Atomic results

The occupation of each tetraliedral and octaliedral site in tliese regularly oriented arrays of cavities by, for example, alkali atoms results in tire transfer of a single electron to tire fullerene s conduction band (ti ) [58]. Consequently,... 

The formation of a fourth covalent bond by the aluminium atom results in spatial rearrangement from the trigonal planar, for three bonding electron pairs, to tetrahedral, for four bonding electron pairs. 

Precision For absorbances greater than 0.1-0.2, the relative standard deviation for atomic absorption is 0.3-1% for flame atomization, and 1-5% for electrothermal atomization. The principal limitation is the variation in the concentration of free-analyte atoms resulting from a nonuniform rate of aspiration, nebulization, and atomization in flame atomizers, and the consistency with which the sample is heated during electrothermal atomization. 

V n der W ls Interactions. Van der Waals iateractions result from the asymmetric distribution of electronic charge surrounding an atom, which induces a complementary dipole in a neighboring atom, resulting in an attractive force. In general, the attractive force of van der Waals interactions is very weak (<4.2 kJ/mol (1 kcal/mol)) but may become significant if steric complementarity creates an opportunity to form a large number of van der Waals attractions. 

The transfer of a hydrogen atom resulting in isomerization of the radical... 

Primary bond formation takes place by various interactions between electrons in the outermost shell of two atoms resulting in the production of a more stable... 

The resultant close packing and the heavy chlorine atom result in the polymer having a high specific gravity (1.875) and a low permeability to vapours and gases. 

The crystal structure of many compounds is dominated by the effect of H bonds, and numerous examples will emerge in ensuing chapters. Ice (p. 624) is perhaps the classic example, but the layer lattice structure of B(OH)3 (p. 203) and the striking difference between the a- and 6-forms of oxalic and other dicarboxylic acids is notable (Fig. 3.9). The more subtle distortions that lead to ferroelectric phenomena in KH2PO4 and other crystals have already been noted (p. 57). Hydrogen bonds between fluorine atoms result in the formation of infinite zigzag chains in crystalline hydrogen fluoride... 

The mechanism of the rearrangement is explained as shown in Scheme 19. Protonation of the 9-hydroxy group followed by its elimination and subsequent chloride attack at the 4a-carbon generates a chloroindolenine 126. Addition of water to the 9a-imine carbon atom of 126 gives 127. Concerted elimination of the chloride with rearrangement of the alkyl side chain attached to the 9a carbon atom results in 3,3-disubstituted oxindole structure 120a. 

EXAFS is observed as a modulating change in the absorption coefficient caused by the ejected electron wave back-scattering from the surrounding atoms, resulting in interference between ejected and back-scattered waves. It is defined as ... 

Usually atoms resulting from nuclear fission arc radioactive. There are also radioactive atoms produced from neutron capture by both U and U. Both types of radioactive atoms remain in the nuclear fuel. It is these radioactive atoms that comprise the nuclear wastes that require disposal in an environmentally acceptable manner. 

Since the nucleus has positive charge, it attracts electrons (each with negative charge). If a nucleus attracts the number of electrons just equal to the nuclear charge, an electrically neutral atom is formed. Consider a nucleus containing two protons, a helium nucleus. When the helium atom has two electrons as well (2— charge), an electrically neutral helium atom results ... 

In contrast, bromine does not add to the thiepin C —C double bond in 3-benzothiepins, whether these double bonds are substituted with carboxy groups or not. In the former case, one equivalent of bromine added to the sulfur atom resulting in the formation of a dibromosulfurane65 (see Section 2.1.4.1.). 

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