Velocity, average

Thus the average velocity decays exponentially to zero on a time scale detennined by the friction coefficient and the mass of the particle. This average behaviour is not very interesting, because it corresponds to tlie average of a quantity that may take values in all directions, due to the noise and friction, and so the decay of the average value tells us little about the details of the motion of the Brownian particle. A more interesting... 

Assuming a thennal one-dimensional velocity (Maxwell-Boltzmaim) distribution with average velocity /2k iT/rr/tthe reaction rate is given by the equilibrium flux if (1) the flux from the product side is neglected and (2) the thennal equilibrium is retamed tliroughout the reaction ... 

The application of a small external electric field A to a semiconductor results in a net average velocity component of the carriers (electrons or holes) called the drift velocity, v. The coefficient of proportionality between E and is known as the carrier mobility p. At higher fields, where the drift velocity becomes comparable to the thennal... 

The Reynolds number for flow in a tube is defined by dvpirj, where d is the diameter of the tube, V is the average velocity of the fluid along the tube, p is the density of the fluid, and rj is its dynamic viscosity. At flow velocities corresponding with values of the Reynolds number of greater than 2000, turbulence is encountered. 

Tracer Type. A discrete quantity of a foreign substance is injected momentarily into the flow stream and the time interval for this substance to reach a detection point, or pass between detection points, is measured. From this time, the average velocity can be computed. Among the tracers that have historically been used are salt, anhydrous ammonia, nitrous oxide, dyes, and radioactive isotopes. The most common appHcation area for tracer methods is in gas pipelines where tracers are used to check existing metered sections and to spot-check unmetered sections. 

Simila.rityAna.Iysis, Similarity analysis starts from the equation describing a system and proceeds by expressing all of the dimensional variables and boundary conditions in the equation in reduced or normalized form. Velocities, for example, are expressed in terms of some reference velocity in the system, eg, the average velocity. When the equation is rewritten in this manner certain dimensionless groupings of the reference variables appear as coefficients, and the dimensional variables are replaced by their normalized relatives. If another physical system can be described by the same equation with the same numerical values of the coefficients, then the solutions to the two equations (normalized variables) are identical and either system is an accurate model of the other. 

A separate equation is obtained for each component i Consider the important case of steady-state flow of a single fluid through the pipe section of Figure 21b, where the flow is taken to be perpendicular to the cross sections and Making use of the concept of average velocity ... 

In terms of enthalpy and average velocities, this becomes... 

Measurement by Thermal Effects. When a fine wire heated electrically is exposed to a flowing gas, it is cooled and its resistance is changed. The hot-wire anemometer makes use of this principle to measure both the average velocity and the turbulent fluctuations in the flowing stream. The fluid velocity, L, is related to the current, /, and the resistances, R, of the wire at wire, and gas, g, temperatures via... 

The effective thermal conductivity of a Hquid—soHd suspension has been reported to be (46) larger than that of a pure Hquid. The phenomenon was attributed to the microconvection around soHd particles, resulting in an increased convective heat-transfer coefficient. For example, a 30-fold increase in the effective thermal conductivity and a 10-fold increase in the heat-transfer coefficient were predicted for a 30% suspension of 1-mm particles in a 10-mm diameter pipe at an average velocity of 10 m/s (45). 

In turbulent mixing, the Hquid velocity at any point u can be considered the sum of an average velocity ul and a fluctuating (with time) velocity u ... 

The shear rate between the average velocities is called macroscale shear present in eddies of 500 p.m or larger in size. The shear rate between the fluctuating velocities, present in smaller than 100 p.m eddies, is called microscale shear. A mixing tank, therefore, has several types of shear, ie, macroscale and microscale, maximum and minimum, average in the impeller zone and in the entire tank. 

The first equahty (on the left-hand side) corresponds to the molar flux with respect to the volume average velocity while the equahty in the center represents the molar flux with respect to the molar average velocity and the one on the right is the mass flux with respect to the mass average velocity These must be used with consistent flux expressions for fixed coordinates and for Nc components, such as ... 

Laminar and Turbulent Flow, Reynolds Number These terms refer to two distinct types of flow. In laminar flow, there are smooth streamlines and the fuiid velocity components vary smoothly with position, and with time if the flow is unsteady. The flow described in reference to Fig. 6-1 is laminar. In turbulent flow, there are no smooth streamlines, and the velocity shows chaotic fluctuations in time and space. Velocities in turbulent flow may be reported as the sum of a time-averaged velocity and a velocity fluctuation from the average. For any given flow geometry, a dimensionless Reynolds number may be defined for a Newtonian fluid as Re = LU p/ I where L is a characteristic length. Below a critical value of Re the flow is laminar, while above the critical value a transition to turbulent flow occurs. The geometry-dependent critical Reynolds number is determined experimentally. 

Simplified forms of Eq. (6-8) apply to special cases frequently found in prac tice. For a control volume fixed in space with one inlet of area Ai through which an incompressible fluid enters the control volume at an average velocity Vi, and one outlet of area Ao through which fluid leaves at an average velocity V9, as shown in Fig. 6-4, the continuity equation becomes... 

Here g is the gravity vector and tu is the force per unit area exerted by the surroundings on the fluid in the control volume. The integrand of the area integr on the left-hand side of Eq. (6-10) is nonzero only on the entrance and exit portions of the control volume boundary. For the special case of steady flow at a mass flow rate m through a control volume fixed in space with one inlet and one outlet, (Fig. 6-4) with the inlet and outlet velocity vectors perpendicular to planar inlet and outlet surfaces, giving average velocity vectors Vi and V9, the momentum equation becomes... 

A useful simphfication of the total energy equation applies to a particular set of assumptions. These are a control volume with fixed solid boundaries, except for those producing shaft work, steady state conditions, and mass flow at a rate m through a single planar entrance and a single planar exit (Fig. 6-4), to whi(m the velocity vectors are perpendicular. As with Eq. (6-11), it is assumed that the stress vector tu is normal to the entrance and exit surfaces and may be approximated by the pressure p. The equivalent pressure, p + pgz, is assumed to be uniform across the entrance and exit. The average velocity at the entrance and exit surfaces is denoted by V. Subscripts 1 and 2 denote the entrance and exit, respectively. 

Here, h is the enthalpy per unit mass, h = u + p/. The shaft work per unit of mass flowing through the control volume is 6W5 = W, /m. Similarly, is the heat input rate per unit of mass. The fac tor Ot is the ratio of the cross-sectional area average of the cube of the velocity to the cube of the average velocity. For a uniform velocity profile, Ot = 1. In turbulent flow, Ot is usually assumed to equal unity in turbulent pipe flow, it is typically about 1.07. For laminar flow in a circiilar pipe with a parabohc velocity profile, Ot = 2. 

Friction Factor and Reynolds Number For a Newtonian fluid in a smooth pipe, dimensional analysis relates the frictional pressure drop per unit length AP/L to the pipe diameter D, density p, and average velocity V through two dimensionless groups, the Fanning friction factor/and the Reynolds number Re. 

Velocity Profiles In laminar flow, the solution of the Navier-Stokes equation, corresponding to the Hagen-PoiseuiUe equation, gives the velocity i as a Innction of radial position / in a circular pipe of radius R in terms of the average velocity V = Q/A. The parabolic profile, with centerline velocity t ce the average velocity, is shown in Fig. 6-10. 

FIG. 6-10 Parabolic velocity profile for laminar flow in a pipe, with average velocity V. 

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