nitromethan 1942 Methylamin 1950, 1957 MW (47) Methylisocyanat 1940 Azomethan 1935 Athylamin 1950 1,2-Dimethylhydrazin 1948 N.N -Dichlorpiperazin 1949 Hexamethylentetramin 1938... [Pg.32]

The slow thermal decomposition of gaseous azomethane becomes explosive above... [Pg.339]

Using an alternative route involving [3+2] cycloaddition of phosphoranediyldi-azomethane (43) with trimethylsilylphosphaethyne (44), 5-trimethylsilyl derivative (45) of the zwitterionic 3-phosphino-[l,2,4]diazaphospholide (42) was obtained (Scheme 13) [44],... [Pg.184]

Kobaek-Larsen M, Christensen L P, Vach W, Ritskes-Hoitinga J and Brandt K (2005), Inhibitory effects of feeding with carrots or (-) falcarinol on development of azomethane-induced preneoplastic lesions in the rat colon , J Agric Food Chem, 53, 1823-1827. [Pg.325]

The regioselective ozonation of alkylidene-sultams 282 followed by reaction with di azomethane leads to the formation of highly reactive bicyclic trioxo-isothiazolidine 284... [Pg.267]

Recently the two-step decomposition of azomethane was proved in the study of the femtosecond dynamics of this reaction [68]. The intermediate CH3N2 radical was detected and isolated in time. The reaction was found to occur via the occurrence of the first and the second C—N bond breakages. The lifetime of CH3N2 radical is very short, i.e., 70fsec. The quantum-chemical calculations of cis- and /nmv-azomcthanc dissociation was performed [69]. [Pg.122]

Free radicals formed from an initiator in the gas phase take part in other reactions and recombine with a very low probability (0.1-2%). The decomposition of the initiator in the liquid phase leads to the formation of radical pairs, and the probability of recombination of formed radicals in the liquid phase is high. For example, the photolysis of azomethane in the gas phase in the presence of propane (RH) gives the ratio [C2H6]/[N2] = 0.015 [76]. This ratio is low due to the fast reactions of the formed methyl radicals with propane ... [Pg.124]


See other pages where Azomethan is mentioned: [Pg.538]    [Pg.538]    [Pg.582]    [Pg.582]    [Pg.167]    [Pg.204]    [Pg.118]    [Pg.610]    [Pg.86]    [Pg.697]    [Pg.890]    [Pg.308]    [Pg.328]    [Pg.549]    [Pg.44]    [Pg.339]    [Pg.25]    [Pg.807]    [Pg.807]    [Pg.851]    [Pg.851]   
See also in sourсe #XX -- [ Pg.103 ]




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Azomethan trans

Azomethane

Azomethane

Azomethane pyrolysis

Azomethane reaction

Azomethane synthesis

Azomethane via retro Diels-Alder reactions

Azomethane, chain sensitization

Azomethane, decomposition

Azomethane, photolysis

Azomethane, photooxidation

Azomethane, spectroscopy

Ethane from azomethane

Methanes Azomethane

Nitrogen from azomethane

Phenyldi azomethan

Rate laws azomethane decomposition

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